Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Below is a proposed mechanism for the chlorination of methane:

step1 CH4(g)+Cl2(g)⇀↽CH3(g)+HCl(g)+Cl∙ slow

step2 CH3(g)+Cl2(g)⇀↽CH3Cl(g)+Cl∙ fast

a. Write the overall chemical reaction and write an overall rate expression for the appearance of CH3Cl (g). Note that this rate expression can include the concentration of intermediates.

b. Using your answer to part b, write the rate expression for the change in concentration of CH3 (g)

c. Using the steady state approximation, give an expression for the appearance of CH3Cl (g) that does not depend on the concentration of CH3 (g). Note that the first reaction is reversible and the second is not.

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