Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 10, Problem 10.72QE
(a)
Interpretation Introduction
Interpretation:
Picture that shows overlap of
(b)
Interpretation Introduction
Interpretation:
Picture that shows overlap of
(c)
Interpretation Introduction
Interpretation:
Picture that shows overlap of
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For each statement, indicate whether it is true or false. (a) The greater the orbital overlap in a bond, the weaker the bond. [b] The greater the orbital overlap in a bond, the shorter the bond. [c] To create a hybrid orbital, you could use the s orbital on one atom with a p orbital on another atom. [d] Nonbonding electron pairs cannot occupy a hybrid orbital.
Which of the following statements is INCORRECT?
(1)
In the hybridized state, mixing of the 2s orbitals with the 2px, 2py and/or 2pz
orbitals can give sp, sp2 or sp3 hybrid orbitals.
(2)
A sp3 hybrid orbital is formed from one s-orbital and three p-orbitals to give a
total of four orbitals.
(3)
There are no unhybrized orbitals when carbon is sp3 hybridized.
(4)
There are no unhybrized orbitals when carbon is sp2 hybridized.
Use valence bond theory to explain the bonding in F2, HF, and ClBr.
(a)
F2
This molecule is symmetrical. The single bond present in this molecule is derived from the overlap of two (1s, 2s, 2p, 3s, 3d, 3p, 4s, 4d, 4p) orbitals contributed by each of the F atoms.
(b)
HF
This molecule is asymmetrical. The single bond present in this molecule is derived from the overlap of one (1s, 2s, 2p, 3s, 3d, 3p, 4s, 4d, 4p) orbital contributed by the H atom and one (1s, 2s, 2p, 3s, 3d, 3p, 4s, 4d, 4p) orbital contributed by the F atom.
(c)
ClBr
This molecule is also asymmetrical. The single bond present in this molecule is derived from the overlap of one (1s, 2s, 2p, 3s, 3d, 3p, 4s, 4d, 4p) orbital contributed by the Cl atom and one (1s, 2s, 2p, 3s, 3d, 3p, 4s, 4d, 4p) orbital contributed by the Br atom.
Sketch the overlap of the atomic orbitals involved in the bonds.
Chapter 10 Solutions
Chemistry: Principles and Practice
Ch. 10 - Prob. 10.1QECh. 10 - Prob. 10.2QECh. 10 - Prob. 10.3QECh. 10 - Prob. 10.4QECh. 10 - Prob. 10.5QECh. 10 - Prob. 10.6QECh. 10 - Prob. 10.7QECh. 10 - Prob. 10.8QECh. 10 - Prob. 10.9QECh. 10 - Prob. 10.10QE
Ch. 10 - Which atomic orbitals overlap to form the bonds in...Ch. 10 - Prob. 10.12QECh. 10 - Identify the hybrid orbitals used by boron in BCl3...Ch. 10 - Identify the hybrid orbitals used by antimony in...Ch. 10 - Prob. 10.15QECh. 10 - Prob. 10.16QECh. 10 - Prob. 10.17QECh. 10 - Prob. 10.18QECh. 10 - Prob. 10.19QECh. 10 - Prob. 10.20QECh. 10 - Compare and contrast the molecular orbital and...Ch. 10 - Describe the bonding in molecular orbital terms...Ch. 10 - Prob. 10.23QECh. 10 - Prob. 10.24QECh. 10 - Prob. 10.25QECh. 10 - Prob. 10.26QECh. 10 - Prob. 10.27QECh. 10 - Prob. 10.28QECh. 10 - Prob. 10.29QECh. 10 - Prob. 10.30QECh. 10 - Prob. 