Chemistry: Atoms First
2nd Edition
ISBN: 9780073511184
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 10, Problem 10.64QP
Interpretation Introduction
Interpretation: The change in enthalpy of given reaction has to be calculated in kilojoules.
Concept Introduction:
The change in enthalpy that is associated with the formation of one mole of a substance from its related elements being in standard state is called standard enthalpy of formation
(
The standard enthalpy of reaction is the enthalpy of reaction that takes place under standard conditions.
The equation for determining the standard enthalpies of compound and element can be given by,
To calculate: The overall change in enthalpy
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionChapter 10 Solutions
Chemistry: Atoms First
Ch. 10.1 - Prob. 10.1.1SRCh. 10.1 - Prob. 10.1.2SRCh. 10.1 - Prob. 10.1.3SRCh. 10.2 - Calculate the overall change in internal energy,...Ch. 10.2 - Calculate the change in total internal energy for...Ch. 10.2 - Calculate the magnitude of q for a system that...Ch. 10.2 - The diagram on the left shows a system before a...Ch. 10.2 - Prob. 10.2.1SRCh. 10.2 - Prob. 10.2.2SRCh. 10.3 - Determine the work done (in joules) when a sample...
Ch. 10.3 - Calculate the work done by or on the system during...Ch. 10.3 - (a) Against what external pressure must a gas...Ch. 10.3 - The diagram on the left shows a sample of gas...Ch. 10.3 - Given the thermochemical equation for...Ch. 10.3 - Calculate the solar energy required to produce...Ch. 10.3 - Prob. 3PPBCh. 10.3 - The diagrams represent systems before and after...Ch. 10.3 - Prob. 10.3.1SRCh. 10.3 - Prob. 10.3.2SRCh. 10.4 - Prob. 10.4WECh. 10.4 - Prob. 4PPACh. 10.4 - Prob. 4PPBCh. 10.4 - A metal pellet with a mass of 100.0 g. originally...Ch. 10.4 - What would the final temperature be if the pellet...Ch. 10.4 - Prob. 5PPBCh. 10.4 - Prob. 5PPCCh. 10.4 - A Famous Amos bite-sized chocolate chip cookie...Ch. 10.4 - A serving of Grape-Nuts cereal (5.80 g) is burned...Ch. 10.4 - Prob. 6PPBCh. 10.4 - Suppose an experiment to determine the energy...Ch. 10.4 - Prob. 10.4.1SRCh. 10.4 - Prob. 10.4.2SRCh. 10.4 - Prob. 10.4.3SRCh. 10.4 - Prob. 10.4.4SRCh. 10.5 - Given the following thermochemical equations....Ch. 10.5 - Use the thermochemical equations provided in...Ch. 10.5 - Prob. 10.5.1SRCh. 10.5 - Prob. 10.5.2SRCh. 10.6 - Prob. 10.8WECh. 10.6 - Using data from Appendix 2, calculate Hrn for...Ch. 10.6 - Prob. 8PPBCh. 10.6 - The diagrams represent a system before and after a...Ch. 10.6 - Given the following information, calculate the...Ch. 10.6 - Use the following data to calculate Hf for...Ch. 10.6 - Prob. 9PPBCh. 10.6 - The diagrams represent a system before and after a...Ch. 10.6 - Prob. 10.6.1SRCh. 10.6 - Prob. 10.6.2SRCh. 10.6 - Prob. 10.6.3SRCh. 10.7 - Use bond enthalpies from Table 10.4 to estimate...Ch. 10.7 - Use bond enthalpies from fable 10.4 to estimate...Ch. 10.7 - Prob. 10PPBCh. 10.7 - Prob. 10PPCCh. 10.7 - Prob. 10.7.1SRCh. 10.7 - Prob. 10.7.2SRCh. 10.7 - Prob. 10.7.3SRCh. 10.7 - Prob. 10.7.4SRCh. 10.8 - Prob. 10.11WECh. 10.8 - Prob. 11PPACh. 10.8 - The lattice energy of MgO is 3890 kJ/mol, and the...Ch. 10.8 - Prob. 11PPCCh. 