Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 1, Problem 1C.4E
Interpretation Introduction

Interpretation:

The given molar volume of oxygen has 3.90dm3mol1 at 10bar and 200oC. The second virial coefficient of oxygen at this temperature has to be calculated.

Concept Introduction:

Van der Waals equation:

The deviation from ideal gas law was accounted using two constants, a and b and was given by an equation called van der Waals equation which is similar to ideal gas law as follows,

  (P+n2aV2)(V-nb) = nRT

Where,

(a) and (b) are constantsP= is the pressureV= is the volumeT= is the temperatureR= is molar gas constantn= is the mole

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