3) Given the following reaction:a) Draw the mechanism for the formation of two possible compounds, which are isomers.b) Illustrate what the methyl resonance(s) would look like in the proton spectrum of one isomer.c) Draw a mechanism for the reductive elimination from one of your two isomers.SMe2NCH3-1PtCH3

The reaction mechanism for the formation of two possible compounds, which are isomers, can be…

Answered: 3) Given the following reaction: a)…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter15: Radical Reactions

Section: Chapter Questions

Problem 13E

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3) Use the reaction shown below and the associated reaction energy diagram to answer the following questions. E A Но- + Br HO. Br- reaction coordinate a) In the space above, use curved arrows to show the mechanism of the reaction. b) Classify the reaction as either addition, elimination or substitution. c) In this reaction is hydroxide (HO-) acting as a nucleophile or as a base? c) Based on the reaction energy diagram, is the reaction endergonic or exergonic? d) Based on the reaction energy diagram, and assuming the reaction is reversible, would the equilibrium lie to the left or to the right? e) Which position on the reaction energy diagram (A, B or C) corresponds to the transition state?
027 In Part 1 add the curved arrows to the nucleophilic acyl substitution reaction mechanism. In Part 2, answer the multiple-choice question about the reaction in Part 1. Part 1 4 See Periodic Table O See Hint :0: :Br: Add the missing curved arrow notation. S CI Br Part 2 Which statement is most correct regarding the equilibrium for the above reaction? Choose one: O The equilibrium favors the right (i.e., Kea > 1) because acetate is a better leaving group than bromide. O The equilibrium favors the right (i.e., Kea > 1) because bromide is a better leaving group than acetate. O The equilibrium favors the left (i.e., Keq« 1) because acetate is a better leaving group than bromide. O The equilibrium favors the left (i.e., Keg 1) because bromide is a better leaving group than acetate. +
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Consider the reduction of 4-nitrobenzaldehyde using sodium borohydride, NaBH4 in ethanol: what happen at initial step 1) a hydride ion attacks the carbonyl group's carbon atom 2)a hydride ion attacks the nitro group's nitrogen atom 3) a sodium ion attacks the carbonyl groups oxygen atom 4) a sodium ion attacks a nitro group's oxygem atom
don 13. (1) Draw the (E)- and (Z)- isomers of 1,3-dichloro-2-methylbut-2-ene. Using curved arrows, draw (a) an SN2 mechanism and (b) and SN1 mechanism for the substitution reaction shown below. Br ) Draw the organic product(s) formed in the following reactions: 1)0, by 2) Zn. H,0 MShow a sequence of reactions that could be used to synthesize the following compound. You must start from 3-pentanol. No mechanisms needed (HINT: You wil need to bring together more than one of the reactions you have seen in Modules 3 and 4]
Choose the best explanation for the proposed curved arrow mechanism for an electrophilic addition reaction of butadiene with HBr.
Which statement is true concerning the two carbocations formed by the protonation (attachment of an H*) of 2-methylpropene? a) The activation energy associated with the primary carbocation intermediate is less than the activation energy associated with the tertiary carbocation. b) The rate of the formation of the tertiary carbocation is less (slower) than the rate of the formation of the primary carbocation. c) The activation energy and the rate of formation associated with the formation of the primary carbocation is greater. d) The activation energy is greater for the formation of the primary carbocation but its rate of formation is less. O a O b
b) This question refers to the following reaction: Br Но CH, C-CH3 ČH3 F i) Determine whether the main reaction to form F is a substitution or an elimination reaction. Explain your choice in no more than two sentences. ii) Draw the structure of the product F. iii) What is the mechanism of the above reaction (i.e. SN1, SN2, E1 or E2)? Explain your choice in one sentence based on your answer in (i) above. iv) Using curly arrows show the mechanism for the reaction to give F.
Draw the curved arrow(s) to depict the formation of the keto form of an enolate ion via a strong base, B. Complete the resonance structures of the enolate anion\'s keto and enolate forms with bonds, charges, and nonbonding electron pairs. Use curved arrows to show how the keto form resonates to the enolate form.
2. Draw the mechanism of the following reaction. Show how all of the following products form. Determine the function of the reagent. Br CH;OH
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