Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Question
Chapter 3.8, Problem 3.23YT
Interpretation Introduction
Interpretation:
The given equation has to be rewritten using Lewis structure; all the free radicals present have to be identified.
Concept Introduction:
Lewis structure: The bonding between atoms in a molecule satisfies the octet rule of valence electrons and the lone pairs also exist in the molecule. The electron is represented as dot.
Geometry: The spatial arrangement of atoms or group of atoms around the central atom defines the geometry of the compound. The geometry can be determined by constructing Lewis structure and VSEPR model.
Hybridization: The concept of mixing atomic orbitals into new hybrid orbitals that possess different shapes, size, and energy than the constituent atomic orbitals.
- Ø Lone-pair electrons are valence electrons that are not used in bonding.
- Ø A proton is positively charged hydrogen ion. A hybrid ion is a negatively charged hydrogen ion.
- Ø Formal charge = the number of valence electron – the number of electrons the atom has to itself (the entire lone pair electron and one – half of the bonding electrons).
- Ø Lewis structure indicates which atom is bonded together and show lone pairs and formal charge.
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Part A) Consider the structural changes that occur in the following molecules. Begin by drawing the best Lewis Structure for each of the following molecules. BH3 CH4 NH3 H2O HF
Part B)What are the ideal bond angles for each structure, and which are expected to be distorted? For the ones that are distorted look up on the internet and record their experimental values here:
Part C)According to Lewis and VSEPR theory, why do these changes occur?
Many free radicals combine to form molecules that do not contain any unpaired electrons. The driving force for the radical-
radical combination reaction is the formation of a new electron-pair bond.
Consider the chemical equation.
N(g)+NO(g) → NNO(g)
Write Lewis formulas for the reactant and product species in the chemical equation. Include nonbonding electrons.
N(g)
NO(g)
Select
Draw
Rings
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Erase
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Rings
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N
Question Source: McQuarrie, Rock, And Gallogly 4e - General Chemsitry Publisher: University Science Books
of
Use this condensed chemical structure to complete the table below.
CH, — CH —
CH,
The condensed chemical structure of isobutane
1
CH,
Some facts about the isobutane molecule:
number of carbon-carbon single (C C) bonds:
number of carbon-hydrogen single (C - H) bonds:
number of carbon-carbon double (C = C) bonds:
Explanation
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Chapter 3 Solutions
Chemistry In Context
Ch. 3.1 - Prob. 3.2YTCh. 3.1 - Using Equation 3.1, answer the following...Ch. 3.1 - Prob. 3.4YTCh. 3.1 - Prob. 3.5YTCh. 3.1 - Scientific Practices Energy from the Sun Examine...Ch. 3.2 - Skill Building Wavelength, Frequency, and Energy...Ch. 3.3 - Skill Building The ABCs of Solar UV a. Arrange...Ch. 3.3 - Prob. 3.9YTCh. 3.4 - Prob. 3.10YTCh. 3.4 - You Decide Exposure Examine the curve shown in...
Ch. 3.4 - Prob. 3.12YTCh. 3.4 - Prob. 3.13YTCh. 3.5 - Prob. 3.14YTCh. 3.5 - Prob. 3.15YTCh. 3.6 - Prob. 3.16YTCh. 3.7 - Draw the Lewis structure for each molecule. a. HBr...Ch. 3.7 - Prob. 3.18YTCh. 3.7 - Prob. 3.19YTCh. 3.7 - You Decide The Ozone Layer Based on the reactions...Ch. 3.8 - Prob. 3.21YTCh. 3.8 - Prob. 3.22YTCh. 3.8 - Prob. 3.23YTCh. 3.8 - Prob. 3.24YTCh. 3.9 - Prob. 3.25YTCh. 3.10 - Prob. 3.26YTCh. 3.10 - Prob. 3.27YTCh. 3.10 - Prob. 3.28YTCh. 3.10 - Prob. 3.29YTCh. 3.11 - Skill Building Particulate Classification An...Ch. 3.11 - Prob. 3.31YTCh. 3.11 - Prob. 3.32YTCh. 3.11 - Prob. 3.33YTCh. 3.11 - Scientific Practices UV Interactions with Matter...Ch. 3 - How does ozone differ from oxygen in its chemical...Ch. 3 - Prob. 2QCh. 3 - Prob. 3QCh. 3 - Prob. 4QCh. 3 - Prob. 5QCh. 3 - a. What is a Dobson unit? b. Does a reading of 320...Ch. 3 - Using the periodic table as a guide, specify the...Ch. 3 - Consider this representation of a periodic table....Ch. 3 - Give the name and symbol for the element with this...Ch. 3 - Prob. 10QCh. 3 - Assuming that the octet rule applies, draw the...Ch. 3 - Prob. 12QCh. 3 - Consider these two waves representing different...Ch. 3 - Use Figure 3.4 to specify the region of the...Ch. 3 - What determines the color of light? Describe the...Ch. 3 - Prob. 16QCh. 3 - Does all light travel at the same speed in a...Ch. 3 - Arrange these types of radiation in order of...Ch. 3 - The microwaves in home microwave ovens have a...Ch. 3 - Ultraviolet radiation is categorized as UVA, UVB,...Ch. 3 - Calculate the wavelength, in nanometers, of the...Ch. 3 - The distance from Earth to the Sun is about 1.50 ...Ch. 3 - Draw Lewis structures for any two different CFCs.Ch. 3 - Prob. 24QCh. 3 - Prob. 25QCh. 3 - Prob. 26QCh. 3 - The following free radicals all play a role in...Ch. 3 - a. How were the original measurements of increases...Ch. 3 - Prob. 29QCh. 3 - The EPA has used the slogan Ozone: Good Up High,...Ch. 3 - Nobel Laureate F. Sherwood Rowland referred to the...Ch. 3 - Prob. 32QCh. 3 - Prob. 33QCh. 3 - Prob. 34QCh. 3 - Prob. 35QCh. 3 - The average length of an OO single bond is 132 pm....Ch. 3 - Prob. 37QCh. 3 - Describe why ozone is more reactive than oxygen...Ch. 3 - Prob. 39QCh. 3 - Prob. 40QCh. 3 - Prob. 41QCh. 3 - All the reports of the damage caused by UV...Ch. 3 - Prob. 43QCh. 3 - Prob. 44QCh. 3 - Prob. 45QCh. 3 - Prob. 46QCh. 3 - Prob. 47QCh. 3 - Development of the stratospheric ozone hole has...Ch. 3 - Prob. 49QCh. 3 - Prob. 50QCh. 3 - Resonance structures can be used to explain the...Ch. 3 - Prob. 52QCh. 3 - Prob. 53QCh. 3 - Prob. 54QCh. 3 - Prob. 55QCh. 3 - Many different types of ozone generators...Ch. 3 - The effect a chemical substance has on the ozone...Ch. 3 - Cooking with an electric stove can have a negative...Ch. 3 - One mechanism that helps break down ozone in the...Ch. 3 - Polar stratospheric clouds (PSCs) play an...Ch. 3 - Prob. 61Q
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