Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 10, Problem 5P
10-11 What important experiment did Wohler carry out in 1828?
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Use Figures 7.17 and 7.18 (or the
combined version in the lecture
worksheet) to answer this question.
Match the reaction to its MOST LIKELY
mechanism in the reactions in Figure 10-
1.
1
2
D Questi
[Choose ]
✓ [Choose ]
E2 with some SN2
SN1 with some E1
SN1
E2
E1
SN2 with some E2
SN2
MgBr
Mg
C,H,OC,H,
MgBr
o-CH
O *MgBr
C,H,OC,H,
+ CH,OH
H,O, H,SO,
O "MgBr
OH
Data
Glassware oven-dried, assembled, placed under nitrogen (balloon).
Materials: 10 mL anhydrous diethyl ether, 1.0 g Mg turnings. 4.5 mL bromobenzene. 10
mL more anhydrous diethyl ether. 2.5 ml methyl benzoate.
Approximate initiation time: 15 min. Stir 10 min after addition of methyl benzoate.
Transfer reaction mixture to 100 mL Erlenmeyer flask. Rinse reaction flask (2 x 20 mL
diethyl ether).
Acid quench solution: 25 mL 10 % aqueous sulfuric acid/15 g ice.
Saturated NaCI solution: used 20 mL
Hexanes: 20 mL
Isolated: 1.82 g white solid
What is the % yield of the reaction? What is the limiting reagent? Show complete
calculations for the theoretical and % yield calculations
11,12,13
Chapter 10 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 10.3 - Prob. 10.1QCCh. 10.4 - Prob. 10.2QCCh. 10.4 - Prob. 10.3QCCh. 10.4 - Prob. 10.4QCCh. 10.4 - Prob. 10.5QCCh. 10.4 - Prob. 10.6QCCh. 10 - Prob. 1PCh. 10 - Prob. 2PCh. 10 - 10-9 Is there any difference between vanillin made...Ch. 10 - Prob. 4P
Ch. 10 - 10-11 What important experiment did Wohler carry...Ch. 10 - Prob. 6PCh. 10 - Prob. 7PCh. 10 - Prob. 8PCh. 10 - 10-15 How many electrons are in the valence shell...Ch. 10 - 10-16 What is the relationship between the number...Ch. 10 - Prob. 11PCh. 10 - Prob. 12PCh. 10 - 10-19 Write Lewis structures for these ions. (a)...Ch. 10 - 10-20 Why are the following molecular formulas...Ch. 10 - 10-21 Explain how to use the valence-shell...Ch. 10 - 10-22 Suppose you forget to take into account the...Ch. 10 - Suppose you forget to take into account the...Ch. 10 - Prob. 18PCh. 10 - Prob. 19PCh. 10 - Prob. 20PCh. 10 - 10-27 What is meant by the term functional group?Ch. 10 - 10-28 List three reasons why functional groups are...Ch. 10 - Prob. 23PCh. 10 - Prob. 24PCh. 10 - Prob. 25PCh. 10 - 10-32 Draw a structural formula for the one...Ch. 10 - 10-33 What is the meaning of the term tertiary (...Ch. 10 - Prob. 28PCh. 10 - Draw structural formulas for each of the...Ch. 10 - 10-36 Draw structural formulas for the six ketones...Ch. 10 - 10-37 Draw structural formulas for the eight...Ch. 10 - Prob. 32PCh. 10 - 10-39 (Chemical Connections 10A) How was Taxol...Ch. 10 - Prob. 34PCh. 10 - Prob. 35PCh. 10 - Silicon is immediately below carbon in Group 4A of...Ch. 10 - 10-43 Phosphorus is immediately below nitrogen in...Ch. 10 - Draw the structure for a compound with the...Ch. 10 - 10-45 Draw structural formulas for the eight...Ch. 10 - Prob. 40PCh. 10 - 10-47 Which of these covalent bonds are polar, and...Ch. 10 - Of the bonds in Problem 10-47, which is the most...Ch. 10 - Prob. 43PCh. 10 - Prob. 44PCh. 10 - Following is a structural formula for naphthalene....Ch. 10 - Prob. 46PCh. 10 - Prob. 47PCh. 10 - Urea, (NH.,)2CO, is used in plastics and in fertil...Ch. 10 - Prob. 49PCh. 10 - Prob. 50PCh. 10 - Aspirin is prepared by the reaction of salicylic-...Ch. 10 - Following is the structural formula of acetamide....Ch. 10 - Prob. 53P
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- 10-39 (Chemical Connections 10A) How was Taxol discovered?arrow_forward10-22 Suppose you forget to take into account the presence of the unshared pair of electrons on nitrogen in the molecule NH3. What would you then predict for the H—N—H bond angles and the geometry (bond angles and shape) of ammonia?arrow_forward10-32 Draw a structural formula for the one tertiary (3°)alcohol with the molecular formula C4Hi0O.arrow_forward
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