Set up the rate expressions for the following reaction mechanism: A 2 B B +C 3 D If the concentration of B is small compared with the concentrations of A, C, and D, the steady-state approximation may be used to derive the rate law of the overall reaction. 1. Show that this reaction may follow the first-order reaction with [A] at high concentrations (or excess) of [C] kith k3>> k2. 2. Under this high concentrations (or excess) of [C] with k3 >> k2, graph the concentrations of [A], [B], and [D] vs time. Assume the initially only A and C exist in the system.

Set up the rate expressions for the following reaction mechanism: A 2 B B +C 3 D If the concentration of B is small compared with the concentrations of A, C, and D, the steady-state approximation may be used to derive the rate law of the overall reaction. 1. Show that this reaction may follow the first-order reaction with [A] at high concentrations (or excess) of [C] kith k3>> k2. 2. Under this high concentrations (or excess) of [C] with k3 >> k2, graph the concentrations of [A], [B], and [D] vs time. Assume the initially only A and C exist in the system.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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