Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Draw the major organic product for each of the following reactions. You must show the correct stereochemistry of the product where relevant.
Transcribed Image Text:### Organic Chemistry Reactions
This diagram outlines several organic chemistry reactions, each with a specific reactant, reagent, and resulting product, as detailed below:
1. **Reaction 1:**
- **Reactant:** An alkyne with a terminal propyl group.
- **Reagent:** 1 equivalent of chlorine gas (Cl₂).
- **Product:** The product likely features a dihalide addition, resulting in a chlorinated alkene or geminal dihalide.
2. **Reaction 2:**
- **Reactant:** An alkyne with a linear butyl group.
- **Reagent:** H₃O⁺/HgSO₄ (mercuric sulfate in acidic solution).
- **Product:** This typically results in the hydration of the alkyne to form a ketone through keto-enol tautomerism.
3. **Reaction 3:**
- **Reactant:** Iodobenzene.
- **Reagent:** Lithium diethylcuprate (\((CH₃)₂CuLi\)) in ether.
- **Product:** This is a Gilman reagent reaction, which substitutes the iodine with an ethyl group, forming ethylbenzene.
4. **Reaction 4:**
- **Reactant:** An alkyne with a phenyl group.
- **Reagent:** Hydrogen gas (H₂) in the presence of Lindlar's catalyst.
- **Product:** This results in syn-addition of hydrogen to form a cis-alkene, specifically cis-stilbene.
Each product is represented by an empty box, indicating the position for the structure of the resulting chemical compound.
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