10.8 - Prob. 10.8.1SRCh. 10.8 - Prob. 10.8.2SRCh. 10 - Define these terms: system, surroundings, thermal...Ch. 10 - What is heat? How does heat differ from thermal...Ch. 10 - Prob. 10.3QPCh. 10 - Define these terms: thermochemistry, exothermic...Ch. 10 - Prob. 10.5QPCh. 10 - Describe two exothermic processes and two...Ch. 10 - Decomposition reactions are usually endothermic,...Ch. 10 - On what law is the first law of thermodynamics...Ch. 10 - Explain what is meant by a state function. Give...Ch. 10 - Prob. 10.10QPCh. 10 - Prob. 10.11QPCh. 10 - Prob. 10.12QPCh. 10 - Prob. 10.13QPCh. 10 - Prob. 10.14QPCh. 10 - Prob. 10.15QPCh. 10 - Prob. 10.16QPCh. 10 - Define these terms: enthalpy and enthalpy of...Ch. 10 - Prob. 10.18QPCh. 10 - Prob. 10.19QPCh. 10 - Prob. 10.20QPCh. 10 - Prob. 10.21QPCh. 10 - A gas expands and does PV work on the surroundings...Ch. 10 - Prob. 10.23QPCh. 10 - Prob. 10.24QPCh. 10 - Consider the reaction at a certain temperature. If...Ch. 10 - Prob. 10.26QPCh. 10 - Prob. 10.27QPCh. 10 - Prob. 10.28QPCh. 10 - Prob. 10.1VCCh. 10 - Prob. 10.2VCCh. 10 - Prob. 10.3VCCh. 10 - Prob. 10.4VCCh. 10 - Prob. 10.5VCCh. 10 - Prob. 10.6VCCh. 10 - Prob. 10.7VCCh. 10 - Referring to the process depicted in Figure 10.10,...Ch. 10 - What is the difference between specific heat and...Ch. 10 - Define calorimetry and describe two commonly used...Ch. 10 - Prob. 10.31QPCh. 10 - Prob. 10.32QPCh. 10 - A sheet of gold weighing 10.0 g and at a...Ch. 10 - Prob. 10.34QPCh. 10 - A quantity of 2.00 102 mL of 0.862 M HC1 is mixed...Ch. 10 - Prob. 10.36QPCh. 10 - Prob. 10.37QPCh. 10 - Prob. 10.38QPCh. 10 - A 25.95-g sample of methanol at 35.6C is added to...Ch. 10 - Prob. 10.40QPCh. 10 - Prob. 10.41QPCh. 10 - Prob. 10.42QPCh. 10 - Prob. 10.43QPCh. 10 - Prob. 10.44QPCh. 10 - Prob. 10.45QPCh. 10 - Prob. 10.46QPCh. 10 - Prob. 10.47QPCh. 10 - Prob. 10.48QPCh. 10 - Prob. 10.49QPCh. 10 - Prob. 10.50QPCh. 10 - What is meant by the standard-state condition?Ch. 10 - How are the standard enthalpies of an element and...Ch. 10 - What is meant by the standard enthalpy of a...Ch. 10 - Write the equation for calculating the enthalpy of...Ch. 10 - Prob. 10.55QPCh. 10 - Prob. 10.56QPCh. 10 - Prob. 10.57QPCh. 10 - Calculate the heats of combustion for the...Ch. 10 - Calculate the heats of combustion for the...Ch. 10 - Prob. 10.60QPCh. 10 - Prob. 10.61QPCh. 10 - Prob. 10.62QPCh. 10 - From the standard enthalpies of formation,...Ch. 10 - Prob. 10.64QPCh. 10 - Prob. 10.65QPCh. 10 - Prob. 10.66QPCh. 10 - Which is the more negative quantity at 25C: Hf for...Ch. 10 - Prob. 10.68QPCh. 10 - Prob. 10.69QPCh. 10 - Prob. 10.70QPCh. 10 - Prob. 10.71QPCh. 10 - Prob. 10.72QPCh. 10 - Prob. 10.73QPCh. 10 - Prob. 10.74QPCh. 10 - Prob. 10.75QPCh. 10 - Prob. 10.76QPCh. 10 - For the reaction 2C2H6(g)+7O2(g)4CO2(g)+6H2O(g)...Ch. 10 - Prob. 10.78QPCh. 10 - Prob. 10.79QPCh. 10 - Prob. 10.9VCCh. 10 - Prob. 10.10VCCh. 10 - Prob. 10.11VCCh. 10 - Prob. 10.12VCCh. 10 - Explain how the lattice energy of an ionic...Ch. 10 - Specify which compound in each of the following...Ch. 10 - Prob. 10.82QPCh. 10 - Prob. 10.83QPCh. 10 - Prob. 10.84QPCh. 10 - Prob. 10.85QPCh. 10 - Prob. 10.86QPCh. 10 - Prob. 10.87QPCh. 10 - Hydrazine (N2H4) decomposes according to the...Ch. 10 - Prob. 10.89QPCh. 10 - Prob. 10.90QPCh. 10 - Prob. 10.91QPCh. 10 - Prob. 10.92QPCh. 10 - Prob. 10.93QPCh. 10 - Prob. 10.94QPCh. 10 - You are given the following data....Ch. 10 - Prob. 10.96QPCh. 10 - Prob. 10.97QPCh. 10 - Prob. 10.98QPCh. 10 - Prob. 10.99QPCh. 10 - Compare the heat produced by the complete...Ch. 10 - The so-called hydrogen economy is based on...Ch. 10 - Prob. 10.102QPCh. 10 - Prob. 10.103QPCh. 10 - Prob. 10.104QPCh. 10 - Prob. 10.105QPCh. 10 - Prob. 10.106QPCh. 10 - Prob. 10.107QPCh. 10 - Prob. 10.108QPCh. 10 - A certain gas initially at 0.050 L undergoes...Ch. 10 - Prob. 10.110QPCh. 10 - The first step in the industrial recovery of zinc...Ch. 10 - Calculate the standard enthalpy change for the...Ch. 10 - Portable hot packs are available for skiers and...Ch. 10 - Prob. 10.114QPCh. 10 - Prob. 10.115QPCh. 10 - Prob. 10.116QPCh. 