Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 1, Problem 1C.9E
Interpretation Introduction

Interpretation:

Using the given conditions the Boyle temperature for carbon disulphide CS2 has to be calculated.

Concept introduction:

Ideal gas equation,

PV=nRTWhere,P:PressureV:Volumen:NumberofmolesR:GasconstantT:Temperature

Virial equation: This is an equation of state for real gases in Z as a power series in terms of 1Vm for a pure gas.

Z=PVmRT=1+BVm+CVm2+.....

B and C are the second and third virial coefficients and both are temperature dependent.

Van der Waals equation:

The deviation from ideal gas law was accounted using two constants, a and b and was given by an equation called van der Waals equation which is similar to ideal gas law as follows,

   (P+n2aV2)(v-nb)=nRT

  Where,

a and b are constants

P is the pressure

V is the volume

T is the temperature

R is molar gas constant

n is the mole

Using van der Waal’s equation, the pressure can be determined as,

P=nRTVnba(nV)2

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