Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Question
Chapter 9, Problem 9.22QE
Interpretation Introduction
Interpretation:
The reason behind the exact measurement of
Concept Introduction:
The bond dissociation energy or bond energy
The equation that describes the bond dissociation for
Bond dissociation energies are endothermic and have a positive sign. It takes energy to break a bond.
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Define the terms bond enthalpy and mean bond enthalpy.Use examples to illustrate the difference between the two quantities.
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In chemical reactions, heat is converted into chemical energy (the potential energy stored
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Part A
Calculate the bond energy per mole for breaking all the bonds in methane, CH4.
ΔΗ
Σ(ΔΗ breaking) + Σ(ΔΗ forming)
Express your answer to four significant figures and include the appropriate units.
where H represents bond energies for the breaking (positive bond energy) or forming
(negative bond energy) of a bond and Hrxn represents the overall enthalpy for the
• View Available Hint(s)
reaction.
Use the table to answer questions about bond energies.
HẢ
Bond energy
Bond
(kJ/mol )
Value
Units
AHCH, =
C-C
347
C=C
611
Submit
Сн
414
C-O
360
Part B
C=OinCO2
799
O-0
142
Calculate the bond…
Chapter 9 Solutions
Chemistry: Principles and Practice
Ch. 9 - Prob. 9.1QECh. 9 - Prob. 9.2QECh. 9 - Prob. 9.3QECh. 9 - What main factors control the magnitude of lattice...Ch. 9 - Prob. 9.5QECh. 9 - Prob. 9.6QECh. 9 - Prob. 9.7QECh. 9 - Prob. 9.8QECh. 9 - Prob. 9.9QECh. 9 - Prob. 9.10QE
Ch. 9 - Prob. 9.11QECh. 9 - Prob. 9.12QECh. 9 - Prob. 9.13QECh. 9 - Compare the trends in electronegativity and...Ch. 9 - Prob. 9.15QECh. 9 - Prob. 9.16QECh. 9 - Prob. 9.17QECh. 9 - What elements are most likely to form...Ch. 9 - Prob. 9.19QECh. 9 - Prob. 9.20QECh. 9 - Prob. 9.21QECh. 9 - Prob. 9.22QECh. 9 - Prob. 9.23QECh. 9 - Prob. 9.24QECh. 9 - Prob. 9.25QECh. 9 - Prob. 9.26QECh. 9 - Write the formulas of the ionic compounds that...Ch. 9 - Prob. 9.28QECh. 9 - Prob. 9.29QECh. 9 - Prob. 9.30QECh. 9 - Arrange the following series of compounds in order...Ch. 9 - Prob. 9.32QECh. 9 - Prob. 9.33QECh. 9 - Prob. 9.34QECh. 9 - Prob. 9.35QECh. 9 - Draw Lewis structures for the following species....Ch. 9 - Prob. 9.37QECh. 9 - Prob. 9.38QECh. 9 - Write the Lewis structure for the following...Ch. 9 - Prob. 9.40QECh. 9 - Prob. 9.41QECh. 9 - Draw a Lewis structure for each of the following...Ch. 9 - Write the Lewis structure for each compound, with...Ch. 9 - Prob. 9.44QECh. 9 - Prob. 9.45QECh. 9 - Write the Lewis structure for each species, with...Ch. 9 - Prob. 9.47QECh. 9 - Prob. 9.48QECh. 9 - Prob. 9.49QECh. 9 - Arrange the members of each of the following sets...Ch. 9 - Prob. 9.51QECh. 9 - Prob. 9.52QECh. 9 - Prob. 9.53QECh. 9 - For each pair of bonds, indicate the more polar...Ch. 9 - Which molecule has the most polar bond: N2, BrF,...Ch. 9 - Given the bonds C N, C H, C Br, and S O, (a)...Ch. 9 - Prob. 9.57QECh. 9 - Prob. 9.58QECh. 9 - Write the Lewis structures showing formal charge...Ch. 9 - Write the Lewis structures showing formal charge...Ch. 9 - Prob. 9.61QECh. 9 - The connectivity of HNO could be either HNO or...Ch. 9 - Prob. 9.63QECh. 9 - Prob. 9.64QECh. 9 - Write all possible resonance structures for the...Ch. 9 - Prob. 9.66QECh. 9 - Prob. 9.67QECh. 9 - Prob. 9.68QECh. 9 - Prob. 9.69QECh. 9 - Prob. 9.70QECh. 9 - Write all resonance structures of toluene,...Ch. 9 - Write all resonance structures of chlorobenzene,...Ch. 9 - Draw all resonance structures for...Ch. 