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Science
Chemistry
(H) + Na2CO3' H₂O (Q) n C-H15 CHO 1 Ph3P' CBг4 Ζη CH2Cl2 2n BuLi (2 eq) THF 78 °C зa* CH3CHO 3b H*, H₂O n C7H15-C=C-Li
(H) + Na2CO3' H₂O (Q) n C-H15 CHO 1 Ph3P' CBг4 Ζη CH2Cl2 2n BuLi (2 eq) THF 78 °C зa* CH3CHO 3b H*, H₂O n C7H15-C=C-Li
BUY
Introduction to General, Organic and Biochemistry
11th Edition
ISBN:
9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:
Cengage Learning
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1 Matter, Energy, And Measurement
2 Atoms
3 Chemical Bonds
4 Chemical Reactions
5 Gases, Liquids, And Solids
6 Solutions And Colloids
7 Reaction Rates And Chemical Equilibrium
8 Acids And Bases
9 Nuclear Chemistry
10 Organic Chemistry
11 Alkanes
12 Alkenes And Alkynes
13 Benzene And Its Derivatives
14 Alcohols, Ethers, And Thiols
15 Chirality: The Handedness Of Molecules
16 Amines
17 Aldehydes And Ketones
18 Carboxylic Acids
19 Carboxylic Anhydrides, Esters, And Amides
20 Carbohydrates
21 Lipids
22 Proteins
23 Enzymes
24 Chemical Communications: Neurotransmitters And Hormones
25 Nucleotides, Nucleic Acids, And Heredity
26 Gene Expression And Protein Synthesis
27 Bioenergetics: How The Body Converts Food To Energy
28 Specific Catabolic Pathways: Carbohydrate, Lipid, And Protein Metabolism
29 Biosynthetic Pathways
30 Nutrition
31 Immunochemistry
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6.1 What Do We Need To Know As We Begin?
6.2 What Are The Most Common Types Of Solutions?
6.3 What Are The Distinguishing Characteristics Of Solutions?
6.4 What Factors Affect Solubility?
6.5 What Are The Most Common Units For Concentration?
6.6 Why Is Water Suca Good Solvent?
6.7 What Are Colloids?
6.8 What Is A Colligative Property?
Chapter Questions
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Problem 6.15P: 6-15 Answer true or false. (a) A solute is the substance dissolved in a solvent to form a solution....
Problem 6.16P: 6-16 Answer true or false. (a) Solubility is a physical property like melting point and boiling...
Problem 6.17P: 6-17 Vinegar is a homogeneous aqueous solution containing 6% acetic acid. Which is the solvent?
Problem 6.18P: 6-18 Suppose you prepare a solution by dissolving glucose in water. Which is the solvent, and which...
Problem 6.19P: 6-19 In each of the following, tell whether the solutes and solvents are gases, liquids, or solids....
Problem 6.20P: 6-20 Give a familiar example of solutions of each of these types: (a) Liquid in liquid (b) Solid in...
Problem 6.21P: 6-21 Are mixtures of gases true solutions or heterogeneous mixtures? Explain.
Problem 6.22P: 6-22 Answer true or false. (a) Water is a good solvent for ionic compounds because water is a polar...
Problem 6.23P: 6-23 We dissolved 0.32 g of aspartic acid in 115.0 mL of water and obtained a clear solution. After...
Problem 6.24P
Problem 6.25P: 6-25 A small amount of solid is added to a separatory funnel containing layers of diethyl ether and...
Problem 6.26P: 6-26 On the basis of polarity and hydrogen bonding, which solute would be the most soluble in...
Problem 6.27P
Problem 6.28P: 6-28 Which pairs of liquids are likely to be miscible? (a) H2O and CH3OH (b) H2O and C6H6 (c)C6H14...
Problem 6.29P
Problem 6.30P: 6-30 Near a power plant, warm water is discharged into a river. Sometimes dead fish are observed in...
Problem 6.31P: 6-31 If a bottle of beer is allowed to stand for several hours after being opened, it becomes "flat"...
Problem 6.32P: 6-32 Would you expect the solubility of ammonia gas in water at 2 atm pressure to be: (a) greater...
Problem 6.33P
Problem 6.34P
Problem 6.35P: 6-35 Describe how we would prepare the following solutions: (a) 280. mL of a 27% v/v solution of...
Problem 6.36P
Problem 6.37P: 6-37 Calculate the w/v percentage of each of these solutes: (a) 623 mg of casein in 15.0 mL of milk...
Problem 6.38P: 6-38 Describe how we would prepare 250 mL of 0.10 M NaOH from solid NaOH and water.
Problem 6.39P: 6-39 Assuming that the appropriate volumetric flasks are available, describe how we would make these...
Problem 6.40P: 6-40 What is the molarity of each solution? (a) 47 g of KCI dissolved in enough water to give 375 mL...
Problem 6.41P: 6-41 A teardrop with a volume of 0.5 mL contains 5.0 mg NaCI. What is the molarity of the NaCI in...
Problem 6.42P
Problem 6.43P: 6-43 The label on a sparkling cider says it contains 22.0 g glucose (C6H12O6) 190. mg K+ , and 4.00...
