The detailed mechanism for the given reaction is to be drawn, and the reason it occurs so easily is to be explained. Concept introduction: The sterically hindered substrate with a good leaving group prefers to undergo a substitution reaction through S N 1 mechanism. In the rate-determining step the formation of stable carbocation intermediate takes place. The adjacent electron-donating atom or a group with lone pair stabilizes the carbocation through resonance effect.

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Answer 1

Question

Chapter 9, Problem 9.78P

Interpretation Introduction

Interpretation:

The detailed mechanism for the given reaction is to be drawn, and the reason it occurs so easily is to be explained.

Concept introduction:

The sterically hindered substrate with a good leaving group prefers to undergo a substitution reaction through SN1 mechanism. In the rate-determining step the formation of stable carbocation intermediate takes place. The adjacent electron-donating atom or a group with lone pair stabilizes the carbocation through resonance effect.

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Answer 2

Question

Chapter 9, Problem 9.78P

Interpretation Introduction

Interpretation:

The detailed mechanism for the given reaction is to be drawn, and the reason it occurs so easily is to be explained.

Concept introduction:

The sterically hindered substrate with a good leaving group prefers to undergo a substitution reaction through SN1 mechanism. In the rate-determining step the formation of stable carbocation intermediate takes place. The adjacent electron-donating atom or a group with lone pair stabilizes the carbocation through resonance effect.

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Answer 3

Question

Chapter 9, Problem 9.78P

Interpretation Introduction

Interpretation:

The detailed mechanism for the given reaction is to be drawn, and the reason it occurs so easily is to be explained.

Concept introduction:

The sterically hindered substrate with a good leaving group prefers to undergo a substitution reaction through SN1 mechanism. In the rate-determining step the formation of stable carbocation intermediate takes place. The adjacent electron-donating atom or a group with lone pair stabilizes the carbocation through resonance effect.

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Answer 4

Question

Chapter 9, Problem 9.78P

Interpretation Introduction

Interpretation:

The detailed mechanism for the given reaction is to be drawn, and the reason it occurs so easily is to be explained.

Concept introduction:

The sterically hindered substrate with a good leaving group prefers to undergo a substitution reaction through SN1 mechanism. In the rate-determining step the formation of stable carbocation intermediate takes place. The adjacent electron-donating atom or a group with lone pair stabilizes the carbocation through resonance effect.

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Answer 5

Chapter 9, Problem 9.78P

Interpretation Introduction

Interpretation:

The detailed mechanism for the given reaction is to be drawn, and the reason it occurs so easily is to be explained.

Concept introduction:

The sterically hindered substrate with a good leaving group prefers to undergo a substitution reaction through SN1 mechanism. In the rate-determining step the formation of stable carbocation intermediate takes place. The adjacent electron-donating atom or a group with lone pair stabilizes the carbocation through resonance effect.

Answer 6

Chapter 9, Problem 9.78P

Interpretation Introduction

Interpretation:

The detailed mechanism for the given reaction is to be drawn, and the reason it occurs so easily is to be explained.

Concept introduction:

The sterically hindered substrate with a good leaving group prefers to undergo a substitution reaction through SN1 mechanism. In the rate-determining step the formation of stable carbocation intermediate takes place. The adjacent electron-donating atom or a group with lone pair stabilizes the carbocation through resonance effect.

Answer 7

Chapter 9, Problem 9.78P

Interpretation Introduction

Interpretation:

The detailed mechanism for the given reaction is to be drawn, and the reason it occurs so easily is to be explained.

Concept introduction:

The sterically hindered substrate with a good leaving group prefers to undergo a substitution reaction through SN1 mechanism. In the rate-determining step the formation of stable carbocation intermediate takes place. The adjacent electron-donating atom or a group with lone pair stabilizes the carbocation through resonance effect.

Answer 8

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Answer 9

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Answer 11

Ch. 9 - Prob. 9.1P Ch. 9 - Prob. 9.2P Ch. 9 - Prob. 9.3P Ch. 9 - Prob. 9.4P Ch. 9 - Prob. 9.5P Ch. 9 - Prob. 9.6P Ch. 9 - Prob. 9.7P Ch. 9 - Prob. 9.8P Ch. 9 - Prob. 9.9P Ch. 9 - Prob. 9.10P

Solution Summary: The author explains that the reaction is a substitution reaction. The nitrogen base acts as an excellent leaving group due to positively charged alkylated nitrogen.

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