Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 1, Problem 26QAP
A listing of a house for sale states that there are 5bedrooms, 4000 ft2 of living area, and a living room with dimensions
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(a) The following synthesis of the molecule shown in the circle has a major problem. What is this problem? (2
pts)
1) HBr
(no peroxides)
2) H-
NaNH2
Br
3) NaNH,
4) CH3Br
5) H2, Pd
(b) Starting with the molecule shown below and any other materials with two carbons or less, write out an
alternate synthesis of the circled molecule. More than one step is needed. Indicate the reagent(s) and the major
product in all the steps in your synthesis. (5 pts)
2024 Fall Term (1) Organic Chemistry 1 (Lec)
CHEM 22204 02[6386] (Hunter College)
(c) Using the same starting material as in part (b) and any other materials win two carpons or less, write out
syntheses of the circled molecules shown below. More than one step is needed in each case. Indicate the
reagent(s) and the major product in all the steps in your synthesis. You may use reactions and products from
your synthesis in part (b). (5 pts)
alt
ons for
Free Response Questions
FRQ 1:
0/5
To spectrophotometrically determine the mass percent of cobalt in an ore containing cobalt and
some inert materials, solutions with known [Co?) are prepared and absorbance of each of the
solutions is measured at the wavelength of optimum absorbance. The data are used to create a
calibration plot, shown below.
0.90-
0.80-
0.70
0.60
0.50
0.40-
0.30
0.20-
0.10-
0.00-
0.005
0.010
Concentration (M)
0.015
A 0.630 g sample of the ore is completely dissolved in concentrated HNO3(aq). The mixture is diluted
with water to a final volume of 50.00 ml. Assume that all the cobalt in the ore sample is converted to
Co2+(aq).
a. What is the [Co2] in the solution if the absorbance of a sample of the solution is 0.74?
13
✗
b. Calculate the number of moles of Co2+(aq) in the 50.00 mL solution.
0.008 mols Co
Please correct answer and don't used hand raiting
Chapter 1 Solutions
Chemistry: Principles and Reactions
Ch. 1 - Classify each of the following as element,...Ch. 1 - Classify each of the following as element,...Ch. 1 - Classify the following as solution or...Ch. 1 - Classify the following as solution or...Ch. 1 - Prob. 5QAPCh. 1 - Prob. 6QAPCh. 1 - Write the symbol for the following elements. (a)...Ch. 1 - Prob. 8QAPCh. 1 - Write the name of the element represented by the...Ch. 1 - Write the name of the element represented by the...
Ch. 1 - What instrument would you use to determine (a) the...Ch. 1 - What instrument would you use to (a) measure the...Ch. 1 - A glass of lukewarm milk is suggested for people...Ch. 1 - A recipe for apple pie calls for a preheated 350F...Ch. 1 - Gallium is one of the few metals that can melt at...Ch. 1 - Computers are not supposed to be in very warm...Ch. 1 - How many significant figures are in each of the...Ch. 1 - How many significant figures are there in each of...Ch. 1 - Round off the following quantities to the...Ch. 1 - Round off the following quantities to the...Ch. 1 - Prob. 21QAPCh. 1 - Prob. 22QAPCh. 1 - Which of the following statements use only exact...Ch. 1 - Which of the following statements use only exact...Ch. 1 - A basketball game at the University of...Ch. 1 - A listing of a house for sale states that there...Ch. 1 - Calculate the following to the correct number of...Ch. 1 - Perform the indicated calculations. Write your...Ch. 1 - Prob. 29QAPCh. 1 - The volume of a square pyramid is (1/3)Bh where B...Ch. 1 - Write the appropriate symbol in the blank (,,or=)....Ch. 1 - Write the appropriate symbol in the blank (,,or=)....Ch. 1 - Convert 22.3 mL to (a) liters (b) in3 (c) quartsCh. 1 - Convert 0.2156 L to (a) mL (b) in3 (c) quartsCh. 1 - The height of a horse is usually measured in...Ch. 1 - At sea, distances are measured in nautical miles...Ch. 1 - The unit of land measure in the English system is...Ch. 1 - A gasoline station in Manila, Philippines, charges...Ch. 1 - A lap in most tracks in the United States is 0.25...Ch. 1 - Cholesterol in blood is measured in milligrams of...Ch. 1 - Prob. 41QAPCh. 1 - The area of the 48 contiguous states is 3.02106...Ch. 1 - Prob. 43QAPCh. 1 - In the old pharmaceutical system of measurements,...Ch. 1 - The cup is a measure of volume widely used in...Ch. 1 - The egg whites from four large eggs occupy a...Ch. 1 - A metal slug weighing 25.17 g is added to a flask...Ch. 1 - A solid with an irregular shape and a mass of 11.3...Ch. 1 - A waterbed filled with water has the dimensions...Ch. 1 - Wire is often sold in pound spools according to...Ch. 1 - Air is 21% oxygen by volume. Oxygen has a density...Ch. 1 - The unit for density found in many density tables...Ch. 1 - Magnesium sulfate (MgSO4) has a solubility of 38.9...Ch. 1 - Potassium sulfate has a solubility of 15 g/ 100 g...Ch. 1 - Sodium bicarbonate (baking soda) is commonly use...Ch. 1 - Magnesium chloride is an important coagulant used...Ch. 1 - The solubility of lead nitrate at 100C is 140.0...Ch. 1 - Radiation exposure to human beings is usually...Ch. 1 - The following data refer to the element...Ch. 1 - A supersaturated sugar solution (650.0 g sugar in...Ch. 1 - The density of wind-packed snow is estimated to be...Ch. 1 - The dimensions of aluminum foil in a box for sale...Ch. 1 - The Kohinoor Diamond (d=3.51g/cm3) is 108 carats....Ch. 1 - A pycnometer is a device used to measure density....Ch. 1 - Prob. 65QAPCh. 1 - Label each of the properties of iodine as...Ch. 1 - How do you distinguish (a) chemical properties...Ch. 1 - What is the difference between (a) mass and...Ch. 1 - Mercury, ethyl alcohol, and lead are poured into a...Ch. 1 - How many significant figures are there in the...Ch. 1 - Consider the following solubility graph. (a) At...Ch. 1 - Given the following solubility curves, answer the...Ch. 1 - A Different civilization on a distant planet has...Ch. 1 - At what point is the temperature in F exactly...Ch. 1 - Prob. 75QAPCh. 1 - A laboratory experiment requires 12.0 g of...Ch. 1 - An average adult breathes about 8.50103 L of air...Ch. 1 - A student determines the density of a metal by...
