Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Question
Chapter 1, Problem 1.11P
Interpretation Introduction
(a)
Interpretation: The second resonance structure for the given species is to be drawn with the help of curved arrows.
Concept Introduction: Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.
Interpretation Introduction
(b)
Interpretation: The second resonance structure for the given species is to be drawn with the help of curved arrows.
Concept Introduction: Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.
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Follow the curved arrows and draw a second resonance structure for each species.
a. CH,-NEN:
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NH2
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d.
CH
Follow the curved arrows to draw a second resonance structure for each
species.
a.
b. :o:
C.
-NEN:
NH₂
b. Write the structure showing lone pairs of electrons and draw all possible resonance structures
for
Use curved arrows to track the movement of electron pairs converting one
resonance contributor to the other.:
c. Write the structure showing lone pairs of electrons for the molecule below and draw all
. Use curved arrows to track the
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movement of a pair of electrons.
Chapter 1 Solutions
Organic Chemistry
Ch. 1 - While the most common isotope of nitrogen has a...Ch. 1 - Label each bond in the following compounds as...Ch. 1 - How many covalent bonds are predicted for each...Ch. 1 - Draw a valid Lewis structure for each species. a....Ch. 1 - Draw an acceptable Lewis structure for each...Ch. 1 - Prob. 1.6PCh. 1 - Draw a Lewis structure for each ion. a. CH3Ob....Ch. 1 - Draw Lewis structures for each molecular formula....Ch. 1 - Prob. 1.9PCh. 1 - Prob. 1.10P
Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Draw a second resonance structure for each...Ch. 1 - Prob. 1.14PCh. 1 - Draw a second resonance structure for nitrous...Ch. 1 - Prob. 1.16PCh. 1 - Prob. 1.17PCh. 1 - Prob. 1.18PCh. 1 - Prob. 1.19PCh. 1 - Prob. 1.20PCh. 1 - Simplify each condensed structure by using...Ch. 1 - Prob. 1.22PCh. 1 - Prob. 1.23PCh. 1 - Convert each skeletal structure to a complete...Ch. 1 - Draw in all hydrogens and lone pairs on the...Ch. 1 - Prob. 1.26PCh. 1 - What orbitals are used to form each of the CC, and...Ch. 1 - What orbitals are used to form each bond in the...Ch. 1 - Determine the hybridization around the highlighted...Ch. 1 - Classify each bond in the following molecules as ...Ch. 1 - Prob. 1.31PCh. 1 - Rank the following atoms in order of increasing...Ch. 1 - Prob. 1.33PCh. 1 - Prob. 1.34PCh. 1 - Provide the following information about...Ch. 1 - Use the ball-and-stick model to answer each...Ch. 1 - Citric acid is responsible for the tartness of...Ch. 1 - Zingerone gives ginger its pungent taste. a.What...Ch. 1 - Two radioactive isotopes of iodine used for the...Ch. 1 - Prob. 1.40PCh. 1 - Assign formal charges to each carbon atom in the...Ch. 1 - Assign formal charges to each N and O atom in the...Ch. 1 - Draw one valid Lewis structure for each compound....Ch. 1 - Prob. 1.44PCh. 1 - Prob. 1.45PCh. 1 - Prob. 1.46PCh. 1 - Draw all possible isomers for each molecular...Ch. 1 - 1.45 Draw Lewis structures for the nine isomers...Ch. 1 - Prob. 1.49PCh. 1 - Prob. 1.50PCh. 1 - Prob. 1.51PCh. 1 - Prob. 1.52PCh. 1 - Prob. 1.53PCh. 1 - Prob. 1.54PCh. 1 - Draw all reasonable resonance structures for each...Ch. 1 - Prob. 1.56PCh. 1 - Rank the resonance structures in each group