10 - Prob. 10.117QPCh. 10 - Prob. 10.118QPCh. 10 - Prob. 10.119QPCh. 10 - Prob. 10.120QPCh. 10 - Prob. 10.121QPCh. 10 - Prob. 10.122QPCh. 10 - Prob. 10.123QPCh. 10 - Prob. 10.124QPCh. 10 - Prob. 10.125QPCh. 10 - Vinyl chloride (C2H3Cl) differs from ethylene...Ch. 10 - Prob. 10.127QPCh. 10 - Prob. 10.128QPCh. 10 - Prob. 10.129QPCh. 10 - Determine the standard enthalpy of formation of...Ch. 10 - Prob. 10.131QPCh. 10 - Prob. 10.132QPCh. 10 - Prob. 10.133QPCh. 10 - Prob. 10.134QPCh. 10 - Prob. 10.135QPCh. 10 - Prob. 10.136QPCh. 10 - Both glucose and fructose arc simple sugars with...Ch. 10 - About 6.0 1013 kg of CO2 is fixed (converted to...Ch. 10 - Experiments show that it takes 1656 kJ/mol to...Ch. 10 - From a thermochemical point of view, explain why a...Ch. 10 - Prob. 10.141QPCh. 10 - Prob. 10.142QPCh. 10 - Prob. 10.143QPCh. 10 - Prob. 10.144QPCh. 10 - Prob. 10.145QPCh. 10 - Prob. 10.146QPCh. 10 - Prob. 10.147QPCh. 10 - Prob. 10.148QPCh. 10 - A drivers manual states that the stopping distance...Ch. 10 - Prob. 10.150QPCh. 10 - Prob. 10.151QPCh. 10 - Prob. 10.152QPCh. 10 - When 1.034 g of naphthalene (C10H8), is burned in...Ch. 10 - Prob. 10.154QPCh. 10 - A gas company in Massachusetts charges 27 cents...Ch. 10 - Prob. 10.156QPCh. 10 - Prob. 10.157QPCh. 10 - According to information obtained from...Ch. 10 - Using data from Appendix 2, calculate the standard...Ch. 10 - Using data from Appendix 2, calculate the standard...Ch. 10 - Prob. 10.3KSPCh. 10 - Prob. 10.4KSP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The decomposition of ozone, O3, to oxygen, O2, is an exothermic reaction. What is the sign of q? If you were to touch a flask in which ozone is decomposing to oxygen, would you expect the flask to feel warm or cool?arrow_forwardAt 298 K, the standard enthalpies of formation for C2H2(g) and C6H6(l) are 227 kJ/mol and 49 kJ/mol, respectively. a. Calculate H for C6H6(l)3C2H2(g) b. Both acetylene (C2H2) and benzene (C6H6) can be used as fuels. Which compound would liberate more energy per gram when combusted in air?arrow_forwardThe formation of aluminum oxide from its elements is highly exothermic. If 2.70 g Al metal is burned in pure O2 to give A12O3, calculate how much thermal energy is evolved in the process (at constant pressure).arrow_forward
- Gasohol, a mixture of gasoline and ethanol, C2H5OH, is used as automobile fuel. The alcohol releases energy in a combustion reaction with O2. C2H5OH(l)+3O2(g)2CO2(g)+3H2O(l) If 0.115 g ethanol evolves 3.62 kJ when burned at constant pressure, calculate the combustion enthalpy for ethanol.arrow_forwardThe enthalpy change for the following reaction is 393.5 kJ. C(s,graphite)+O2(g)CO2(g) (a) Is energy released from or absorbed by the system in this reaction? (b) What quantities of reactants and products are assumed? (c) Predict the enthalpy change observed when 3.00 g carbon burns in an excess of oxygen.arrow_forwardAn industrial process for manufacturing sulfuric acid, H2SO4, uses hydrogen sulfide, H2S, from the purification of natural gas. In the first step of this process, the hydrogen sulfide is burned to obtain sulfur dioxide, SO2. 2H2S(g)+3O2(g)2H2O(l)+2SO2(g);H=1124kJ The density of sulfur dioxide at 25C and 1.00 atm is 2.62 g/L, and the molar heat capacity is 30.2 J/(mol C). (a) How much heat would be evolved in producing 1.00 L of SO2 at 25C and 1.00 atm? (b) Suppose heat from this reaction is used to heat 1.00 L of the SO2 from 25C to 500C for its use in the next step of the process. What percentage of the heat evolved is required for this?arrow_forward