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- Closo-boranes and arachno-boranes are structures that exhibit B-B, B-H-B, and B-H bonds. Correct?arrow_forwardIndicate why boron hydrides cannot form large linear or planar structures.arrow_forwardNido-boranes are structures with the molecular formula BnHn+4 that exhibit B-B, B-H-B and B-H bonds. Correct?arrow_forward
- 8:07 AM Wed Dec 18 Final Exam 2024 copy Home Insert Draw Page Layout Formulas Data Review AA 田 General A G fx Alexis Cozort ☑ ⚫ 61% A B D E F H K M N P R S T U 3+ 10 125 mM that yielded peak heights of Aa = 9 1-(a)A sample solution was examined under XRF to quantify the analyte Ce³+. Find the response factor F, when standardized concentration of analyte [Ce³+]A = concentration of internal standard S i.e. [In³*]s = 151 mM was spiked with standardized 1600 and As = 3015 respectively? 11 12 (i)Define F, F = Aa As [A] [S] + X 13 (*Define with variables) 4000 14 15 (ii)Calculate F, F = numeral (You will use the F value in part 1-(b) below) As 16 (*Calculate with numerals) 17 18 1-(b)To determine the unknown conc of analyte [Ce³+], a volume of 15 mL of internal standard S having a concentration [In³+]s = 0.264 M 19 20 was added to 45 mL of unknown, and the mixture was diluted to 100 mL in a volumetric flask. XRF analysis yielded a spectrum, Figure-1, where peak heights A and As are…arrow_forwardAll structural types of Boron hydrides exhibit B-B, B-H-B and B-H bonds. Correct?arrow_forwardN-nitrosodimethylamine (NDMA) is a suspected carcinogen that can form via reactions between dimethylamine (DMA) and monochloramine (NH2Cl). The relevant elementary reactions and the corresponding rate constants are as shown below. Reaction Rate constant (M¹s¹) DMA + NH2Cl = DMCA + NH3 k =1.4×10-1, kr = 5.83×10-3 1.28×10-3 DMA + NH2Cl → UDMH UDMH + NH2Cl → NDMA -> 1.11×10-1 If the initial concentrations of DMA and NH2Cl are given, you should be able to predict the concentrations of all species at any given reaction time. Please write down the rate equations for DMA, NH2C1, DMCA, UDMH and NDMA.arrow_forward
- You wish to add enough NaOCl (sodium hypochlorite) to a 150 m³ swimming pool to provide a dose of 5.0 mg/L TOTOCI as Cl2. (a) How much NaOCI (kg) should you add? (Note: the equivalent weight of NaOCl is based on the reaction: NaOCl + 2H + 2 e→CI + Na +H₂O.) (10 pts) (atomic weight: Na 23, O 16, C1 35.5) (b) The pH in the pool after the NaOCl addition is 8.67. To improve disinfection, you want at least 90% of the TOTOCI to be in the form of HOCI (pKa 7.53). Assuming that HOCI/OCI is the only weak acid/base group in solution, what volume (L) of 10 N HCl must be added to achieve the goal? (15 pts) Note that part a) is a bonus question for undergraduate students. If you decide not to work on this part of the question, you many assume TOTOCI = 7×10-5 M for part b).arrow_forwardPart A 2K(s)+Cl2(g)+2KCI(s) Express your answer in grams to three significant figures. Part B 2K(s)+Br2(1)→2KBr(s) Express your answer in grams to three significant figures. Part C 4Cr(s)+302(g)+2Cr2O3(s) Express your answer in grams to three significant figures. Part D 2Sr(s)+O2(g) 2SrO(s) Express your answer in grams to three significant figures. Thank you!arrow_forwardA solution contains 10-28 M TOTCO3 and is at pH 8.1. How much HCI (moles per liter of solution) is required to titrate the solution to pH 7.0? (H2CO3: pKa1=6.35, pKa2=10.33)arrow_forward
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