10.31QECh. 10 - Prob. 10.32QECh. 10 - Prob. 10.33QECh. 10 - Prob. 10.34QECh. 10 - Prob. 10.35QECh. 10 - Prob. 10.36QECh. 10 - Prob. 10.37QECh. 10 - Prob. 10.38QECh. 10 - Prob. 10.39QECh. 10 - Use the VSEPR model to predict the bond angles...Ch. 10 - Prob. 10.41QECh. 10 - Prob. 10.42QECh. 10 - For each of the following molecules, complete the...Ch. 10 - Prob. 10.44QECh. 10 - Prob. 10.45QECh. 10 - Prob. 10.46QECh. 10 - Indicate which molecules are polar and which are...Ch. 10 - Prob. 10.48QECh. 10 - Indicate which of the following molecules are...Ch. 10 - Prob. 10.50QECh. 10 - Prob. 10.51QECh. 10 - Prob. 10.52QECh. 10 - Prob. 10.53QECh. 10 - Prob. 10.54QECh. 10 - Prob. 10.55QECh. 10 - Prob. 10.56QECh. 10 - Prob. 10.57QECh. 10 - Prob. 10.58QECh. 10 - Prob. 10.59QECh. 10 - Prob. 10.60QECh. 10 - Prob. 10.61QECh. 10 - Prob. 10.62QECh. 10 - Prob. 10.63QECh. 10 - Prob. 10.64QECh. 10 - Prob. 10.65QECh. 10 - Prob. 10.66QECh. 10 - Prob. 10.67QECh. 10 - Prob. 10.68QECh. 10 - Prob. 10.69QECh. 10 - Prob. 10.70QECh. 10 - Prob. 10.71QECh. 10 - Prob. 10.72QECh. 10 - Identify the orbitals on each of the atoms that...Ch. 10 - Prob. 10.74QECh. 10 - Prob. 10.75QECh. 10 - How many sigma bonds and how many pi bonds are...Ch. 10 - Give the hybridization of each central atom in the...Ch. 10 - Prob. 10.78QECh. 10 - Prob. 10.79QECh. 10 - Prob. 10.80QECh. 10 - Prob. 10.81QECh. 10 - Predict the hybridization at each central atom in...Ch. 10 - Prob. 10.83QECh. 10 - Tetrafluoroethylene, C2F4, is used to produce...Ch. 10 - Prob. 10.85QECh. 10 - Prob. 10.86QECh. 10 - Prob. 10.87QECh. 10 - Prob. 10.88QECh. 10 - Prob. 10.89QECh. 10 - Prob. 10.90QECh. 10 - Prob. 10.91QECh. 10 - Prob. 10.92QECh. 10 - Prob. 10.93QECh. 10 - Prob. 10.94QECh. 10 - Prob. 10.95QECh. 10 - Prob. 10.96QECh. 10 - Prob. 10.97QECh. 10 - Prob. 10.98QECh. 10 - The molecular orbital diagram of NO shown in...Ch. 10 - The molecular orbital diagram of NO shown in...Ch. 10 - The molecular orbital diagram of NO shown in...Ch. 10 - Prob. 10.102QECh. 10 - Prob. 10.103QECh. 10 - Prob. 10.104QECh. 10 - Prob. 10.105QECh. 10 - Following are the structures of three isomers of...Ch. 10 - The ions ClF2 and ClF2+ have both been observed....Ch. 10 - Aspirin, or acetylsalicylic acid, has the formula...Ch. 10 - Aspartame is a compound that is 200 times sweeter...Ch. 10 - Prob. 10.110QECh. 10 - Prob. 10.111QECh. 10 - Calcium cyanamide, CaNCN, is used both to kill...Ch. 10 - Histidine is an essential amino acid that the body...Ch. 10 - Formamide, HC(O)NH2, is prepared at high pressures...Ch. 10 - Prob. 10.115QECh. 10 - Prob. 10.116QECh. 10 - Prob. 10.117QECh. 10 - Prob. 10.118QECh. 10 - Prob. 10.119QECh. 10 - Prob. 10.120QECh. 10 - Prob. 10.121QECh. 10 - Prob. 10.122QECh. 10 - Prob. 10.123QECh. 10 - Prob. 10.124QECh. 10 - Two compounds have the formula S2F2. Disulfur...Ch. 10 - Prob. 10.126QECh. 10 - Prob. 10.127QE
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