(a) Interpretation: The absolute configuration of the alkyl chloride obtained from the reaction of thionyl chloride with ( S ) -CH 3 CH 2 CH 2 CHD − OH is to be stated. Concept introduction: The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile. The S N 2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

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Answer 1

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Chapter 10, Problem 10.21P

Interpretation Introduction

(a)

Interpretation:

The absolute configuration of the alkyl chloride obtained from the reaction of thionyl chloride with (S)-CH3CH2CH2CHD−OH is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of 2-bromopentane obtained from the reaction of Ph3PBr2 with the R enantiomer of 2-pentanol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

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Answer 2

Question

Chapter 10, Problem 10.21P

Interpretation Introduction

(a)

Interpretation:

The absolute configuration of the alkyl chloride obtained from the reaction of thionyl chloride with (S)-CH3CH2CH2CHD−OH is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of 2-bromopentane obtained from the reaction of Ph3PBr2 with the R enantiomer of 2-pentanol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

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Answer 3

Question

Chapter 10, Problem 10.21P

Interpretation Introduction

(a)

Interpretation:

The absolute configuration of the alkyl chloride obtained from the reaction of thionyl chloride with (S)-CH3CH2CH2CHD−OH is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of 2-bromopentane obtained from the reaction of Ph3PBr2 with the R enantiomer of 2-pentanol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

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Answer 4

Question

Chapter 10, Problem 10.21P

Interpretation Introduction

(a)

Interpretation:

The absolute configuration of the alkyl chloride obtained from the reaction of thionyl chloride with (S)-CH3CH2CH2CHD−OH is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of 2-bromopentane obtained from the reaction of Ph3PBr2 with the R enantiomer of 2-pentanol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

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Answer 5

Chapter 10, Problem 10.21P

Interpretation Introduction

(a)

Interpretation:

The absolute configuration of the alkyl chloride obtained from the reaction of thionyl chloride with (S)-CH3CH2CH2CHD−OH is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of 2-bromopentane obtained from the reaction of Ph3PBr2 with the R enantiomer of 2-pentanol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

Answer 6

Chapter 10, Problem 10.21P

Interpretation Introduction

(a)

Interpretation:

The absolute configuration of the alkyl chloride obtained from the reaction of thionyl chloride with (S)-CH3CH2CH2CHD−OH is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

Answer 7

Chapter 10, Problem 10.21P

Interpretation Introduction

(a)

Interpretation:

The absolute configuration of the alkyl chloride obtained from the reaction of thionyl chloride with (S)-CH3CH2CH2CHD−OH is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of 2-bromopentane obtained from the reaction of Ph3PBr2 with the R enantiomer of 2-pentanol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The absolute configuration of 2-bromopentane obtained from the reaction of Ph3PBr2 with the R enantiomer of 2-pentanol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 10 - Prob. 10.1P Ch. 10 - Prob. 10.2P Ch. 10 - Prob. 10.3P Ch. 10 - Prob. 10.4P Ch. 10 - Prob. 10.5P Ch. 10 - Prob. 10.6P Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Prob. 10.10P

Solution Summary: The author explains that the absolute configuration of the alkyl halide obtained from the reaction of thionyl chloride with pyridine is to be stated.

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Chapter 10 Solutions