Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 1, Problem 1B.5E
Interpretation Introduction

Interpretation:

Pressure at which the mean free path of argon at 25°C become comparable to the diameter of a 1.0dm3 vessel that contains it, has to be calculated.

Concept introduction:

The average distance travelled by a molecule between the collisions is called the mean free path.  The mean free path is calculated by the formula,

    λ=kTσp

    where,λ=meanfreepathP=Pressureσ=collision crosssection of the moleculesT=Temperature

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