Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- = ● ENTROPY AND FREE ENERGY Calculating dG from dH and dS A chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 52.0 °c and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy as of the first reaction, and the reaction enthalpy Aн and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and As for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. 2NO(g) + Cl₂(g) → 2NOCI(g) N₂H₂(g) + H₂(g) → 2NH₂(g) ΔΗ - - 76, kJ AS-234. AG = 24 Which is spontaneous? O this reaction O…arrow_forwardA chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 72.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. C₂H₂(g) + 50₂(g) → 3CO₂(g) + 4H₂O(1) 2CO₂ (g) + 4H₂O(g) → 2CH, OH (g) + 30₂ (g) ΔΗ = -1220. ΚΙ J K AS-6432. AG - KJ Which is spontaneous? O this reaction O the reverse reaction…arrow_forwardA chem V ngineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 90.0 °C and constant total pressure. Then. he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. AH = 2220, kJ J AS = 6113. K AG = kJ 3co,() + 4H,0(1) → C,H,(g) + 50,(g) Which is spontaneous? O this reaction O the reverse reaction O neither AH = -951. kJ J AS = AG = – 14. kJ 2A1(s)…arrow_forward
- A chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 144.0°C and constant total pressure. Then, he measures the reaction enthalpy ΔH and reaction entropy ΔS of the first reaction, and the reaction enthalpy ΔH and reaction free energy ΔG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate ΔG for the first reaction and ΔS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. →+C3H8g5O2g+3CO2g4H2Ol =ΔH−2220.kJ =ΔS−5322.JK =ΔGkJ Which is spontaneous? this reaction the…arrow_forwardIn each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 72.0 °C and constant total pressure. Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. P₂010 (s) + 6H₂0 (1) 4H₂ PO(s) 4 2NH₂ (g) → N₂H₂(g) + H₂ (g) 2 4 2 ΔΗ = -439. kJ AS-1179. AG = AH = k AS = kJ Which is spontaneous? this reaction the reverse reaction neither 188. kJ OK- K J K AG 16. kJ Which is spontaneous? this reaction the reverse…arrow_forwardA chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 144.0°C and constant total pressure. Then, he measures the reaction enthalpy ΔH and reaction entropy ∆S of the first reaction, and the reaction enthalpy ΔH and reaction free energy ΔG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate ΔG for the first reaction and ∆S for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium.arrow_forward
- A chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 50.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. alo Ar ΔΗ - 439. kJ J AS = - 1359. K ? P,01, (s) + 6H,0(1) . | kJ AG = 4H,PO, (s) Which is spontaneous? this reaction the reverse reaction neitherarrow_forward0/5 Nerbs A chemical engineer is studying the two reactions shown in the table below. In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 85.0 °C and constant total pressure. Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. do AH = -2220. kJ J AS = -6189 K C,H, (g) + 50, (g) 3Co, (g) + 4H,0(1) AG = KJ Which is spontaneous? O this reaction O the reverse reaction O neither AH = -50. kJ 0- AS =…arrow_forwardA chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 133.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. 2CH₂OH(g) + 30₂(g) → 2CO₂(g) + 4H₂O(g) 4H₂PO4(s) P4O10 (s) + 6H₂0 (1) AH-1353. kJ AS = -3331. AG = Which is spontaneous? Othis reaction O the reverse reaction Oneither ΔΗ = 439. kJ -…arrow_forward
- A chemical engineer is studying the two reactions shown in the table below. In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 24.0 °C and constant total pressure. Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. AH = 188. kJ AS = X Ś ? N₂H₂(g) + H₂(g) → 2NH₂(g) AG = 4 2 P₂(g) + 6Cl₂ (g) 4PC1₂ (g) 688. kJ Which is spontaneous? this reaction the reverse reaction neither AH = - 1207. kJ J AS =…arrow_forwardA chemical engineer is studying the two reactions shown in the table below.. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 124.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. CC14 (8)→ C(s) + 2Cl₂ (g) TICI (g) + 2H₂O(g) → TiO₂ (s) + 4HCl(g) ΔΗ = 107. kJ AS = 310. AG= kJ Which is spontaneous? O this reaction. O the reverse reaction Oneither ΔΗ = -70. KJ…arrow_forwardExplain pleaseeeeeeeeeeearrow_forward
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