Tutorial 10 - Selectivity and Reactivity of Enolate Reaction Worksheet 1. Predict the products that result when 2-cyclohexen-1-one is reacted with the following reagents. FL A NaCN, HCN 5-10 °C 1) (CH3CH2)2CuLi 2) H3O+ B PhNH2, toluene E 1) nBuLi, Et₂O 2) H3O+ 1) PhCH2MgBr 2) H3O+ OMe NaOMe, HOME
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- Reagent 3 list; commas separate the choices benzylamine,cyclohexlbromide, cyclohexylamine NaBH3CN catalytic H+, h30, NaOH Reagent 4 list; CH3(Ch2)2MgBr, cyclohexylamine NaBH3CN catalytic H+, Na2 Cr2 O7 H2O H2SO4,cyclohexabromide reagent 5 list; cyclohexylamine NaBH3CN catalytic H+,CH3(Ch2)2MgBr, cyclohexabromide, benzylaminePredict the major products A- N for each of the following reactions. он NAOH 1) O3 D concd. H2SO4 в + heat 2) H2S 180°C NH,NH2 Кон (CH3)2CHOH Br2/FeBr3 KMNO4 F heat NaOH LIAIH4 SOCI, CH3O'Na* > K Br HBr K* "OC(CH3)3 t-BUOH ROOR (peroxide) Na* OCH3 CH3OHlotu PREDICT THE FINAL SEQUENCE OF REACTIONSSIL A) H-CEC-H n Navita B) H-CC-H 2) Mez 3) R2BH 4112021 NaOH 1) NaNz 2) Me D 3) NaNH2 4)6+2 5) Na, NH3 (1) 4.
- The following series of reactions will yield ___________. 1) CH3CH2SH + NaOH 2) Cl-CH2-CH2-C6H5 ortho-chloro-ethyl-benzene 2-chloro-4-ethyl-benzenesulfonic acid CH3CH2-S-CH2CH2C6H5 1-phenyl-3-chloro-propane CH3CH2-O-CH2CH2C6H5 Thank you!Choose the best reagents to complete the reaction shown below. HO 0= 0= OH e A B C D E 1.03 2. HOẠC mCPBA 2. H3O+ 1. Hg(OAc)2, H₂O 2. NaBH4, NaOH RCO3H 1. OsO4 (catalytic),Question 13 Propose best Williamson ether syntheses for the following compounds. Select all applicable options (multiple answers can be possible). Note: Some compounds cannot be made using Williamson synthesis reaction. ΚΗ A: + ⚫OH ΕΘ OK SN2 KH ΘΘ + -Br B: -OH OK SN1 C: ☐ A B ☐ C Cannot be synthesized using Williamson ether syntheses.
- What sequence of reactions will transform the starting material shown into the product? N' 1) SOCI, 2) NaCN 3) H2, Raney Ni 4) CH3I (2 eq) (CH;CH2),NH, HCI (cat.), NaBH3CN 1) SOCI, 2) (CH3CH2),NH (> 2 eq) 3) LİAIH4 4) H30+ 1) LİAIH4 2) H3O+ 3) (CH3CH2)2NH , HCI (cat.), NaBH3CNPropose best Williamson ether syntheses for the following compounds. Select all applicable options (multiple answers can be possible). Note: Some compounds cannot be made using Williamson synthesis reaction. ـيـة A: -OH Na Na Br -Br SN2 Na CI B: -OH C: B ☐ C -CI Na O SN1 Cannot be synthesized using Williamson ether syntheses. MacBook Air 80 000 AA DII F3 F4 F5 F6 F7 F8 DD F9The following series of reactions will yield 2) CI-CH2-CH2-C6H5 1) CH3CH2SH + N2OH O 2-chloro-4-ethyl-benzenesulfonic acid O CH;CH2-S-CH2CH2C6H5 O ortho-chloro-ethyl-benzene O 1-phenyl-3-chloro-propane O CH3CH2-O-CH2CH2C6H5
- Question 14 Propose best Williamson ether syntheses for the following compounds. Select all applicable options (multiple answers can be possible). Note: Some compounds cannot be made using Williamson synthesis reaction. همه ΚΗ A: LOH ΘΘ OK Br SN2 Br NaH B: ⚫OH -ONa SN2 C: A B C Cannot be synthesized using Williamson ether syntheses.1) LiAlH4; ) H3O+ will do which of the following reactions? 3-Phenyl-butanoic acid → 3-phenyl-butan-1-ol Benzene → cyclohexane Benzoic acid → benzaldehyde 2-Phenyl-hexanoic acid → benzoic acid and carbon dioxide 2,3-dimethyl-pent-1-yne → 2,3-dimethyl-pent-1-eneucf.edu/courses/1379813/quizzes). Question 12 Identify the major product from the following series of reactions. 1. NaOEt 1. NaOEt 2. CH3CH2CI OEt 2. H30*, Quendch 3. H30*, Heat но он HO H.