Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 12, Problem 12.65E
Interpretation Introduction

Interpretation:

The value of E(1) is to be numerically evaluated. The agreement between the corresponding calculated value and the given value of the energy correction is to be demonstrated.

Concept introduction:

Perturbation theory assumes that a system can be approximated as a known, solvable system. The difference between the known system and system of interest is small and additive. The average value of observable energy is represented as,

E=E(0)+E(1)

Where,

E(0) represents the average energy of the ideal system.

E(1) represents the first-order correction to the energy.

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Chapter 12 Solutions

Physical Chemistry

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