||| = ● ENTROPY AND FREE ENERGY Calculating dG from dH and dS A chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 52.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy as of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and As for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. 2NO(g) + Cl₂(g) → 2NOCI(g) N₂H₂(g) + H₂(g) → 2NH₂(g) AH-76. kJ AS-234. - AG = KJ Which is spontaneous? O this reaction O the reverse reaction Oneither AH 188. kJ AS= -0-- : AG = -23. kJ Which is spontaneous? O this reaction O the reverse reaction O neither

||| = ● ENTROPY AND FREE ENERGY Calculating dG from dH and dS A chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 52.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy as of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and As for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. 2NO(g) + Cl₂(g) → 2NOCI(g) N₂H₂(g) + H₂(g) → 2NH₂(g) AH-76. kJ AS-234. - AG = KJ Which is spontaneous? O this reaction O the reverse reaction Oneither AH 188. kJ AS= -0-- : AG = -23. kJ Which is spontaneous? O this reaction O the reverse reaction O neither

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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A chem V ngineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 90.0 °C and constant total pressure. Then. he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. AH = 2220, kJ J AS = 6113. K AG = kJ 3co,() + 4H,0(1) → C,H,(g) + 50,(g) Which is spontaneous? O this reaction O the reverse reaction O neither AH = -951. kJ J AS = AG = – 14. kJ 2A1(s)…
Consider the following reaction at 25 °C: 5 SO3(g) + 2 NH3(g) → 2 NO(g) + 5 SO2(g) + 3 H2O(g) If AH° = 42.4 kJ./mol and AS° = 562.3 J/mol•K, estimate the temperature at which this reaction would be at equilibrium assuming that enthalpy and entropy are independent of temperature. %3D %3D
Use the data in Table T2 to calculate ΔS° for the reaction of H2(g) with liquid benzene (C6H6) to give cyclohexane (C6H12). Answer should be −361.1 J/K
7. Calculate the standard enthalpy change at 25°C for the reaction CH, (g) + 2 H₂S (g) →→ CS₂ (1) + 4H₂(g) The values of AH'at 298 K for reactants and products are: Adf 298/kJ mol¹: CH4(g) = -74.8; H₂S (g)=-20.6; CS₂ (1)=+89.7; H₂(g) - 0.
Elemental carbon usually exists in one of two forms: graphite or diamond. It is generally believed that diamonds last forever. The table shows the standard enthalpy of formation (AH) and the standard molar entropy (Sº) values for diamond and graphite. Part A AGrxn= What is the standard Gibbs free energy for the transformation of diamond to graphite at 298 K? Cdiamond →Cgraphite Submit Express your answer to three significant figures and include the appropriate units. ► View Available Hint(s) O Substance Cgraphite Cdiamond μA Value AH (kJ/mol) Units 0 1.897 ? S° (J/mol. K) 5.740 2.38
A chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 144.0°C and constant total pressure. Then, he measures the reaction enthalpy ΔH and reaction entropy ∆S of the first reaction, and the reaction enthalpy ΔH and reaction free energy ΔG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate ΔG for the first reaction and ∆S for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium.
1 2 words O English (United States) Calculating dG from dH and d A chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 130.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. ALO3(s) + 2Fe(s)- 2Al(s) + Fe₂O₂ (s) co₂(g) + 2H₂O(g) - CH₂(g) + 20₂ (8) AH = 852. kJ AS = 2044. MacBook Air AG=kJ…
A chemical engineer is studying the two reactions shown in the table below. In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 24.0 °C and constant total pressure. Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. AH = 188. kJ AS = X Ś ? N₂H₂(g) + H₂(g) → 2NH₂(g) AG = 4 2 P₂(g) + 6Cl₂ (g) 4PC1₂ (g) 688. kJ Which is spontaneous? this reaction the reverse reaction neither AH = - 1207. kJ J AS =…
A chemical engineer is studying the two reactions shown in the table below.. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 124.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. CC14 (8)→ C(s) + 2Cl₂ (g) TICI (g) + 2H₂O(g) → TiO₂ (s) + 4HCl(g) ΔΗ = 107. kJ AS = 310. AG= kJ Which is spontaneous? O this reaction. O the reverse reaction Oneither ΔΗ = -70. KJ…
Enthalpy and Gibb's Free Energy Chemical energy is released or absorbed from reactions in various forms. The most easily measurable form of energy comes in the form of heat, or enthalpy. The enthalpy of a reaction can be calculated from the heats of formation of the substances involved in the reaction: AHxn = AH₂ (products) - AH (reactants) Entropy change, AS°, is a measure of the number of energetically equivalent microstates introduced into the system during the reaction. The degree of spontaneity of a reaction is represented by the Gibbs free energy, AGO. The Gibbs free energy depends on both the enthalpy and entropy changes that take place during the reaction: AG=AH° - TAS° where T is standard temperature, 298 K. ▼ Part A Calculate the standard enthalpy change for the reaction where the heats of formation are given in the following table: ΔΗ Substance (kJ/mol) A B C D -241 -407 191 -501 Express your answer in kilojoules. ► View Available Hint(s) {—| ΑΣΦ AHixn= 2A+B=2C+2D ? kJ…
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