Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- 5. The reaction: 2NO₂(g) + 7H₂(g) = 2NH3(g) + 4H₂O(g) was allowed to reach equilibrium at 455 K. Analysis showed that there was 34.6 g of NO2, 53.2 g of H₂, 52.6 g of NH3 and 87.4 g H₂O present in a 2.65 L vessel once equilibrium was achieved. a. Determine the equilibrium concentration for both reactants. b. Determine the equilibrium concentration for both products. C. Write the Kc expression. d. Solve for the Kc. e. Solve for the Kp at the same temperature.arrow_forward2NO(g) + 2H₂(g) = N₂(g) + 2H₂O(g) The system initially contained 0.2500 M NO, 0.1300 M H2, and 0.2500 M H₂O. At equilibrium, the concentration of NO is 0.1296 M. What is the equilibrium concentration of H₂? [H₂] = [?] x 10¹ M K= [N₂] [H₂O]2 [NO]2[H₂]2 Coefficient (green) Exponent (yellow) Enterarrow_forwardConsider the following equilibrium system at 355 K. 2NOBr(g) -----> 2NO(g)+Br2(g). If an equilibrium mixture of the three gases at 355 K contains 3.21x10^-2 M NOBr, 2.01x10^-2 M NO,and 3.98x10^-2 M Br2 what is the value of the equilibrium constant Karrow_forward
- Consider the following equilibrium: 2NOCl (g) <--> 2NO (g) + Cl2 (g) With K = 1.6 x 10-5. 1.00 mole of pure NOCl and 0.964 mole of pure Cl2 are placed in a 1.00 L container. Calculate the equilibrium concentration of Cl2 (g).arrow_forward2. The compound NOCl decomposes to nitric oxide and chlorine according to the following equation: 2 NOCl (g) → 2 NO (g) + Cl2 (g) Suppose that 0.810 mol NOCl is placed in a 4.00-L flask at a given temperature. When equilibrium has been established, it is found that the concentration of Cl2 is 0.0105 M. Calculate the equilibrium constant for this reaction.arrow_forwardA chemist is studying the following equilibirum, which has the given equilibrium constant at a certain temperature: 2 NO(g) + Cl₂(g) 2 NOC1 (g) K₂ = 1. x 10 -6 He fills a reaction vessel at this temperature with 13. atm of nitrogen monoxide gas and 17. atm of chlorine gas. Use this data to answer the questions in the table below. Can you predict the equilibrium pressure of NOCI, using only the tools available to you within ALEKS? If you said yes, then enter the equilibrium pressure of NOCI at right. Round your answer to 1 significant digit. O yes O no atm 0 X S BEEN 000 Ararrow_forward
- Keq from Equilibrium Composition, Variously Expressed. At some temperature, an equilibrium mixture, in a 1.00-L container, involving the chemical system PCI5(g) = PCI3(g) + Cl2(g) is found to contain 5.74x1020 molecules of PCI5, 0.00921 mol of PCI3, and 0.228 g of Cl2. Calculate the equilibrium constant (Keg expressed in terms of the molar concentrations) at this temperature. (No units required.)arrow_forwardSulfur dioxide and oxygen react to form sulfur trioxide during one of the key steps in sulfuric acid synthesis. An industrial chemist studying this reaction fills a 50.0 L tank with 15, mol of sulfur dioxide gas and 3.8 mol of oxygen gas, and when the mixture has come to equilibrium measures the amount of sulfur trioxide gas to be 2.3 mol. Calculate the concentration equilibrium constant for the reaction of sulfur dioxide and oxygen at the final temperature of the mixture. Round your answer to 2 significant digits. 0.P X CO M 00arrow_forwardA student adds 0.600 mol of methane gas, CH4(g) into a 2.00 L container and the methane forms ethyne, C2H2(g) and hydrogen gas, H2(g). At equilibrium, the container was found to contain 0.045 mol/L C2H2.a) Calculate the initial concentration of CH4. Then complete an ICE Table to organize the initial, change and equilibrium concentrations for this equilibrium system. Show any calculations needed. 2CH4(g) ⇄ C2H2(g) + 3H2(g)b) Calculate the equilibrium constant, Keq, for this equilibrium. Show all work.c) What is the equilibrium concentration of H2(g) ?arrow_forward
- 6. Hydrogen gas is finding more acceptance as an alternative fuel. It is produced along with carbon dioxide by the reaction of carbon monoxide and gaseous water at 915 K. At this temperature, the equilibrium constant (K.) is 1.56. If this reaction is started in a 4.00 L closed system flask with 0.450 mol of CO, 1.25 mol H2O, 1.15 mol CO2, and 3.50 mol H2, calculate the concentrations of all substances in the flask initially and at equilibrium. Put these values in the ICE table below. (Hint: you will need to use the quadratic formula.) CO Н20 CO2 H2 INITIAL CHANGE EQUILIBRIUM 0.1125 0.3125 0.2875 0.875 -X -X +X +x e these values in the table. d. Calculate the reaction quotient, Q. e. Express the direction of equilibrium shift as an algebraic expression. Complete the change row of the table. f. Substitute the algebraic expressions into the equilibrium expression and solve for the equilibrium concentrations. Place these values in the table.arrow_forwardConsider the reaction A + B C+D, which has an equilibrium constant, K, equal to 3.4 x 102. If one begins a reaction by placing 0.600 moles of A in a 1.0 L container as well as 0.150 moles of 1. B, what will be the equilibrium concentrations of A, B, C, and D? Write your answers in the spaces provided below. a. [А] b. [B]= [C]= С. d. [D]= Once the reaction in problem 1 reaches equilibrium, some additional B is injected into the flask 2. from an outside source. LeChatelier's principle says the reaction will (circle one): be unchanged shift to the right shift to the left Pyridine is a weak base with a Kb 1.7 x 109. If 0.300 moles of pyridine is added to 1.00 L of 3. water, what will be the equilibrium concentrations of the species below: a. [Pyridine] = b. [Pyridine-H] (the pyridinium ion) [ОН-] 3 С. What is the pH of the solution in problem 4 (above)? .arrow_forwardA chemist is studying the following equilibirum, which has the given equilibrium constant at a certain temperature: N2(g) + 2H2O(g) 2 NO(g) + 2 H2(g) K=2.x 10 -10 He fills a reaction vessel at this temperature with 6.0 atm of nitrogen gas and 11. atm of water vapor. Use this data to answer the questions in the table below. Can you predict the equilibrium pressure of H2, using only the tools available to you within ALEKS? ○ yes x10 O no If you said yes, then enter the equilibrium pressure of H₂ at right. Round your answer to 1 significant digit. atm 5arrow_forward
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