14 helit ds pod 1. B gh 2.1-buOK S. BH, in THE 4 Ho, NaOH (8) BH (A) 114 (B) (C) (D) OH

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter24: Amines And Heterocycles
Section24.SE: Something Extra
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Predit ds produc
1. Br ght
2.1-BuOK
38 Which represet soy depis
2mthyleyclohexeol where the wo
ubatitum are
S.BH, in THE
4 HO, NaOH
(A)
(m)
CH
(A)
1014
(B)
BH
CH
OH
(C)
(D)
(9 O
он
(D)
25.
What radical interediate is fonmed in
CHa
this reaction?
CH
HC
2
HOOH
H,C
30
Which molecules sre chiral?
H.
hv
HO
(m)
COH
Br
(C)
HO
(D)
HO V
26.
Predict the product
OH
SOci
II
IV
(A) 1,II, II, & IV
(C) H& II
pyridine
(B) II, II, A IV
(D) I1& IV
(A)
(B)
CI
31.
Explain why this synthetic route will not
produce this product.
şoCi
1) CHMgr
2) HHP
(C)
(D)
SOCI
H,HO
heal
Which reagents produce this
transformation?
27.
(A) The Grigrard reagent will not add
to the ketone.
OH
HO.
(B) The Grignard reagent will not add
to the alcohol.
(A) 1) LIAIH
2) H, H;0
(C) The Markovnikov rule will lead to
a different product.
(B) NABH,, HO
(D) Acid catalyzed dehydration will lead to
the formation of the more
(C) PCC, CH,Cl;
(D) KMNO, NaOH, H;O, heat
thermodynamically stable alkene.
What is the formal
charge of oxygen
in this molecule?
28.
A) -1
(B) +1
(D) +6
Page 5 of 12
Transcribed Image Text:Predit ds produc 1. Br ght 2.1-BuOK 38 Which represet soy depis 2mthyleyclohexeol where the wo ubatitum are S.BH, in THE 4 HO, NaOH (A) (m) CH (A) 1014 (B) BH CH OH (C) (D) (9 O он (D) 25. What radical interediate is fonmed in CHa this reaction? CH HC 2 HOOH H,C 30 Which molecules sre chiral? H. hv HO (m) COH Br (C) HO (D) HO V 26. Predict the product OH SOci II IV (A) 1,II, II, & IV (C) H& II pyridine (B) II, II, A IV (D) I1& IV (A) (B) CI 31. Explain why this synthetic route will not produce this product. şoCi 1) CHMgr 2) HHP (C) (D) SOCI H,HO heal Which reagents produce this transformation? 27. (A) The Grigrard reagent will not add to the ketone. OH HO. (B) The Grignard reagent will not add to the alcohol. (A) 1) LIAIH 2) H, H;0 (C) The Markovnikov rule will lead to a different product. (B) NABH,, HO (D) Acid catalyzed dehydration will lead to the formation of the more (C) PCC, CH,Cl; (D) KMNO, NaOH, H;O, heat thermodynamically stable alkene. What is the formal charge of oxygen in this molecule? 28. A) -1 (B) +1 (D) +6 Page 5 of 12
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