Including activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M KBr.

You are to prepare 100. mL of an acetate buffer of pH 5.00 using 1.0 M acetic acid (CH3CO2H, also written as HC2H3O2) and solid sodium acetate (NaC2H3O2). To prepare for the investigation, complete the following calculations. The pKa for HC2H3O2 is 4.74.     The Henderson-Hasselbach equation is pH = pKa + log ([conjugate base]/[acid])    (a) What ratio of [NaC2H3O2] to [CH3CO2H] is required for a pH = 5.00?  (b) You will want the concentrations relatively dilute, so use an acid concentration of 0.10 M. What volume of 1.0 M CH3CO2H would be needed to prepare 100. mL of buffer with the desired concentration of 0.10 M? Use M1V1 = M2V2  (c) Use the ratio from (a) and the concentration desired (discussed in (b)) to calculate how many grams of NaC2H3O2 · 3 H2O would be needed to prepare 100. mL of buffer if the acid concentration is 0.10 M?

Calculate the pH of 1.00 L of 0.195 M HC2H3O2 /0.125 M C2H3O2 - buffer system after the addition of 10.20 mL of 1.00 M HCl. [HC2H3O2: Ka = 1.8 x 10-5 ) (b) Compare the new pH with what you calculated from problem 1. Is the HC2H3O2 /C2H3O2 - mixture effective as a buffer? Explain. (c). Which buffer system is the best choice to create a buffer with pH = 7.20? Explain your choice. (HC2H3O2 Ka = 1.8 x 10-5 ; NH4 + Ka = 5.6 x 10-10; HClO2 Ka = 1.1 x 10-2 ; HClO Ka = 2.9 x 10-8 ) HC2H3O2/KC2H3O2 NH3/NH4Cl HClO2/KClO2 HClO/KClO.        Solution part a,b,c properly fast

Determine the volumes of 0.10 M CH3COOH and 0.10 M CH3COONa required to prepare 10 mL of the following pH buffers. (Note: the pKa of CH3COOH =4.7) a)pH=4.7