Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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**Transcription and Explanation for Educational Use:**

---

**Instructions:**
10. For each set of reactions, 1) identify the reaction mechanism as \( S_N1 \), \( S_N2 \), E1, and/or E2 (write in box at left), 2) fill in the missing reactants, reagents, or major product(s), and 3) provide a curved-arrow mechanism. Make sure to include relevant stereochemistry.

---

### Reaction Set 1:

**Reactant:**
- A benzyl bromide compound with a double bond in the alkene group.

**Reagents:**
- Sodium chloride (NaCl) in the presence of water (\( H_2O \)).

**Mechanism Type:**
- A box to determine whether it's \( S_N1 \), \( S_N2 \), E1, or E2.

**Requirements:**
- Determine the product and provide the mechanism with sterochemistry.

---

### Reaction Set 2:

**Reactant:**
- A tert-butoxide ion in dichloromethane (\( CH_2Cl_2 \)).

**Product:**
- An alkene with two methyl groups on the first carbon.

**Mechanism Type:**
- A box to decide if it's \( S_N1 \), \( S_N2 \), E1, or E2.

**Requirements:**
- Identify missing reactants/reagents and demonstrate the mechanism.

---

### Reaction Set 3:

**Reactant:**
- A cyclopentyl chloride with an explicit stereochemistry showing wedge bonds.

**Reagents:**
- Sodium cyanide (\( NaCN \)) in dimethylformamide (DMF).

**Mechanism Type:**
- A box to specify \( S_N1 \), \( S_N2 \), E1, or E2.

**Requirements:**
- Predict product and explain with a curved-arrow mechanism considering stereochemistry.

---

### Reaction Set 4:

**Reactant:**
- Cyclohexanol with an attached OH group.

**Reagents:**
- \( H^+ / H_2O \) with heat.

**Mechanism Type:**
- A box to label as \( S_N1 \), \( S_N2 \), E1, or E2.

**Requirements:**
- Determine the resulting product and describe the reaction mechanism.

---

### Reaction Set 5:

**Reactant:**
- A chlor
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Transcribed Image Text:**Transcription and Explanation for Educational Use:** --- **Instructions:** 10. For each set of reactions, 1) identify the reaction mechanism as \( S_N1 \), \( S_N2 \), E1, and/or E2 (write in box at left), 2) fill in the missing reactants, reagents, or major product(s), and 3) provide a curved-arrow mechanism. Make sure to include relevant stereochemistry. --- ### Reaction Set 1: **Reactant:** - A benzyl bromide compound with a double bond in the alkene group. **Reagents:** - Sodium chloride (NaCl) in the presence of water (\( H_2O \)). **Mechanism Type:** - A box to determine whether it's \( S_N1 \), \( S_N2 \), E1, or E2. **Requirements:** - Determine the product and provide the mechanism with sterochemistry. --- ### Reaction Set 2: **Reactant:** - A tert-butoxide ion in dichloromethane (\( CH_2Cl_2 \)). **Product:** - An alkene with two methyl groups on the first carbon. **Mechanism Type:** - A box to decide if it's \( S_N1 \), \( S_N2 \), E1, or E2. **Requirements:** - Identify missing reactants/reagents and demonstrate the mechanism. --- ### Reaction Set 3: **Reactant:** - A cyclopentyl chloride with an explicit stereochemistry showing wedge bonds. **Reagents:** - Sodium cyanide (\( NaCN \)) in dimethylformamide (DMF). **Mechanism Type:** - A box to specify \( S_N1 \), \( S_N2 \), E1, or E2. **Requirements:** - Predict product and explain with a curved-arrow mechanism considering stereochemistry. --- ### Reaction Set 4: **Reactant:** - Cyclohexanol with an attached OH group. **Reagents:** - \( H^+ / H_2O \) with heat. **Mechanism Type:** - A box to label as \( S_N1 \), \( S_N2 \), E1, or E2. **Requirements:** - Determine the resulting product and describe the reaction mechanism. --- ### Reaction Set 5: **Reactant:** - A chlor
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