Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Question
Chapter 1, Problem 35P
Interpretation Introduction
Interpretation:
By considering the given pairs of structural isomers, it is to be identified whether they represent constitutional isomers of each other, non-isomeric compounds, or the same compound.
Concept introduction:
Compounds having different structures but the same molecular formula are known as isomers.
Structural isomerism or constitutional isomerism is shown by different compounds having difference in the sequence of atoms but having the same molecular formula.
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Write condensed formulae for a real example of a pair of different substances which have the same molecular formula but different molecular structures. Such molecules are known as
structural isomers.
Write the systematic name of each organic molecule:
structure
CH3-CH2-CH2-NH-C-CH2 —CH 2 —CH 2 —CH3
CH3-CH2-CH2-N-C-CH2-CH3
CH3
○
CH3-CH2-CH₂ — CH₂ · -C-N-CH2-CH2-CH3
CH2-CH3
name
☐
Functional Groups
FUNCTIONAL GROUPS IN ORGANIC CHEMISTRY
FUNCTIONAL GROUPS ARE GROUPS OF ATOMS IN ORGANIC MOLECULES THAT ARE RESPONSIBLE FOR THE CHARACTERISTIC CHEMICAL REACTIONS OF THOSE MOLECULES.
IN THE GENERAL FORMULAE SHOWN BELOW FOR EACH FUNCTIONAL GROUP, 'R' REPRESENTS THE REST OF THE MOLECULE, AND X REPRESENTS ANY HALOGEN ATOM.
HALOGEN HETEROATOMICS CARBONYL COMPOUNDS
HYDROCARBONS
SIMPLE OXYGEN HETEROATOMICS
NITROGEN-BASED SULFUR-BASED
AROMATIC
R-OH
0-R₂
R-X
ALKANE
ALKENE
ALKYNE
EPOXIDE
Noming one
egethane
Noming ene
egethene
Noming ye
ALCOHOL
Naming-of
egethanol
ETHER
Naming-ory ane
eg. methoxyethane
Naming ene oxide
egethene oxide
HALOALKANE
Naming: holo
eg. chloroethane
eg ethyne
ÅR
(PNP)
-Å-X
OR₂
ALDEHYDE
Naming al
eg ethanal
KETONE
Naming: one
eg propanone
CARBOXYLIC ACID
Naming oic acid
eg, ethanoic acid
ACID ANHYDRIDE
Noming oic anhydride
eg. ethanoic anhydride
ESTER
Naming late
eg. ethyl ethanoate
AMIDE
Naming: amide
eg. ethanamide
ACYL HALIDE
Naming ay halide
eg…
Chapter 1 Solutions
Organic Chemistry
Ch. 1 - Prob. 1PPCh. 1 - Prob. 2PPCh. 1 - Prob. 3PPCh. 1 - Prob. 4PPCh. 1 - Prob. 5PPCh. 1 - Prob. 6PPCh. 1 - Prob. 7PPCh. 1 - Prob. 8PPCh. 1 - Prob. 9PPCh. 1 - Prob. 10PP
Ch. 1 - Prob. 11PPCh. 1 - Prob. 12PPCh. 1 - Prob. 13PPCh. 1 - Prob. 14PPCh. 1 - Prob. 15PPCh. 1 - Prob. 16PPCh. 1 - Prob. 17PPCh. 1 - Prob. 18PPCh. 1 - Prob. 19PPCh. 1 - Prob. 20PPCh. 1 - Prob. 21PPCh. 1 - Practice Problem 1.22 Which of the following...Ch. 1 - Prob. 23PPCh. 1 - Prob. 24PPCh. 1 - Practice Problem 1.25
What do the bond angles of...Ch. 1 - Prob. 26PPCh. 1 - Practice Problem 1.27
Use VSEPR theory to predict...Ch. 1 - Practice Problem 1.28 Predict the bond angles of...Ch. 1 - 1.29 Which of the following ions possess the...Ch. 1 - 1.30 Write a Lewis structure for each of the...Ch. 1 - Prob. 31PCh. 1 - Add any unshared electrons to give each element an...Ch. 1 - Prob. 33PCh. 1 - What is the molecular formula for each of the...Ch. 1 - Prob. 35PCh. 1 - Prob. 36PCh. 1 - 1.37 Write bond-line formulas for all of the...Ch. 1 - Prob. 38PCh. 1 - Prob. 39PCh. 1 - Prob. 40PCh. 1 - Prob. 41PCh. 1 - (a) Cyanic acid (HOCN) and isocyanic acid (HN=C=O)...Ch. 1 - Consider a chemical species (either a molecule or...Ch. 1 - 1.44 Consider a chemical species like the one in...Ch. 1 - 1.45 Consider another chemical species like the...Ch. 1 - Draw a three-dimensional orbital representation...Ch. 1 - Ozone (O3) is found in the upper atmosphere where...Ch. 1 - Write resonance structures for the azide ion, N3....Ch. 1 - Write structural formulas of the type indicated:...Ch. 1 - Prob. 50PCh. 1 - 1.51 In Chapter 15 we shall learn how the...Ch. 1 - Prob. 52PCh. 1 - (a) Consider a carbon atom in its ground state....Ch. 1 - Open computer molecular models for dimethyl ether,...Ch. 1 - Boron is a group IIIA element. Open the molecular...Ch. 1 - 1.56 There are two contributing resonance...Ch. 1 - Prob. 1LGPCh. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Consider the compound with the following condensed...Ch. 1 - Prob. 7LGPCh. 1 - Prob. 8LGP
