Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- Calculate the work of reversible, isothermal expansion of a perfect gas. Suppose that the expansion is reversible but not isothermal and that the temperature decreases as the expansion proceeds. (a) Find an expression for the work when T = Ti; - c( V- Vi), with c a positive constant. (b) Is the work greater or smaller than for isothermal expansion?arrow_forward3. Compute the change in volume when one kilogram of Toluene is compressed from 1 bar to 100 bar at a constant temperature of 20 °C. The volumetric properties of Toluene at 20 °C are: specific volume 1.154 L kg 1, isothermal compressibility = 8.96 x 10-5 bar-1, and volume expansivity = 1.05 × 10–3 °C-1.arrow_forwardAn ideal gas is undergoing a process in which temperature and volume relation is TaV5 . Calculate the work done by the gas is going from state -1 in which pressure is 100 bar and the volume is 4 m' to a state-2 in which the volume is 2 m'. Also calculate the pressure at the state-2 of the system. a) P, = 264 bar and W =-32 MJ b) P, = 274 bar and W =-42 MJ c) P = 266 bar and W = 36 MJ d) P, = 364 bar and W = 52 MJarrow_forward
- PROBLEM 9. A bottle of milk was taken from a refrigerator and put in a bowl of hot water to warm. According to Newton's empirical law of cooling, change of temperature of the milk in the bottle M(t) and change of temperature of water in the bowl W (t) can be described by the differential equations dM dt = -k, (M – W) dW dt :-k2(W – Ta) – k3( – M), where t is time (in minutes), Tą is the ambient temperature, k, = 0.1, k2 = 0.03, and kg = 0.18 are constants of proportionality. The temperature in the refrigerator is 5°C, the room temperature is 20°C and the initial temperature of the water in the bowl is 80°C. a) Find the solution of the nonhomogeneous system X(t)=X.(t) + Xp(t) if the particular solution Xp(t) is given by: 20 20 b) Find the temperature of milk and water as function of time. c) Find the values of W (t) and M(t) when t → o.arrow_forwardI need an answer to all three, please help!arrow_forwardA rigid tank is divided into two equal parts by a partition. One part of the tank contains 2.5 kg of compressed liquid water at 400 kPa and 60°C while the other part is evacuated. The partition is now removed, and the water expands to fill the entire tank. Determine the entropy change of water during this process, if the final pressure in the tank is 40 kPa.arrow_forward
- An insulated tank is divided in half. One half contains 2 mol N2 at 2 bar and 30°C and the other half contains 1 mol Oz at 1 bar and 30°C. A valve is opened between the compartments. The final temperature of the gas inside the tank is 30°C. N2 2 bar. 30°C bar 30°C equal to O greater than O less thanarrow_forwardA fixed volume tank has water in vapor-liquid equilibrium. A mole of methane is added to the system. All gases are ideal. The amount of water in the vapor phase [_ а. stays the same vapor b. increases 1 mỏl CH, С. decreases liquidarrow_forwardA) Define the following: Pipes in series, Dehydration, Critical point, Condensate, Real gas B) A 50-cubic ft tank contains gas at 50 psia and 50F°. It is connected to another tank that contains gas at 25 psia and 50Fº When the valve between the two is opened, the pressure equalizes at 35 psia at 50F° as in the adjacent figure. ÉT What is the volume of the second tank? Tank-2 Tank-1arrow_forward
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