Problem 1E Problem 2E: Explain why it is necessary to hybridize atomic orbitals when applying the valence bond method-that... Problem 3E: Describe the molecular geometry of H2O suggested by each of the following methods: (a) Lewis theory;... Problem 4E: Describe the molecular geometry of NH2 suggested by each of the following methods: (a) Lewis theory;... Problem 5E: In which of the following, CO32-,SO2,CCl4,CO,NO3- , would you expect to find sp2 hybridization of... Problem 6E: In the manner of Example 11-1, describe the probable structure and bonding in (a) Hl; (b) BrCl; (c)... Problem 7E: For each of the following species, identify the central atom(s) and propose a hybridization scheme... Problem 8E: Propose a plausible Lewis structure, geometric structure, and hybridization scheme for the ONF... Problem 9E: Describe a hybridization scheme for the central Cl atom in the molecule CIF: that is consistent with... Problem 10E: Describe a hybridization scheme for the central S atom in the molecule SFO that is consistent with... Problem 11E: Match each of the following species with one of these hybridization schemes: sp, sp2 , sp3 , sp3d ,... Problem 12E: Propose a hybridization scheme to account for bonds formed by the central carbon atom in each of the... Problem 13E: Indicate which of the following molecules and ions are linear, which are planar, and which are... Problem 14E: In the manner of Figure 11-18, indicate the structures of the following molecules in terms of the... Problem 15E: Write Lewis structures for the following molecules, and then label each and bond. (a) HCN;(b) C2N2... Problem 16E: Represent bonding in the carbon dioxide molecule, CO2 by (a) a Lewis structure and (b) the... Problem 17E: Use the method of Figure 11-19 to represent bonding in each of the following molecules: (a) CCI4 ;... Problem 18E: Use the method of Figure 11-19 to represent bonding in each of the following ions: (a) NO3 ; (b) I3... Problem 19E: The molecular model below represents citric acid, an acidic component of citrus juices. Represent... Problem 20E: Malic is e common organic acid found in unripe apples and other fruit. the help of the molecular... Problem 21E: Shown below are ball-and-stick models. Describe hybridization and orbital-overlap schemes consistent... Problem 22E: Shown below are ban-and-stick models. Describe hybridization and orbital-overlap schemes consistent... Problem 23E Problem 24E: The structure of the molecule allene, CH2CCH2 , is shown here. Propose hybridization schemes for the... Problem 25E: Angelic acid, shown below, occurs in symbol root, a herb used as a stimulant. Represent the bonding... Problem 26E: Dimethylolpropionic acid, shown below, is used in the preparation of resins. Represent the bonding... Problem 27E: Explain the essential difference in how the valence-bond method and molecular orbital theory... Problem 28E: Describe the bond order of diatomic carbon, C2 , with Lewis theory and molecular orbital theory, and... Problem 29E Problem 30E: The paramagnetism of gaseous B2 has been established. Explain how this observation confirms that the... Problem 31E Problem 32E: Is it correct to say that when a diatomic molecule loses an electron, the bond energy always... Problem 33E: For the following pairs of molecular orbitals, indicate the one you expect to have the lower energy,... Problem 34E: For each of the species C2+,O2,F2+ , and NO+ ; a. Write the molecular orbital occupancy diagram (as... Problem 35E: Write plausible molecular orbital occupancy diagrams for the following heteronuclear diatomic... Problem 36E: We have used the term “isoelectronic” to refer to atoms with identical electron configurations. In... Problem 37E: Consider the molecules NO+ and N2+ and use molecular orbital theory to answer the following: Write... Problem 38E: Consider the molecules CO+ and CN- and use molecular orbital theory to answer the following Write... Problem 39E: Construct the molecular orbital diagram for CF. Would you expect the bond length of CF+ to be longer... Problem 40E: Construct the molecular orbital diagram for SrCl. Would you expect the bond length of SrCI+ to be... Problem 41E: Explain why the concept of delocalized molecular orbitals is essential to an understanding of... Problem 42E: Explain how it is possible to avoid the concept of resonance by using molecular orbital theory. Problem 43E: In which of the following molecules would you expect to find delocalized molecular orbitals'... Problem 44E: In which of the following ions would you expect to find delocalized molecular orbitals? Explain. (a)... Problem 45IAE: The Lewis structure of N2 indicates that the nitrogen-to-nitrogen bond is a triple covalent bond.... Problem 46IAE: Show that both the valence bond method and molecular orbital theory provide an explanation for the... Problem 47IAE: A group of