Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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- For each of the following reaction diagrams, estimate the activation energy (Ea) of the reaction:arrow_forwardThe oxidation of iodide ion by the hypochlorite ion in the presence of hydroxide ions I(aq) + ClO(aq) IO(aq) + Cl(aq) was studied at 25 C, and the following initial rates data (Y. Chia and R. E. Connick, Journal of Physical Chemistry, Vol. 63, p. 1518, 1959) were collected: (a) Determine the rate law for this reaction. (b) One mechanism that has been proposed for this reaction is the following: Show that the rate law predicted by this mechanism matches the experimentally determined rate law in part a. (Note that when writing the expression for K the equilibrium constant, [H2O] is not involved. See Chapter 15.)arrow_forwardWhat is the activation energy of a reaction, and how is this energy related to the activated complex of the reaction?arrow_forward
- Please helparrow_forwardhe activation energy for the gas phase isomerization of cyclobutene is 136 kJ.(CH2)2(CH)2CH2=CHCH=CH2The rate constant at 428 K is 2.88×10-4 /s. The rate constant will be 3.08×10-3 /s at K.arrow_forwardUnder certain conditions the reaction H2O2 + 3I + 2H*→ I3¯ + 2H2O occurs by the following series of steps: ki Step 1. H2O2+H* =H;O2" + with K (equilibrium constant) = k1/k-1 Step 2. H3O2* +I→ H2O + HOI (slow, rate constant k2) Step 3. HỘI + I→ OH¯ +I2 (fast, rate constant k3) Step 4. OH + H*→ H2O (fast, rate constant k4) Step 5. I2 + I→ 13 (fast, rate constant k5) Use approximations (RDS, eq, steady-state) if necessary The rate constant k for the reaction would be given byarrow_forward
- Consider this organic mechanism: 1 wwww. H c+ C C H-CI: ~ Does this mechanism describe an acid/base reaction? O Note for advanced students: we mean only acid- base reactions in the Brønsted-Lowry sense. Which reactants, if any, are acting as Brønsted- Lowry acids? Which reactants, if any, are acting as Brønsted- Lowry bases? If you said this mechanism does describe an acid- base reaction, draw the products of the reaction on the right-hand side above. X $ 2 C Yes! Certainly not. Who knows? We need more information to decide. 2 Click and drag to start drawing a structure. S ? 0 3 olo Ar 3:arrow_forwardCr.arrow_forwardFor the reactionMo(CO)6 + P(CH3)3----->Mo(CO)5P(CH3)3 + COthe proposed mechanism isMo(CO)6---->Mo(CO)5 + COMo(CO)5 + P(CH3)3----->Mo(CO)5P(CH3)3(a) Is the proposed mechanism consistent with the equationfor the overall reaction? (b) What is the molecularity of eachstep of the mechanism? (c) Identify the intermediate(s).arrow_forward
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