(b)2.(C) Assign the hybridization, number of p orbitals remaining following hybridization, andHybridization and MOSformal charge for nitrogen and carbon 1 in the molecule below.H₂-CH₂NHHAtomHybridization(sp, sp², or sp³)Carbon 1Nitrogen# p orbitalsremaining(0, 1, 2, or 3)Formal charge(0, -1, or +1)σCircle all types of molecular orbitals that are present in this moleculeπ(c) (1) Circle the HOMO of the molecule in (a):σπ(d) ) Circle the LUMO of the molecule in (a):σπσ'ποnonbondingποnonbondingπ"HO

Part (a): Hybridization, Number of p Orbitals Remaining, and Formal ChargeIn the molecule, you have…

Answered: (b) 2. (C) Assign the hybridization,…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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1. What are the VSEPR shapes (i.e., molecular geometries) associated with the nitrogen atoms in this molecule? (A) (B) (C) (D) I bent bent bent tetrahedral 2. How many sp² hybridized carbon atoms are present in this structure? (A) 1 HO. Br II trigonal pyramidal N. bent trigonal pyramidal I bent (A) aldehyde, ether, sulfide (B) aldehyde, ketone, thiol (C) amide, ketone, sulfide (D) amide, ether, ester II NH₂ III III trigonal pyramidal (B) 4 (C) 5 (D) 6 3. Which functional groups are NOT present in this molecule? trigonal pyramidal tetrahedral trigonal pyramidal
H genistein HO, H H : ОН HO, H (a) Is the hybridization of each C in the right-most ring the same? Explain. (b) Is the hybridization of the O atoms in/on the center ring the same as that of the O atoms in the OH groups? Explain. (c) How many carbon-oxygen o-bonds are there in genistein? How many carbon-oxygen n-bonds? (d) Do all the lone pairs on the oxygens occupy the same type of hybrid orbital? Explain by labeling the hybridization of each oxygen atom in genistein.
Specify the local electron geometrles about the atoms labelled a-d. Unshared electron pairs affect locall geometry and are included in the structural formula. For each atom enter one of the following: tetrahedral, square planar, trigonal planar, trigonal pyramidal, or linear. (a) (b) (c) (d) H till H
Acetyl salicylic acid (aspirin), the most widely used medi-cine in the world, has the Lewisstructure at right. (a) What is the hybridization of each C and each O atom? (b) How many localized π bonds are present? (c) How many C atoms have a trigonal planar shape around them? A tetra hedral shape?
6
Specify the local electron geometries about the atoms labelled a-d. Unshared electron pairs affect local geometry and are included in the structural formula. For each atom enter one of the following: tetrahedral, square planar, trigonal planar, trigonal pyramidal, or linear. (a) (b) (c) (d) H- H H-C H H H H H 05 > -H
For each of the following structures, determine the hybridization requested and whether the electrons will be delocalized: (a) Hybridization of each carbon н :0: Н | || | Н—с—с——н H. (b) Hybridization of sulfur (c) All atoms EN: H.
3) Which statement best describe the structure of a carbonate anion C02- ? A) The electron geometry of carbon in a carbonate anion is trigonal planar with a sp2 hybridization and bond angles are 120°. There is a n-bond formed between a non-hybridized "C" p-orbital overlapping with an "O" p-orbital. C) The electron geometry of carbon in a carbonate anion is trigonal planar with a sp2 hybridization and bond angles are 120°. There is a 7-bond formed between a non-hybridized “C" p-orbital overlapping with an “O" p-orbital.
Use an MO diagram and the bond order you obtain from it to answer: (a) Is O2- stable? (b) Is O2- paramagnetic? (c) What is the outer (valence) electron configuration of O2-?
(b) (ii) types of bonds between carbon and nitrogen a character in character (iii) type of orbital that contains the lone electron pair on nitrogen ++* H H- (1) hybridization of C and N C [References]
The unmistakable odor of a freshly cut cucumber is largely due to cucumber aldehyde. (a) How many sp2 hybridized carbon atoms does cucumber aldehyde contain? (b) What is the hybridization of the O atom? (c) What orbitals are used to form the carbon–oxygen double bond? (d) How many σ bonds does cucumber aldehyde contain? (e) How many π bonds does it contain?
The unmistakable odor of a freshly cut cucumber is largely due to cucumber aldehyde. (a) How many sp2 hybridized carbon atoms does cucumber aldehyde contain? (b) What is the hybridization of the O atom? (c) What orbitals are used to form the carbon–oxygen double bond? (d) How many σ bonds does cucumber aldehyde contain? (e) How many π bonds does it contain?

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