Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 12, Problem 12.CCP
Interpretation Introduction
Interpretation:
The reaction between a small crystal of sodium acetate with a
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An equilibrium reaction between chromate ions, CrO4 2- (yellow), and H+ ions is established to produce dichromate, Cr₂072-
(orange). Note the colours.
A student adds NaOH to a test tube containing an orange mixture of the above reagents. What is observed?
01. The solution turns from orange to yellow
O 2.A precipitate forms
3. The solution tuimns from orange to colourless
O4. The solution remains orange
The formation of the iron(III) thiocyanate complex ion is an exothermic equilibrium system. For each change to the system, indicate how the concentration of each species in the chemical equation will change to reestablish equilibrium. An up arrow indicates an increase in concentration, a down arrow indicates a decrease in concentration, and leaving it blank means there is no change in the concentration.
(a) In the determination of chloride by the Mohr method, what will be the
equilibrium concentration of silver ions in mg/L., on the basis of the solubility
product principle, when the chloride concentration has been reduced to 0.2 mg/L?
(b) If the concentration of chromate indicator used is 5 x 10 M, how much
excess silver ion in mg/L. must be present before the formation of a red
precipitate will begin?
Chapter 12 Solutions
Chemistry: The Molecular Science
Ch. 12.1 - The introduction to this chapter states that at a...Ch. 12.1 - Prob. 12.2CECh. 12.2 - After a mixture of cis-2-butene and trans-2-butene...Ch. 12.2 - Prob. 12.1PSPCh. 12.2 - Prob. 12.4ECh. 12.2 - When carbon dioxide dissolves in water it reacts...Ch. 12.2 - For each of these reactions, calculate KP from Kc....Ch. 12.3 - Prob. 12.3PSPCh. 12.4 - Suppose that solid AgCl and AgI are placed in 1.0...Ch. 12.4 - Prob. 12.6CE
Ch. 12.5 - For the equilibrium 2 SO2(g) + O2(g) 2 SO3(g) Kc...Ch. 12.5 - Prob. 12.7CECh. 12.5 - Prob. 12.6PSPCh. 12.5 - Prob. 12.7PSPCh. 12.6 - Prob. 12.8CECh. 12.6 - Prob. 12.9ECh. 12.6 - Prob. 12.10CECh. 12.6 - Prob. 12.8PSPCh. 12.7 - For the ammonia synthesis reaction
⇌
Does the...Ch. 12.8 - Prob. 12.13CECh. 12 - Prob. 1QRTCh. 12 - Prob. 2QRTCh. 12 - Prob. 3QRTCh. 12 - Decomposition of ammonium dichromate is shown in...Ch. 12 - For the equilibrium reaction in Question 4, write...Ch. 12 - Indicate whether each statement below is true or...Ch. 12 - Prob. 7QRTCh. 12 - Prob. 8QRTCh. 12 - Prob. 9QRTCh. 12 - Prob. 10QRTCh. 12 - The atmosphere consists of about 80% N2 and 20%...Ch. 12 - Prob. 12QRTCh. 12 - Prob. 13QRTCh. 12 - Prob. 14QRTCh. 12 - Prob. 15QRTCh. 12 - Prob. 16QRTCh. 12 - Prob. 17QRTCh. 12 - Prob. 18QRTCh. 12 - Prob. 19QRTCh. 12 - Prob. 20QRTCh. 12 - Prob. 21QRTCh. 12 - Prob. 22QRTCh. 12 - Prob. 23QRTCh. 12 - Prob. 24QRTCh. 12 - Prob. 25QRTCh. 12 - Prob. 26QRTCh. 12 - Prob. 27QRTCh. 12 - Prob. 28QRTCh. 12 - Prob. 29QRTCh. 12 - Prob. 30QRTCh. 12 - Given these data at a certain temperature,...Ch. 12 - The vapor pressure of water at 80. C is 0.467 atm....Ch. 12 - Prob. 33QRTCh. 12 - Prob. 34QRTCh. 12 - Prob. 35QRTCh. 12 - Prob. 36QRTCh. 12 - Carbon dioxide reacts with carbon to give carbon...Ch. 12 - Prob. 38QRTCh. 12 - Prob. 39QRTCh. 12 - Prob. 40QRTCh. 12 - Nitrosyl chloride, NOC1, decomposes to NO and Cl2...Ch. 12 - Suppose 0.086 mol Br2 is placed in a 1.26-L flask....Ch. 12 - Prob. 43QRTCh. 12 - Prob. 44QRTCh. 12 - Prob. 45QRTCh. 12 - Using the data of Table 12.1, predict which of...Ch. 12 - Prob. 47QRTCh. 12 - The equilibrium constants for dissolving silver...Ch. 12 - Prob. 49QRTCh. 12 - Prob. 50QRTCh. 12 - At room temperature, the equilibrium constant Kc...Ch. 12 - Prob. 52QRTCh. 