spectroscopists believe that they have detected one of the following species: NeF, NeF+ ,... Problem 48IAE: Lewis theory is satisfactory to explain bonding in the ionic compound K2O1 , but it does not readily... Problem 49IAE: The compound potassium sesquoxide has the empirical formula K2O2 . Show that this compound tan be... Problem 50IAE: Draw a Lewis structure for the urea molecule, CO( NH2)2 , and predict its geometric shape with the... Problem 51IAE: Methyl nitrate, CH2NO2 , is used as a rocket propellant. The skeletal structure of the molecule is... Problem 52IAE: Fluorine nitrate, FONO2 , is an oxidizing agent used as a rocket propellant. A reference source... Problem 53IAE: Draw a Lewis structure(s) for the nitrite ion, NO2 . Then propose a bonding scheme to describe the ... Problem 54IAE: Think of the reaction shown here as involving the transfer of a fluoride ion from ClF2 to AsF5 , to... Problem 55IAE Problem 56IAE Problem 57IAE: The molecule formamide, HCONH2 , has the approximate bond angles H-C-O, 123o; H-C-N, 113o; N-C-O,... Problem 58IAE: Pyridine, C2H2N , is used in the synthesis of vitamins and drugs. The molecule can be thought of in... Problem 59IAE Problem 60IAE: The ion F2Cl is linear, but the ion F2Cl+ is bent. Describe hybridization schemes for the central CI... Problem 61IAE Problem 62IAE Problem 63IAE Problem 64IAE Problem 65IAE: Histidine, an essential amino acid, serves as a part of the active center in many enzymes. It is the... Problem 66IAE: The anion I42 is linear, and the anion I5 is V-shaped, with a 95° angle between the two arms of the... Problem 67IAE Problem 68IAE: A conjugated hydrocarbon has an alternation of double and single bonds. Draw the molecular orbitals... Problem 69IAE: An elusive intermediate of atmospheric reactions of HONO may be nitrosyl O-hydroxide, HOON.... Problem 70FP: Resonance energy is the difference in energy between a real molecule—a resonance hybrid—and its most... Problem 71FP: Furan, C4H4O , is a substance derivable from oat hulls, corn cobs, and other cellulosic waste. It is... Problem 72FP: As discussed in Are You Wondering 11-1, the sp hybrid orbitals are algebraic combinations of the s... Problem 73FP: In Chapter 10, we saw that electronegativity differences determine whether bond dipoles exist in a... Problem 74FP: Borazine, B2N2H2 is often referred to as inorganic benzene because of its similar structure. Like... Problem 75FP: Which of the following combinations of orbitals give rise to bonding molecular orbitals? For those... Problem 76FP Problem 77SAE Problem 78SAE Problem 79SAE: Explain the important distinctions between the terms in each of the following pairs: (a) and p... Problem 80SAE: A molecule in which sp2 hybrid orbitals are used by the central atom in forming covalent bonds is... Problem 81SAE Problem 82SAE: The hybridization scheme for the central atom includes a d orbital contribution in (a) I3- ; (b)... Problem 83SAE: Of the following, the species with a bond order of 1 is (a) H2+ ; (b) Li2 ; (c) He2 ; (d) H2 . Problem 84SAE: The hybridization scheme for Xe in XeF2 is (a) sp; (b) sp2 ; (c) sp2d ; (d) sp2d2 . Problem 85SAE: Delocalized molecular orbitals are found in (a) H2; (b) HS- ; (c) CH4 ; (d) CO32 Problem 86SAE Problem 87SAE: Why does the hybridization sp2d not account for bonding in the molecule BrF5 ? What hybridization... Problem 88SAE: What is the total number of (a) bonds and (b) p bonds in the molecule CH2NCO ? Problem 89SAE: Which of the following species are paramagnetic? (a) B2 ; (b) B2 ;(c) B2+. Which species has the... Problem 90SAE: Use the valence molecular orbital configuration to determine which of the following species is... Problem 91SAE: Use the valence molecular orbital configuration to determine which of the following species is... Problem 92SAE: Which of these diatomic molecules do you think has the greater bond energy, Li2 or C2 ? Explain? Problem 93SAE: For each of the following ions or molecules, decide whether the structure is best described by a... Problem 94SAE: Draw Lewis structures for the NO2 and NO2+ ions, and determine the geometry for each by using VSEPR... Problem 95SAE: In which of the following is the central atom sp hybridized? (a) BeCl2 ; (b) BCl2 ; (c) CCl2 ; (d)... Problem 96SAE Problem 97SAE: According to molecular orbital theory, the O22 ion has which of the following? (a) two unpaired... Problem 98SAE: What is the angle between the hybrid orbitals obtained by combining the 2s and two 2p orbitals of an... Problem 99SAE: Consider the molecule with the Lewis structure given below. How many and bonds are there? What is... Problem 100SAE: Construct a concept map that embodies the ideas of valence bond theory. Problem 101SAE Problem 102SAE: Construct a concept map that describes the interconnection between valence bond theory and molecular... format_list_bulleted