Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Please predict the products for each of the following reactions.
Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).
If a mixture of enantiomers is formed, please draw all the enantiomers.
OA
OB
C
A
Br2
CH₂OH
1. 03
2. DMS
KMnO4, NaOH
cold
HI
H₂
Pd or Pt (catalyst)
HBr
20
2
17
mCPBA
1. OsO4
2. H₂O2
CH.COSH
(peroxyacid)
MCPBA
H3O+
16
13.
12 11
3
HBr
ROOR (peroxide)
H₂O
H₂SO4
HCI
1. BH, THF
2. H₂O2, NaOH
Br₂
Br2
H₂O
BH3⚫THF
Bra
Pd or Ni (
Ni (catalyst)
D2 (deuterium)
FIOH
B
C
D
Br
Br
Br
Br
Br
Br
Br
xx
Br
"Br
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Transcribed Image Text:Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. OA OB C A Br2 CH₂OH 1. 03 2. DMS KMnO4, NaOH cold HI H₂ Pd or Pt (catalyst) HBr 20 2 17 mCPBA 1. OsO4 2. H₂O2 CH.COSH (peroxyacid) MCPBA H3O+ 16 13. 12 11 3 HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH, THF 2. H₂O2, NaOH Br₂ Br2 H₂O BH3⚫THF Bra Pd or Ni ( Ni (catalyst) D2 (deuterium) FIOH B C D Br Br Br Br Br Br Br xx Br "Br
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