Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Following is a structural formula for guanidine, the compound by which migratory birds excrete excess metabolic nitrogen. The hydrochloride salt of this compound is a white crystalline powder, freely soluble in water and ethanol.

Q. Does proton transfer to guanidine occur preferentially to one of its -NH2 groups (cation A) or to its =NH group (cation B)? Explain.

NH
NH
NH,+
H,N-C-NH, + HCI H,N-C-NH,+
H,N-C-NH, + CI-
or
Guanidine
A
B
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Transcribed Image Text:NH NH NH,+ H,N-C-NH, + HCI H,N-C-NH,+ H,N-C-NH, + CI- or Guanidine A B
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