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Why does the number of known compounds of carbon far exceeds the number of compounds of all the other elements combined? Select the correct response O Carbon cannot form multiple combinations of single, double, and triple bonds with itself and with other elements Carbon atorns have the special property of being able to bond together to form chains, rings, spheres, and sheets of almost any size O Carbon can fom multiple combinations with itself but not with other elements. Carbon is a small atom that can form more than four bondsarrow_forwardSelect the statement that is correct about these two molecules (molecule on the left vs. molecúle on the right). Note: if your images appear stacked on top of each other, please expand your browser window. If it still appears stacked then the top molecule is the "left" one and the bottom molecule is the "right" one. но но The molecule on the left has fewer carbon atoms than the molecule on the right The molecule on the left has more hydrogens than the molecule on the right The molecule on the left has fewer hydrogens than the molecule on the right O The molecule on the left has more carbon atoms than the molecule on the rightarrow_forwardV Are these two compounds constitutional isomers? Explain your reasoning. ie Match the words in the left column to the appropriate blanks in the sentences on the right.. are not different are the same The two compounds have They Submit Previous Answers Request Answer isomers. molecular formulas and Reset Help chemical structuresarrow_forward
- For each of the organic molecules listed below write the name and condensed formular in the respective space below.arrow_forwardO REPRESENTATIONS OF ORGANIC MOLECULES Identifying organic functional groups in simple structures Name the functional group shown in each molecule below. The first answer has been filled in for you. molecule HIC C- CH3 CH3- CH3 1 CH–NH= CH3 CH3 I CH3- -CHOIC- O CH3 0=C- CH₂ - CH₂ 1 OH functional group alkynearrow_forwardFill in the boxes with the names of the class of compounds.arrow_forward
- Assignment Identify the functional group and give the different chemical formula of the compound by filling up the table below. Submit your answer on or before the date that will be posted. Functional Structural Formula Condensed SF Condensed Formula Bond-line or Group/ (SF) Line-angle Molecular Formula Formula 1 3 CH3 4 5 CH3-C-CH-CH-CH3 CH3 6 8 9 10 OH-Ö-(CH2)4-C 7 11 13 14 15 12 16 18 19 20 CH3 17 CH3-C-CH2CH2-C-NH-CH3 CH3 21 23 24 25 -NH. 22arrow_forwardChemistry wireframe; labels Which of the following represent structural isomers of the molecule shown in the model? Choose all that apply. CH₂ CHCHCHCHC CH₂-CH-CH₂-CH₂-CH₂-CH₂ CH₂ H₂-C-CH₂-CH₂ CH3 CH₂-CH₂ CH₂-CH₂-CH-CH₂-CH₂ CH₂ CH₂-C-CH₂-CH₂-CH₂ CH CH3 CH CH-CH-C-CH-CH CH₂arrow_forwardSelect all of the following elements that are expected to form compounds with the molecular formula or formula unit consisting of two atoms of one element for every one atom of the other, i.e. AB2 or A2B. O B& H V Ca & Si C & CI Na & S Ca & CIarrow_forward
- Name the following molecular compounds using the prefix system. N2O5arrow_forwardWhich of the interpretations provided below best represents the meaning generated by the phrase structure representation below? D the NP N detective S examined D the VP NP A N giant hamster P with PP NP N binoculars Neither of these is a possible interpretation that can be generated from this representation. Z The examination was done using binoculars. The examination involved a giant hamster that had binoculars. They are both possible interpretations that can be generated from this representation.arrow_forward
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