Problem 6.44P
Problem 6.45P: 6-45 The label on ajar of jam says it contains 13 g of sucrose, C12H22O11 per tablespoon (15 mL)....
Problem 6.46P: 6-46 A particular toothpaste contains 0.17 g NaF in 75 mL, toothpaste. What are the percent w/v and...
Problem 6.47P: 6-47 A student has a bottle labeled 0.750% albumin solution. The bottle contains exactly 5.00 mL....
Problem 6.48P: 6-48 How many grams of solute are present in each of the following aqueous solutions? (a) 575 mL of...
Problem 6.49P: 6-49 A student has a stock solution of 30.0% w/v H2O2 (hydrogen peroxide). Describe how the student...
Problem 6.50P
Problem 6.51P
Problem 6.52P
Problem 6.53P: 6-53 Dioxin is considered to be poisonous in concentrations above 2 ppb. If a lake containing L has...
Problem 6.54P: 6-54 An industrial wastewater contains 3.60 ppb cadmium Cd2+. How many mg of Cd2+ could be recovered...
Problem 6.55P: 6-55 According to the label on a piece of cheese, one serving of 28 g provides the following daily...
Problem 6.56P
Problem 6.57P
Problem 6.58P
Problem 6.59P
Problem 6.60P: 6-60 Predict which of these covalent compounds is soluble in water. (a) C2H6 (b) CH3OH (c) HF (d)...
Problem 6.61P
Problem 6.62P
Problem 6.63P
Problem 6.64P
Problem 6.65P
Problem 6.66P: 6-66 What gives nanotubes their unique optical and electrical properties?
Problem 6.67P: 6-67 Calculate the freezing points of solutions made by dissolving 1.00 mole of each of the...
Problem 6.68P: 6-68 If we add 175 g of ethylene glycol, C2H6O2, per 1000. g of water to a car radiator, what will...
Problem 6.69P
Problem 6.70P: 6-70 In winter, after a snowstorm, salt (NaCI) is spread to melt the ice on roads. How many grams of...
Problem 6.71P: 6-71 A 4 M acetic acid (CH3COOH) solution lowers the freezing point by-8°C; a 4 M KF solution yields...
Problem 6.72P
Problem 6.73P: 6-73 In each case, tell which side (if either) rises and why. The solvent is water. (a) 1% glucose...
Problem 6.74P: 6-74 An osmotic semipermeable membrane that allows only water to pass separates two compartments, A...
Problem 6.75P: 6-75 Calculate the osmolarity of each of the following solutions. (a) 0.39 M Na2CO3 (b) 0.62 M...
Problem 6.76P
Problem 6.77P
Problem 6.78P: 6-78 (Chemical Connections 6A) Oxides of nitrogen (NO, NO2,N2O3) are also responsible for acid rain....
Problem 6.79P
Problem 6.80P
Problem 6.81P
Problem 6.82P: 6-82 (Chemical Connections 6C) A solution contains 54 mEq/L ofCI- and 12 mEq/L of HCO3-. If Na+ is...
Problem 6.83P: 6-83 (Chemical Connections 6C) The concentration of Ca2+ ion present in a blood sample is found to...
Problem 6.84P: 6-84 (Chemical Connections 6D) What is the chemical formula for the main component of limestone and...
Problem 6.85P
Problem 6.86P
Problem 6.87P
Problem 6.88P
Problem 6.89P
Problem 6.90P
Problem 6.91P: 6-91 When a cucumber is put into a saline solution to pickle it, the cucumber shrinks; when a prune...
Problem 6.92P
Problem 6.93P: 6-93 Two bottles of water are carbonated, with CO2 gas being added, under 2 atm pressure and then...
Problem 6.94P
Problem 6.95P
Problem 6.96P: 6-96 We know that a 0.89% saline (NaCI) solution is isotonic with blood. In a real-life emergency,...
Problem 6.97P
Problem 6.98P
Problem 6.99P: 6-99 A concentrated nitric acid solution contains 35% HNO3. How would we prepare 300. mL of 4.5%...
Problem 6.100P: 6-100 Which will have greater osmotic pressure? (a) A 0.9% w/v NaCI solution (b) A 25% w/v solution...
Problem 6.101P
Problem 6.102P
Problem 6.103P: 6-103 A swimming pool containing 20,000. L of water is chlorinated to have a final CI2 concentration...
Problem 6.104P
Problem 6.105P
Problem 6.106P
Problem 6.107P
Problem 6.108P
Problem 6.109P
Problem 6.110P
Problem 6.111P: 6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more...
Problem 6.112P: 6-112 List the following aqueous solutions in order of increasing boiling point: 0.060 M glucose...
Problem 6.113P: 6-113 List the following aqueous solutions in order of decreasing freezing point: 0.040 M glycerin...
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(H) + Na2CO3' H₂O
Transcribed Image Text:
(Q) n C-H15 CHO 1 Ph3P' CBг4 Ζη CH2Cl2 2n BuLi (2 eq) THF 78 °C зa* CH3CHO 3b H*, H₂O n C7H15-C=C-Li
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