Concept explainers
(a)
Interpretation:
The solvent with greater solubility in water has to be selected.
Concept Introduction:
Hydrogen bonding: The attractive interactions between hydrogen atom bonded to an atom of high electronegativity (most commonly O or N) and a lone pair of electrons on another atom of electrons on another atom of high electronegativity (again, most commonly O or N).
Solubility: Interaction of polar compound with water occurs by hydrogen bonding formation between compounds and water.
Hydrogen-bond donors: The hydrogen atom that is attached to the high electronegative atom participates in hydrogen bond. Thus, that Hydrogen atom is known as hydrogen-bond donors.
Hydrogen-bond acceptor: The atom (high electronegative atom with lone pairs) to which the hydrogen atom is participated in hydrogen bond.
(b)
Interpretation:
The solvent with greater solubility in water has to be selected.
Concept Introduction:
Hydrogen bonding: The attractive interactions between hydrogen atom bonded to an atom of high electronegativity (most commonly O or N) and a lone pair of electrons on another atom of electrons on another atom of high electronegativity (again, most commonly O or N).
Solubility: Interaction of polar compound with water occurs by hydrogen bonding formation between compounds and water.
Hydrogen-bond donors: The hydrogen atom that is attached to the high electronegative atom participates in hydrogen bond. Thus, that Hydrogen atom is known as hydrogen-bond donors.
Hydrogen-bond acceptor: The atom (high electronegative atom with lone pairs) to which the hydrogen atom is participated in hydrogen bond.
(c)
Interpretation:
The solvent with greater solubility in water has to be selected.
Concept Introduction:
Hydrogen bonding: The attractive interactions between hydrogen atom bonded to an atom of high electronegativity (most commonly O or N) and a lone pair of electrons on another atom of electrons on another atom of high electronegativity (again, most commonly O or N).
Solubility: Interaction of polar compound with water occurs by hydrogen bonding formation between compounds and water.
Hydrogen-bond donors: The hydrogen atom that is attached to the high electronegative atom participates in hydrogen bond. Thus, that Hydrogen atom is known as hydrogen-bond donors.
Hydrogen-bond acceptor: The atom (high electronegative atom with lone pairs) to which the hydrogen atom is participated in hydrogen bond.
(d)
Interpretation:
The solvent with greater solubility in water has to be selected.
Concept Introduction:
Hydrogen bonding: The attractive interactions between hydrogen atom bonded to an atom of high electronegativity (most commonly O or N) and a lone pair of electrons on another atom of electrons on another atom of high electronegativity (again, most commonly O or N).
Solubility: Interaction of polar compound with water occurs by hydrogen bonding formation between compounds and water.
Hydrogen-bond donors: The hydrogen atom that is attached to the high electronegative atom participates in hydrogen bond. Thus, that Hydrogen atom is known as hydrogen-bond donors.
Hydrogen-bond acceptor: The atom (high electronegative atom with lone pairs) to which the hydrogen atom is participated in hydrogen bond.
(e)
Interpretation:
The solvent with greater solubility in water has to be selected.
Concept Introduction:
Hydrogen bonding: The attractive interactions between hydrogen atom bonded to an atom of high electronegativity (most commonly O or N) and a lone pair of electrons on another atom of electrons on another atom of high electronegativity (again, most commonly O or N).
Solubility: Interaction of polar compound with water occurs by hydrogen bonding formation between compounds and water.
Hydrogen-bond donors: The hydrogen atom that is attached to the high electronegative atom participates in hydrogen bond. Thus, that Hydrogen atom is known as hydrogen-bond donors.
Hydrogen-bond acceptor: The atom (high electronegative atom with lone pairs) to which the hydrogen atom is participated in hydrogen bond.
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Chapter 10 Solutions
Organic Chemistry
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- (b) Draw the structural formula for each of the following compounds. (i) 2,2,3-trimethylpentan-3-ol(ii) 2-methyl-3-phenylbut-2-enal(iii) 5-chloro-2-methylheptan-3-olarrow_forwardEthanol (CH3CH2OH) and dimethyl ether (CH3OCH3) are constitutional isomers. (a) Predict which of the two has the higher boiling point. (b) Predict which of the two is more soluble in water.arrow_forward4. Which of the following has a higher boiling point? Explain your answer:(a) 2-propanol or 2-butanol(b) Dimethyl ether or ethanolarrow_forward
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