Concept explainers
(a)
Interpretation:
Liquefaction of the following gases has to be described.
Methyl chloride
Concept introduction:
Liquefaction: It is the process that produces a liquid from a gas or solid that produces a non-liquid state which performs on agreement with fluid subtleties.
Liquid air is cooled to very low temperature. To protect them, they retained in a vacuum system with insulated flask. These kinds of gases called permanent gases. They cannot be liquefied by compression at room temperature.
(b)
Interpretation:
Liquefaction of the following gases has to be described.
Oxygen (critical point is
Concept introduction:
Liquefaction: It is the process that produces a liquid from a gas or solid that produces a non-liquid state which performs on agreement with fluid subtleties.
Liquid air is cooled to very low temperature. To protect them, they retained in a vacuum system with insulated flask. These kinds of gases called permanent gases. They cannot be liquefied by compression at room temperature.
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Chapter 11 Solutions
General Chemistry - Standalone book (MindTap Course List)
- In an experiment, 20.00 L of dry nitrogen gas, N2, at 20.0C and 750.0 mmHg is slowly bubbled into water in a flask to determine its vapor pressure (see the figure on next page). The liquid water is weighed before and after the experiment, from which the experimenter determines that it loses 353.6 mg in mass. Answer the following questions. a How many moles of nitrogen were bubbled into the water? b The liquid water diminished by how many moles? What happened to the liquid? c How many moles of gas exit the flask during the experiment? What is the partial pressure of nitrogen gas exiting? The total gas pressure is 750.0 mmHg. d From these data, calculate the vapor pressure of water at 20C. Does this agree with what you expect?arrow_forwardWhich of the following substances can be liquefied by applying pressure at 25C? For those that cannot, describe the conditions under which they can be liquefied. Substance Critical Temperature Critical Pressure Sulfur dioxide, SO2 158C 78 atm Acetylene, C2H2 36C 62 atm Methane. CH4 82C 46 atm Carbon monoxide, CO 140C 35 atmarrow_forwardThe normal boiling point of SO2 is 263.1 K and that of NH3 is 239.7 K. At −40 °C, would you predict that ammonia has a vapor pressure greater than, less than, or equal to that of sulfur dioxide? Explain.arrow_forward
- Boron nitride (BN) exists in two forms. The first is a slippery solid formed from the reaction of BCl3 with NH3, followed by heating in an ammonia atmosphere at 750C. Subjecting the first form of BN to a pressure of 85,000 atm at 1800C produces a second form that is the second hardest substance known. Both forms of BN remain solids to 3000C. Suggest structures for the two forms of BN.arrow_forwardIn each of the following groups of substances, pick the one that has the given property. Justify your answer. a. highest boiling point: HBr, Kr, or Cl2 b. highest freezing point: H2O, NaCl, or HF c. lowest vapor pressure at 25C: Cl2, Br2, or I2 d. lowest freezing point: N2, CO, or CO2 e. lowest boiling point: CH4, CH3CH3, or CH3CH2CH3 f. highest boiling point: HF, HCl, or HBr g.arrow_forwardA syringe at a temperature of 20 C is filled with liquid ether in such a way that there is no space for any vapor. If the temperature is kept constant and the plunger is withdrawn to create a volume that can be occupied by vapor, what would be the approximate pressure of the vapor produced?arrow_forward
- Answer the following questions: (a) If XX behaved as an ideal gas, what would its graph of Z vs. P look like? (b) For most of this chapter, we performed calculations treating gases as ideal. Was this justified? (c) What is the effect of the volume of gas molecules on Z? Under what conditions is this effect small? When is it large? Explain using an appropriate diagram. (d) What is the effect of intermolecular attractions on the value of Z? Under what conditions is this effect small? When is it large? Explain using an appropriate diagram. (e) In general, under what temperature conditions would you expect Z to have the largest deviations from the Z for an ideal gas?arrow_forwardWhich of the following do you expect to be molecular solids? a silicon tetrachloride, SiCl4 b lithium bromide, LiBr c sodium fluoride, NaF d bromine chloride, BrClarrow_forwardWhat types of solids are these substances? (a) The hydrocarbon decane, C10H22, has a melting point of 31 C and is a poor electrical conductor. (b) Solid MgCl2 has a melting point of 714 C and conducts electricity only when melted.arrow_forward
- What is the density (in g/L) of carbon tetrachloride (CCl4) vapor at 728 mm Hg and 120 °C ?arrow_forwardMass of glass bulb with the unknown gas: 14.402g Mass empty bulb Temperature Volume of glass bulb: 670. mL Pressure 12.232 g 1751. tor 21.C The gas is A,3 8.) (a)Which of the four substances (A, B, C, or D) has the strongest intermolecular forces? (b) How do you know? B . (c) What is the normal boiling point of substance A? (d) What is the boiling point of C at high altitude, where the atmospheric pressure is 650 torr (e) Are any of these substances gases at 90"C? (You may assume the atmospheric pressure is I atm.) If yes, write letter(s) here: Temperature ( Say how you know:arrow_forwardWhy helium and hydrogen gases not liquefied at room temperature by applying very high pressure?arrow_forward
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