- When 1.000 g of gaseous butane, C4H10, is burned at 25C and 1.00 atm pressure, H2O(l) and CO2(g) are formed with the evolution of 49.50 kJ of heat. a Calculate the molar enthalpy of formation of butane. (Use enthalpy of formation data for H2O and CO2.) b Gf of butane is 17.2 kJ/mol. What is G for the combustion of 1 mol butane? c From a and b, calculate S for the combustion of 1 mol butane.arrow_forwardCoal is used as a fuel in some electric-generating plants. Coal is a complex material, but for simplicity we may consider it to be a form of carbon. The energy that can be derived from a fuel is sometimes compared with the enthalpy of the combustion reaction: C(s)+O2(g)CO2(g) Calculate the standard enthalpy change for this reaction at 25C. Actually, only a fraction of the heat from this reaction is available to produce electric energy. In electric generating plants, this reaction is used to generate heat for a steam engine, which turns the generator. Basically the steam engine is a type of heat engine in which steam enters the engine at high temperature (Th), work is done, and the steam then exits at a lower temperature (Tl). The maximum fraction, f, of heat available to produce useful energy depends on the difference between these temperatures (expressed in kelvins), f = (Th Tl)/Th. What is the maximum heat energy available for useful work from the combustion of 1.00 mol of C(s) to CO2(g)? (Assume the value of H calculated at 25C for the heat obtained in the generator.) It is possible to consider more efficient ways to obtain useful energy from a fuel. For example, methane can be burned in a fuel cell to generate electricity directly. The maximum useful energy obtained in these cases is the maximum work, which equals the free-energy change. Calculate the standard free-energy change for the combustion of 1.00 mol of C(s) to CO2(g). Compare this value with the maximum obtained with the heat engine described here.arrow_forwardThe process of dissolving ammonium nitrate, NH4NO3, in water is an endothermic process. What is the sign of q? If you were to add some ammonium nitrate to water in a flask, would you expect the flask to feel warm or cool?arrow_forward
- The standard enthalpies of formation of KNO3(s) and K2S(s) are 494.6 kJ/mol and 376.6 kJ/mol, respectively. a. Determine the standard enthalpy change for the reaction of black powder according to the balanced equation on the previous page. b. Determine the enthalpy change that occurs when 1.00 g of black powder decomposes according to the stoichiometry of the balanced equation above. (Even though black powder is a mixture, assume that we can designate 1 mol of black powder as consisting of exactly 2 mol of KNO3, 3 mol of C, and 1 mol of S.)arrow_forwardThe thermochemical equation for the burning of methane, the main component of natural gas, is CH4(g)+2O2(g)CO2(g)+2H2O(l)H=890kJ (a) Is this reaction endothermic or exothermic? (b) What quantities of reactants and products are assumed if H = 890 kJ? (c) What is the enthalpy change when 1.00 g methane burns in an excess of oxygen?arrow_forwardThe combustion of methane can be represented as follows: a. Use the information given above to determine the value of H for the combustion of methane to form CO2(g) and 2H2O(l). b. What is Hf for an element in its standard state? Why is this? Use the figure above to support your answer. c. How does H for the reaction CO2(g) + 2H2O (1) CH4(g) + O2(g) compare to that of the combustion of methane? Why is this?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Calorimetry Concept, Examples and Thermochemistry | How to Pass Chemistry; Author: Melissa Maribel;https://www.youtube.com/watch?v=nSh29lUGj00;License: Standard YouTube License, CC-BY