Sn2 and N (starting concentration 10 mol/L) should be separated by fractionated precipitation using H₂S. Does a pH range exist allowing to completely precipitate one metal (i.e. the remaining concentration of the precipitated ion has to be 10 mol/L or less) whereas the other stays in solution at its initial concentration? Please calculate this pH range whereby pH values below zero are set to zero! Please illustrate the situation graphically by plotting pH versus in solution/precipitating/fully precipitated for the two ions (9) Solubility product (SnS): 10; (NIS): 1021; Acid constant (H2S): 10-20, r/Concentration of H2S in water: 0.1 mol/L

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter15: Complex Ion And Precipitation Equilibria
Section: Chapter Questions
Problem 76QAP
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Sn2 and N (starting concentration 10 mol/L) should be separated by
fractionated precipitation using H₂S. Does a pH range exist allowing to
completely precipitate one metal (i.e. the remaining concentration of the
precipitated ion has to be 10 mol/L or less) whereas the other stays in
solution at its initial concentration? Please calculate this pH range whereby pH
values below zero are set to zero! Please illustrate the situation graphically by
plotting pH versus in solution/precipitating/fully precipitated for the two ions (9)
Solubility product (SnS): 10; (NIS): 1021;
Acid constant (H2S): 10-20,
r/Concentration of H2S in water: 0.1 mol/L
Transcribed Image Text:Sn2 and N (starting concentration 10 mol/L) should be separated by fractionated precipitation using H₂S. Does a pH range exist allowing to completely precipitate one metal (i.e. the remaining concentration of the precipitated ion has to be 10 mol/L or less) whereas the other stays in solution at its initial concentration? Please calculate this pH range whereby pH values below zero are set to zero! Please illustrate the situation graphically by plotting pH versus in solution/precipitating/fully precipitated for the two ions (9) Solubility product (SnS): 10; (NIS): 1021; Acid constant (H2S): 10-20, r/Concentration of H2S in water: 0.1 mol/L
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