Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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● ENTROPY AND FREE ENERGY
Calculating dG from dH and dS
A chemical engineer is studying the two reactions shown in the table
below.
In each case, he fills a reaction vessel with some mixture of the
reactants and products at a constant temperature of 52.0 °c and constant
total pressure. Then, he measures the reaction enthalpy AH and reaction
entropy as of the first reaction, and the reaction enthalpy Aн and
reaction free energy AG of the second reaction. The results of his
measurements are shown in the table.
Complete the table. That is, calculate AG for the first reaction and As for
the second. (Round your answer to zero decimal places.) Then, decide
whether, under the conditions the engineer has set up, the reaction is
spontaneous, the reverse reaction is spontaneous, or neither forward
nor reverse reaction is spontaneous because the system is at
equilibrium.
2NO(g) + Cl₂(g) → 2NOCI(g)
N₂H₂(g) + H₂(g) → 2NH₂(g)
ΔΗ - - 76, kJ
AS-234.
AG =
24
Which is spontaneous?
O this reaction
O the reverse reaction
O neither
ΔΗ = 188. kJ
J
-0-
AS=
:
AG-23. kJ
Which is spontaneous?
O this reaction
O the reverse reaction
O neither
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Transcribed Image Text:= ● ENTROPY AND FREE ENERGY Calculating dG from dH and dS A chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 52.0 °c and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy as of the first reaction, and the reaction enthalpy Aн and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and As for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. 2NO(g) + Cl₂(g) → 2NOCI(g) N₂H₂(g) + H₂(g) → 2NH₂(g) ΔΗ - - 76, kJ AS-234. AG = 24 Which is spontaneous? O this reaction O the reverse reaction O neither ΔΗ = 188. kJ J -0- AS= : AG-23. kJ Which is spontaneous? O this reaction O the reverse reaction O neither
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