1. Which of the following is true for 0.10 M solution of a weak acid, HA at equilibrium? (a) pOH = 12 Ⓒ both b and d (b) [H] 0.10 M HA HA]> |> [H*] (d) pH = 1.0
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- 8-112 Consider an initial 0.040 M hypobromous acid (HOBr) solution at a certain temperature. At equilibrium after partial dissociation, its pH is found to be 5.05. What is the acid ionization constant, Ka, for hypobromous acid at this temperature?You have a solution of the weak acid HA and add some HCl to it. What are the major species in the solution? What do you need to know to calculate the pH of the solution, and how would you use this information? How does the pH of the solution of just the HA compare with that of the final mixture? Explain.Write the Lewis structures of the reactants and product of each of the following equations, and identify the Lewis acid and the Lewis base in each: (a) CS2+SHHCS3 (b) BF3+FBF4 (c) I+SnI2SnI3 (d) Al(OH)3+OHAl(OH)4 (e) F+SO3SFO3
- For conjugate acidbase pairs, how are Ka and Kb related? Consider the reaction of acetic acid in water CH3CO2H(aq)+H2O(l)CH3CO2(aq)+H3O+(aq) where Ka = 1.8 105 a. Which two bases are competing for the proton? b. Which is the stronger base? c. In light of your answer to part b. why do we classify the acetate ion (CH3CO2) as a weak base? Use an appropriate reaction to justify your answer. In general, as base strength increases, conjugate acid strength decreases. Explain why the conjugate acid of the weak base NH3 is a weak acid. To summarize, the conjugate base of a weak acid is a weak base and the conjugate acid of a weak base is a weak acid (weak gives you weak). Assuming Ka for a monoprotic strong acid is 1 106, calculate Kb for the conjugate base of this strong acid. Why do conjugate bases of strong acids have no basic properties in water? List the conjugate bases of the six common strong acids. To tie it all together, some instructors have students think of Li+, K+, Rb+, Cs+, Ca2+, Sr2+, and Ba2+ as the conjugate acids of the strong bases LiOH, KOH. RbOH, CsOH, Ca(OH)2, Sr(OH)2, and Ba(OH)2. Although not technically correct, the conjugate acid strength of these cations is similar to the conjugate base strength of the strong acids. That is, these cations have no acidic properties in water; similarly, the conjugate bases of strong acids have no basic properties (strong gives you worthless). Fill in the blanks with the correct response. The conjugate base of a weak acid is a_____base. The conjugate acid of a weak base is a_____acid. The conjugate base of a strong acid is a_____base. The conjugate acid of a strong base is a_____ acid. (Hint: Weak gives you weak and strong gives you worthless.)What is the freezing point of vinegar, which is an aqueous solution of 5.00% acetic acid, HC2H3O2, by mass (d=1.006g/cm3)?. Which component of a buffered solution is capable of combining with an added strong acid? Using your example from Exercise 60, show how this component would react with added HC1.
- Consider a 0.33 M solution of the diprotic acid H2X. H2X H+(aq)+ HX(aq)Ka1=3.3 10 4 HX H+(aq)+ X2(aq)Ka2=9.7 10 8 Calculate the pH of the solution and estimate [HX-] and [X2-].You are asked to calculate the H+ concentration in a solution of NaOH(aq). Because sodium hydroxide is a base, can we say there is no H+. since having H+ would imply that the solution is acidic?Benzoic acid (K a=6.6105)is present in many berries. Calculate the pH and % ionization of a 726-mL solution that contains 0.288 mol of benzoic acid.
- . How is the strength of an acid related to the fact that a competition for protons exists in aqueous solution between water molecules and the anion of the acid?The pH of a 0.20-M solution of HP is 1.92. Determine Ka far HF from these data.For oxyacids, how does acid strength depend on a. the strength of the bond to the acidic hydrogen atom? b. the electronegativity of the element bonded to the oxygen atom that bears the acidic hydrogen? c. the number of oxygen atoms? How does the strength of a conjugate base depend on these factors? What type of solution forms when a nonmetal oxide dissolves in water? Give an example of such an oxide. What type of solution forms when a metal oxide dissolves in water? Give an example of such an oxide.