Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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For the cycloaddition reaction shown below
A
B
NC CN
a) Give the curved arrow-pushing and draw the allowed product
for the reaction, be sure to include stereochemistry and indicate
any racemic mixtures
A
heat
b) on TOP of reactant A draw a pictorial representation of the
HOMO (draw it on the structure like the one shown below rather
than the one in the equation so that the curved arrow-pushing isn't
obscured)
B
c) on TOP of reactant B draw a pictorial representation of the
LUMO (draw it on the structure below rather than the one in the
equation so that the curved arrow-pushing isn't obscured)
NC CN
d) Is the allowed reaction suprafacial or antarafacial for reactant
A?
e) Is the allowed reaction suprafacial or antarafacial for reactant
B?
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Transcribed Image Text:For the cycloaddition reaction shown below A B NC CN a) Give the curved arrow-pushing and draw the allowed product for the reaction, be sure to include stereochemistry and indicate any racemic mixtures A heat b) on TOP of reactant A draw a pictorial representation of the HOMO (draw it on the structure like the one shown below rather than the one in the equation so that the curved arrow-pushing isn't obscured) B c) on TOP of reactant B draw a pictorial representation of the LUMO (draw it on the structure below rather than the one in the equation so that the curved arrow-pushing isn't obscured) NC CN d) Is the allowed reaction suprafacial or antarafacial for reactant A? e) Is the allowed reaction suprafacial or antarafacial for reactant B?
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