9 - Prob. 9.74QECh. 9 - Prob. 9.75QECh. 9 - Prob. 9.76QECh. 9 - Write the Lewis structures for the following...Ch. 9 - Write the Lewis structures for the following...Ch. 9 - Prob. 9.79QECh. 9 - Prob. 9.80QECh. 9 - Prob. 9.81QECh. 9 - Prob. 9.82QECh. 9 - Write the Lewis structures of H2CNH and H3CNH2....Ch. 9 - Write the Lewis structures of HNNH and H2NNH2....Ch. 9 - Prob. 9.85QECh. 9 - Prob. 9.86QECh. 9 - Prob. 9.87QECh. 9 - Prob. 9.88QECh. 9 - Prob. 9.89QECh. 9 - Prob. 9.90QECh. 9 - Prob. 9.91QECh. 9 - Prob. 9.92QECh. 9 - Prob. 9.93QECh. 9 - Prob. 9.94QECh. 9 - Prob. 9.95QECh. 9 - Prob. 9.96QECh. 9 - Prob. 9.97QECh. 9 - Prob. 9.98QECh. 9 - The molecule nitrosyl chloride, NOCl, has a...Ch. 9 - Prob. 9.100QECh. 9 - Draw the Lewis structure of BrNO. Which is the...Ch. 9 - Prob. 9.102QECh. 9 - Calculate an approximate enthalpy change (Table...Ch. 9 - Prob. 9.104QECh. 9 - Prob. 9.105QECh. 9 - Prob. 9.106QECh. 9 - Prob. 9.107QE
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- hat is the enthalpy change for a process? Is enthalpy a state function? In what experimental apparatus are enthalpy changes measured?arrow_forwardWhich statement(s) is/are true about bond enthalpy? (a) The bond energy for a triple bond between A and B is three times that of a single bond between A and B. (b) H for the breaking of a bond is always a negative number. (c) Energy is required to make a bond. (d) Bond enthalpy is defined only for bonds broken or formed in the gaseous state. (e) The presence of bonds does not influence the geometry of a molecule. However, the presence of bonds affects the value of the bond enthalpy between two atoms.arrow_forwardThe bond energy for a CH bond is about 413 kJ/mol in CH4 but 380 kJ/mol in CHBr3. Although these values are relatively close in magnitude, they are different. Explain why they are different. Does the fact that the bond energy is lower in CHBr3, make any sense? Why?arrow_forward
- Bond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?arrow_forwardhat does temperature measure? Are the molecules in a beaker of warm water moving at the same speed as the molecules in a beaker of cold water? Explain? What is heat? Is heat the same as temperature?arrow_forwardUsing the standard enthalpy of formation data in Appendix G, show how the standard enthalpy of formation of HCl(g) can be used to determine the bond energy.arrow_forward
- Compare your answers from parts a and b of Exercise 69 of Chapter 3 with H values calculated for each reaction using standard enthalpies of formation in Appendix 4. Do enthalpy changes calculated from bond energies give a reasonable estimate of the actual values?arrow_forwardExplain the decomposition of nitroglycerin in terms of relative bond enthalpies.arrow_forwardWhen a molecule can form two different structures, the structure with the stronger bonds is usually the more stable form. Use bond energies to predict the correct structure of the hydroxylamine molecule:arrow_forward
- 8) In an exothermic reaction, the enthalpy of the reaction can be calculated by a. Subtracting the sum of all the bond energies of the products from the sum of all the bond energies of the reactants. b. Subtracting the sum of all the bond energies of the reactants from the sum of all the bond energies of the products c. Finding the sum of the enthalpies of formation of all the products and reactants together d. All of the abovearrow_forwardDefine the term lattice energy?arrow_forwardWhat is the enthalpy of formation of any structure in the figure, or any structure that contains the same group?arrow_forward
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