Draw the structure (using chair confirmation of pyranose) of the following disaccharides. (a) 4-0-(a-D-glucopyranosyl)-D-galactopyranose (b) a-D -fructofuranosyl-ß-D-mannopyranoside (c) 6-0-(ß-D-galactopyranosyl)-D-glucopyranose
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- Which of the following is the correct systematic name of the disaccharide shown? α-D-glucopyranosyl-(1→3)-β-D-galactopyranose α-D-gulopyranosyl-(1→4)-β-D-glucopyranose α-D-gulopyranosyl-(1→4)-β-D-galactopyranose α-D-glucopyranosyl-(1→3)-β-D-glucopyranoseIdentify the structure of O-a-D-sorbopyranosyl-(24)-B-D-glucopyranose below. The following structures will help: НО Н ОН х Н H H D-sorbose Н OH CH₂OH Н Н Н OH HO Н H HO H н HO ОН Н н Н О ОН O H Н CH₂OH OH OH н 0 CH2OH Н OH Н H OH Н CH₂OH H ОН Н OH Н Н Н РО OH Н HO OH н н -O CH2O Н O H H OH н Н OH CH₂OH о CHOH H H Н Ко OH H OH Н Н OH Н OH Н OH Н CH₂OH -OCHOH H OH O CH OH Н OH Н Н CH₂OH ОН он OH OH H OH H O OH CH₂OH OH ОН Н O OH OH D-glucose Н ОН Н ОН ОНImagine a trisaccharide that has D-Altrose, D-Gulose, and D-Ribose. D-Altrose is bonded to D-Gulose in an α(1→4) glycosidic bond and D-Ribose is bonded to D-Altrose in an α(1→6) glycosidic bond. Draw the imaginary trisaccharide using Haworth projection with the appropriate representation of each monosaccharide.
- Draw the structure of the disaccharide with a systematic name of: (1→6)-B-1) glucopyranosyl-B-D-fructofuranosideDraw the structure of: The polysaccharide in (b) is dextran, a component of dental plaque. Here b: (b) a polysaccharide formed by joining D-glucose units in 1→6-α-glycosidic linkagesWhat is the natural polysaccharide whose repeating structure can be symbolized by GlcUAβ(1 → 3)GlcNAc, with these units connected by β(1 → 4) links?
- Match the following structural composition of each polysaccharide with its identity Linear homoglycan of glucose connected by α1-4 linkages Linear sulfated chains of alternating β-D-galactopyranose and 3,6-anhydro- α-galactopyranosyl units Poly-β-Dmannopyranosyluronic acid and/or Poly-α-L-gulopyranosyluronic acid Repeating Poly-D-galacturonic acid residues deacetylated straight-chain amino-polysaccharide polymer linked in a β(1-4) type of linkage a. Alginate b. amylose c. chitosan d. carrageenan e. Pectin2) Draw the skeletal (line-boad) structure for 2-methylbutanediaicacid. 3) Draw the skeletal structuce for (E)-3-phenylbut - 2-cnois acid. 4) Draw the skele tal structure for (2)-3-chloro-2- phenylprop-2-enaic acid. 5) The common fea ture of all esters is the presence of a A)-OH group B)-CE8)OH group C)-C(=0)H group D)-C(=0)OR group. 6) Draw the skeletal structuce of 3,3-dimethylbutanenitrileRaffinose is a trisaccharide and a minor constituent in sugar beets. (a) Is raffinose a reducing sugar?Explain. (b) What are the monosaccharides that compose raffinose ? (c) β - Galactosidase is an enzyme that will remove galactose residues from an oligosaccharide. What are the products of β - galactosidase treatment of raffinose ?
- Indicate the following for each disaccharide: I) type of glycosidic linkage i.e. a(1→4) II) configuration i.e. alpha or beta 1. OH CH₂OH 0 OH I) II) III) IV) OH CH₂OH -0 OH ОН OH 2. HO CH₂OH 0 I) II) III) IV) ОН HOCH2 ОН HO ОН CH₂OH 3. CH, OH CH2 О CG OH ОН HO ОН HỎ I) II) III) III) reducing or non-reducing sugar IV) name of each monosaccharide IV) OH OH 4. HO I) II) III) IV) CH₂OH OH 0 ОН CH₂OH OH ОН OHMatch the following structural composition with the corresponding polysaccharide Linear homoglycan of glucose connected by α1-4 linkages Branched glycan formed by alternating units of D-galactose and L-galactose Linear sulfated chains of alternating β-D-galactopyranose and 3,6-anhydro- α-galactopyranosyl units Poly-β-Dmannopyranosyluronic acid and/or Poly-α-L-gulopyranosyluronic acid Repeating Poly-D-galacturonic acid residues…Indicate the following for each disaccharide: I) type of glycosidic linkage i.e. a(1→4) II) configuration i.e. alpha or beta 1. ОН CH₂OH OH I) II) III) IV) 0 ОН 0 CH₂OH OH ОН OH 2. HO CH₂OH I) II) III) IV) ОН HOCH₂, OH ·0 НО 0 ОНА CH₂OH 3. HO I) II) III) IV) CH OH OH O ОН III) reducing or non-reducing sugar IV) name of each monosaccharide HO CH₂ ОН OH ОН 4. HO I) II) III) IV) CH₂OH 0 OH ОН CH₂OH OH О ОН ОН