(a) Interpretation: Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH 3 -O - in CH 3 -OH is to be stated. Concept introduction: The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

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Answer 1

Question

Chapter 18, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

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Consider the tetracyclic compound with rings labeled A–D. (a) Which ring is the most reactive in electrophilic aromatic substitution? (b) Which ring is the least reactive in electrophilic aromatic substitution?

1) The carbon-oxygen double bond present in aldehydes and ketones is very polar. What does this mean and how does it arise? 2) The carbon-oxygen double bond is readily attacked by nucleophiles like cyanide ions or ammonia. (i) What do you understand by the term nucleophile? (ii) Which part of the carbon-oxygen double bond is attractive to nucleophiles? 3) Why is there a difference between aldehydes and ketones in their response to oxidizing agents such as potassium dichromate(VI) solution acidified with dilute sulfuric acid?

Biphenyl has the following structure.(a) Is biphenyl a (fused) polynuclear aromatic hydrocarbon?(b) How many pi electrons are there in the two aromatic rings of biphenyl? How does this number compare with that for naphthalene?

Answer 2

Question

Chapter 18, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

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Answer 3

Question

Chapter 18, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

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Answer 4

Question

Chapter 18, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

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Answer 5

Chapter 18, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

Answer 6

Chapter 18, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

Answer 7

Chapter 18, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the one which reacts faster in nucleophilic aromatic substitution reaction with CH₃-O^- in CH₃-OH is to be stated.

Concept introduction:

The replacement or substitution of one nucleophilic group with another different nucleophilic group on the aromatic ring is termed as a nucleophilic aromatic substitution reaction. The electron-rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic aromatic substitution reaction, nucleophile takes the position of leaving group. They are of six types.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - Prob. 18.6P Ch. 18 - Prob. 18.7P Ch. 18 - Prob. 18.8P Ch. 18 - Prob. 18.9P Ch. 18 - Prob. 18.10P

Solution Summary: The author explains that the compound that reacts faster in nucleophilic aromatic substitution reaction is shown in Figure 3.

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