Organic Chemistry
Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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16.40 (•) Predict the product(s) that would result when the alkyl halides shown are allowed to react under the following conditions: (i) PhZnBr, Pd(PPh3) 4; (ii) PhB(OH)2, Pd(PPh3)4, (iii) PhSnBu3, Pd(PPh3)4. (iv)
Cu-C=C-CH3, Pd(PPh3)4; (v) 1. Mg° 2. PhCHO 3. H3O+ quench; (vi) 1. 2 Liº 2. Oxirane 3. H3O+ quench; (vii) 1. H₂C=CHSnBu3, Pd(PPh3)4 2. ICH₂ZnI; (viii) 1. 2 Liº 2. Cul (0.5 equiv.) 3. BrCH=CH2.
(a)
(b)
(d)
Br
(c)
Br
Br
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Transcribed Image Text:[Assessments are ranked according to their difficulty; ●●●●= most difficult.] 16.40 (•) Predict the product(s) that would result when the alkyl halides shown are allowed to react under the following conditions: (i) PhZnBr, Pd(PPh3) 4; (ii) PhB(OH)2, Pd(PPh3)4, (iii) PhSnBu3, Pd(PPh3)4. (iv) Cu-C=C-CH3, Pd(PPh3)4; (v) 1. Mg° 2. PhCHO 3. H3O+ quench; (vi) 1. 2 Liº 2. Oxirane 3. H3O+ quench; (vii) 1. H₂C=CHSnBu3, Pd(PPh3)4 2. ICH₂ZnI; (viii) 1. 2 Liº 2. Cul (0.5 equiv.) 3. BrCH=CH2. (a) (b) (d) Br (c) Br Br
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