in...Ch. 1 - 1.56 Consider the compounds and ions with curved...Ch. 1 - 1.57 Predict all bond angles in each...Ch. 1 - Predict the geometry around each indicated atom....Ch. 1 - Prob. 1.61PCh. 1 - Prob. 1.62PCh. 1 - Draw in all the carbon and hydrogen atoms in each...Ch. 1 - Prob. 1.64PCh. 1 - Prob. 1.65PCh. 1 - Prob. 1.66PCh. 1 - Prob. 1.67PCh. 1 - Each of the following condensed or skeletal...Ch. 1 - Prob. 1.69PCh. 1 - Prob. 1.70PCh. 1 - Prob. 1.71PCh. 1 - Prob. 1.72PCh. 1 - Prob. 1.73PCh. 1 - Prob. 1.74PCh. 1 - Two useful organic compounds that contain Cl atoms...Ch. 1 - Use the symbols + and to indicate the polarity of...Ch. 1 - Label the polar bonds in each molecule. Indicate...Ch. 1 - Answer the following questions about acetonitrile...Ch. 1 - Prob. 1.79PCh. 1 - The principles of this chapter can be applied to...Ch. 1 -
a. What is the hybridization of each N atom in...Ch. 1 - 1.77 Stalevo is the trade name for a medication...Ch. 1 - 1.78 and are two highly reactive carbon...Ch. 1 - 1.79 The N atom in (acetamide) is hybridized,...Ch. 1 - Prob. 1.85PCh. 1 - Prob. 1.86PCh. 1 - Prob. 1.87PCh. 1 - Prob. 1.88PCh. 1 - Prob. 1.89PCh. 1 - Prob. 1.90P
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- Need help drawing any other resonance structures of A.arrow_forwardFollow the curved arrows to draw a second resonance structure for eachspecies.arrow_forwardO REPRESENTATIONS OF ORGANIC MOLECULES Ranking resonance structures Rank the resonance structures in each row of the table from major to minor. For example, in the first row, select (major) for the major resonance contributor. If two or more structures in the same row contribute equally, rank them equally by selecting the same number. H. H H. H. H. H. H. H. (Rank) (Rank) (Rank) H. H. H. H. H. H. H. (Rank) (Rank) :o: Rank) (Rank) 74°F DELL F5 F6 F7 F8 F9 F10 F11 PrtScr F12 24arrow_forward
- Draw two more resonance structures for each species. a. b.arrow_forwardd. b. e o C. a. O 6. Draw at least 3 additional (l.e., in addition to the structure provided) valid resonance (major contributors only) forms of the following ions: Ⓒarrow_forwardDraw a curved arrow starting from the t bond of Draw all atoms of the resulting resonance structure C. Show resonance structure B that will form resonance charges and lone pairs. structure C. Select Draw Rings More Erase Select Draw Rings More Erase C C H :0 : I. H Q Q Resonance structure C is a major (more important) resonance structure. minor (less important) resonance structure.arrow_forward
- Follow the curved arrows to draw a second resonance structure for each species.arrow_forwardDraw all reasonable resonance structures for each species. a. O3 c. Ng e. g. :O: :O: b. NO, (a central N atom) d. CH3-C-CH-C-CH, 1. CH2=CH-CH-CH=CH2arrow_forwardStructure A: Complete the resonance structure. Select Draw Rings More Erase C H H. H. H.arrow_forward
- Consider tne pairs oI SIruciures snown. H. H. А. and H. CH3 CH3 В. and H. :O: and H3C H. H2C D. CH3CH,* and *CH2CH3 Which structures are resonance structures to each other? pair A pair B pair C nair D :O: C.arrow_forwardWith reference to compound A drawn below, label each compound as an isomer, a resonance structure, or neither. :0: :0: :O: :ö: :0: a. b. с. d. A With reference to cation B, label each species as an isomer, a resonance structure, or neither. а. b. С. d.arrow_forwardLabel the resonance structures in each pair as major, minor, or equal contributors to the hybrid. Then draw the hybrid.arrow_forward
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