12 - Consider the equilibrium N2(g)+O2(g)2NO(g) At 2300...Ch. 12 - The equilibrium constant, Kc, for the reaction...Ch. 12 - Prob. 55QRTCh. 12 - Prob. 56QRTCh. 12 - Prob. 57QRTCh. 12 - At 503 K the equilibrium constant Kc for the...Ch. 12 - Prob. 59QRTCh. 12 - Prob. 60QRTCh. 12 - Prob. 61QRTCh. 12 - Prob. 62QRTCh. 12 - Prob. 63QRTCh. 12 - Prob. 64QRTCh. 12 - Prob. 65QRTCh. 12 - Prob. 66QRTCh. 12 - Prob. 67QRTCh. 12 - Hydrogen, bromine, and HBr in the gas phase are in...Ch. 12 - Prob. 69QRTCh. 12 - Prob. 70QRTCh. 12 - Prob. 71QRTCh. 12 - Prob. 72QRTCh. 12 - Prob. 73QRTCh. 12 - Prob. 74QRTCh. 12 - Consider the system
4 NH3(g) + 3 O2(g) ⇌ 2 N2(g) +...Ch. 12 - Prob. 76QRTCh. 12 - Predict whether the equilibrium for the...Ch. 12 - Prob. 78QRTCh. 12 - Prob. 79QRTCh. 12 - Prob. 80QRTCh. 12 - Prob. 81QRTCh. 12 - Prob. 82QRTCh. 12 - Prob. 83QRTCh. 12 - Prob. 84QRTCh. 12 - Prob. 85QRTCh. 12 - Prob. 86QRTCh. 12 - Prob. 87QRTCh. 12 - Consider the decomposition of ammonium hydrogen...Ch. 12 - Prob. 89QRTCh. 12 - Prob. 90QRTCh. 12 - Prob. 91QRTCh. 12 - Prob. 92QRTCh. 12 - Prob. 93QRTCh. 12 - Prob. 94QRTCh. 12 - Prob. 95QRTCh. 12 - Prob. 96QRTCh. 12 - Prob. 97QRTCh. 12 - Prob. 98QRTCh. 12 - Prob. 99QRTCh. 12 - Prob. 100QRTCh. 12 - Two molecules of A react to form one molecule of...Ch. 12 - Prob. 102QRTCh. 12 - In Table 12.1 (←Sec. 12-3a) the equilibrium...Ch. 12 - Prob. 104QRTCh. 12 - Prob. 105QRTCh. 12 - Prob. 106QRTCh. 12 - Prob. 107QRTCh. 12 - Which of the diagrams for Questions 107 and 108...Ch. 12 - Draw a nanoscale (particulate) level diagram for...Ch. 12 -
The diagram represents an equilibrium mixture for...Ch. 12 - The equilibrium constant, Kc, is 1.05 at 350 K for...Ch. 12 - For the reaction in Question 111, which diagram...Ch. 12 - Prob. 113QRTCh. 12 - Prob. 114QRTCh. 12 - Prob. 115QRTCh. 12 - For the equilibrium...Ch. 12 - Prob. 117QRTCh. 12 - Prob. 119QRTCh. 12 - Prob. 120QRTCh. 12 - When a mixture of hydrogen and bromine is...Ch. 12 - Prob. 122QRTCh. 12 - Prob. 123QRTCh. 12 - Prob. 124QRTCh. 12 - Prob. 125QRTCh. 12 - Prob. 12.ACPCh. 12 - Prob. 12.BCPCh. 12 - Prob. 12.CCPCh. 12 - Prob. 12.DCPCh. 12 - Prob. 12.ECPCh. 12 - Prob. 12.FCP
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- Chromium(VI) forms two different oxyanions, the orange dichromate ion, Cr2O72 , and the yellow chromate ion, CrO42 . (See the following photos.) The equilibrium reaction between the two ions is Cr2O72(aq)+H2O(l)2CrO42(aq)+2H+(aq) Explain why orange dichromate solutions turn yellow when sodium hydroxide is added.arrow_forwardScott prepares a solution which contains a large excess of iron and a small amount of thiocyanate. He notices a faint orange color appear in the solution once mixed. He repeats this process with a higher concentration of thiocyanate and notices a deepening of the orange color in the solution once mixed. Explain what has happened to the equilibrium in this case. Has the value of Keq changed? Explain.arrow_forwardIn an aqueous chloride solution cobalt(II) exists in equilibrium with the complex ion CoCl². Co²+ (aq) is pink and CoC14² (aq) is blue. At low temperature the pink color predominates. At high temperature the blue color is strong. If we represent the equilibrium as: Co²+ (aq) + 4C1 (aq) = CoCl₂² (aq) We can conclude that: 1. This reaction O exothermic. O endothermic. Oneutral. O More information is needed to answer this question. 2. When the temperature is increased the equilibrium constant, K: O increases. Odecreases. O remains the same. O More information is needed to answer this question. 3. When the temperature is increased the equilibrium concentration of Co²+: O increases. Odecreases. O remains the same. OMore information is needed to answer this question. Previcarrow_forward
- Potassium Ferrioxalate is mixed with in 50 mL of 1 M H2SO4 In a beaker , it is then placed one-half of this solution in another beaker in the sun and the other half in a cabinet in the dark. the color of both solutions after 0, 5, 15, and 30 minutes are : In the sun it stayed clear the whole 30 min and the sample in the darkness of the cabinet turned light green, Briefly explain your observations in terms of the photochemical properties of ferrioxalate.arrow_forwardChoose the best answer below. Consider the following complex ion formation equilibrium and it's equilibrium constant, Kf. Which of the following statements is FALSE? Cu2+ (aq) + 4CN" (aq) Û Cu(CN)42- (aq) Kf = 1.0x1025 O Adding more CN- will cause more complex ion to form The equilibrium lies in favor of the complex ion Cu2+ is a Lewis acid in the reaction, and CN is a Lewis base Removing some of the Cu2* (e.g., by precipitation) will cause some of the complex ion to dissociate The complex ion is a Lewis acid-base adduct O If enough CN- is added, the equilibrium mixture would contain zero Cu2+arrow_forwardThe Kf for the dicyanosilver complex ion, [Ag(CN)2]-, is 5.6 x 1018. When solid NaCN is added to a 0.010 M solution of AgNO3, 0.50 M CN- was found to be present at equilibrium. Calculate the concentration of silver ion also present at equilibrium.arrow_forward
- In the second part of this experiment, a student makes a solution with initial concentrations of iron(III) and thiocyanate ions of 0.000900 M and 0.000600 M respectively. Using the Beer's Law plot produced in the first part of the lab, the student determines the equilibrium concentration of the thiocyanatoiron(III) complex (Fe(SCN)2+) to be 2.00 × 10−5 M. What are the equilibrium concentrations of the two starting ions, and what is the value of the equilibrium constant? [Fe3+] = [SCN−] = Kc =arrow_forwardIn the second part of this experiment, a student makes a solution with initial concentrations of iron(III) and thiocyanate ions of 0.000900 M and 0.000600 M respectively. Using the Beer's Law plot produced in the first part of the lab, the student determines the equilibrium concentration of the thiocyanatoiron(III) complex (Fe(SCN)2+) to be 1.00×10−5 M.What are the equilibrium concentrations of the two starting ions, and what is the value of the equilibrium constant? [Fe3+]= [SCN−]= Kc =arrow_forwardBarium fluoride has increased solubility in acidic solution. Why?arrow_forward
- Write the K formula for the following reactions.arrow_forward2+ In an aqueous chloride solution cobalt(II) exists in equilibrium with the complex ion CoC142. Co²+ (aq) is pink and CoCl2(aq) is blue. At low temperature the pink color predominates. At high temperature the blue color is strong. If we represent the equilibrium as: 2+ CoCl2(aq) Co²+ (aq) + 4C1¯ (aq) We can conclude that: 1. This reaction is O exothermic. O endothermic. Oneutral. O More information is needed to answer this question. 2. When the temperature is decreased the equilibrium constant, K: O increases. decreases. remains the same. O More information is needed to answer this question. 3. When the temperature is decreased the equilibrium concentration of Co²+: Prevarrow_forwardThe formation of the iron(III) thiocyanate complex ion is an exothermic equilibrium system. For each change to the system, indicate how the concentration of each species in the chemical equation will change to reestablish equilibrium. An up arrow indicates an increase in concentration, a down arrow indicates a decrease in concentration, and leaving it blank means there is no change in the concentration. Fe3+(aq) ++ SCN−(aq) ↽−−⇀↽−−⇀ Fe(SCN)2+(aq) increasing the concentration of Fe3+ decreasing the concentration of Fe(SCN)2 increasing the temperature of the system Answer Bank ↑↑ ↓↓arrow_forward
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