CHEMICAL PRINCIPLES (LL) W/ACCESS
CHEMICAL PRINCIPLES (LL) W/ACCESS
7th Edition
ISBN: 9781319421175
Author: ATKINS
Publisher: MAC HIGHER
bartleby

Concept explainers

bartleby

Videos

Question
Book Icon
Chapter 9, Problem 9.20E

(a)

Interpretation Introduction

Interpretation:

The systematic name and the formula of cis-platin have to be given.

Concept Introduction:

Rules for naming the complex:

  • Name the ligands first, and then the metal atom or ion. A Roman numeral in parentheses denotes the oxidation number of the central metal ion.
  • Neutral ligands, such as H2NCH2CH2NH2 (ethylenediamine) have the same name as the molecule, except for H2O (aqua), NH3 (ammine), CO (carbonyl), and NO (nitrosyl).
  • Anionic ligands end in -o; for anions that end in -ide (such as chloride), -ate (such as sulfate), and -ite (such as nitrite), change the endings as -ide, -ido, ate, -ato, ite, -ito.

Examples: chlorido, sulfato, and nitrito

  • Greek prefixes indicate the number of each type of ligand in the complex ion:2-di, 3-tri, 4-tetra, 5-penta, 6-hexa.
  • If the ligand already contains a Greek prefix (such as the diinethylenediamine) or if it is polydentate (able to attach at more than one binding site simultaneously), then the following prefixes are used instead 2-bis, 3-tris, 4-tetrakis.
  • Ligands are named in alphabetical order, ignoring any Greek prefix.
  • If there is an uncertainty in identifying which atom is linked to the metal atom, then k E is added to the name in parentheses, where E denotes the connecting atom (and k is kappa).
  • If the complex has an overall negative charge (an anionic complex), the suffix -ate is added to the stem of the metal’s name. If the symbol of the metal originates from a Latin name, then the Latin stem is used followed by the oxidation number of the metal in Roman numerals.
  • The name of a coordination compound (as distinct from a complex cation or anion) is built in the same way as that of a simple compound, with the cation named before the anion.

Rules for writing the formula of the complex:

  • Write the chemical symbol of the central atom (usually a metal atom) first, followed by symbols for the ligands, then enclose the entire collection of symbols between square brackets and add the overall charge.
  • Write the chemical symbols of ligands in alphabetical order, when different ligands contain the same element, those denoted by a single letter (e.g., O) take priority over symbols represented by two or more letters (e.g., OH).  If a particular point needs to be emphasized, then the order may be varied.  For example water as a ligand is denoted OH2, to emphasize that the O links to the metal atom.
  • To avoid any ambiguity, the linking atom can be underlined

(b)

Interpretation Introduction

Interpretation:

The possible isomer of cis-platin has to be given.

(c)

Interpretation Introduction

Interpretation:

The coordination geometry of cis platin has to be given.

Blurred answer

Chapter 9 Solutions

CHEMICAL PRINCIPLES (LL) W/ACCESS

Ch. 9 - Prob. 9A.9ECh. 9 - Prob. 9A.10ECh. 9 - Prob. 9A.11ECh. 9 - Prob. 9A.12ECh. 9 - Prob. 9A.13ECh. 9 - Prob. 9A.14ECh. 9 - Prob. 9B.1ASTCh. 9 - Prob. 9B.1BSTCh. 9 - Prob. 9B.2ASTCh. 9 - Prob. 9B.2BSTCh. 9 - Prob. 9B.1ECh. 9 - Prob. 9B.2ECh. 9 - Prob. 9B.3ECh. 9 - Prob. 9B.4ECh. 9 - Prob. 9B.5ECh. 9 - Prob. 9B.6ECh. 9 - Prob. 9B.7ECh. 9 - Prob. 9B.8ECh. 9 - Prob. 9B.9ECh. 9 - Prob. 9B.10ECh. 9 - Prob. 9B.11ECh. 9 - Prob. 9B.12ECh. 9 - Prob. 9B.13ECh. 9 - Prob. 9B.14ECh. 9 - Prob. 9B.15ECh. 9 - Prob. 9B.16ECh. 9 - Prob. 9C.1ASTCh. 9 - Prob. 9C.1BSTCh. 9 - Prob. 9C.2ASTCh. 9 - Prob. 9C.2BSTCh. 9 - Prob. 9C.3ASTCh. 9 - Prob. 9C.3BSTCh. 9 - Prob. 9C.4ASTCh. 9 - Prob. 9C.4BSTCh. 9 - Prob. 9C.1ECh. 9 - Prob. 9C.2ECh. 9 - Prob. 9C.3ECh. 9 - Prob. 9C.4ECh. 9 - Prob. 9C.5ECh. 9 - Prob. 9C.6ECh. 9 - Prob. 9C.7ECh. 9 - Prob. 9C.8ECh. 9 - Prob. 9C.9ECh. 9 - Prob. 9C.10ECh. 9 - Prob. 9C.11ECh. 9 - Prob. 9C.12ECh. 9 - Prob. 9C.13ECh. 9 - Prob. 9C.14ECh. 9 - Prob. 9C.15ECh. 9 - Prob. 9C.16ECh. 9 - Prob. 9C.17ECh. 9 - Prob. 9C.18ECh. 9 - Prob. 9C.19ECh. 9 - Prob. 9C.20ECh. 9 - Prob. 9D.1ASTCh. 9 - Prob. 9D.1BSTCh. 9 - Prob. 9D.2ASTCh. 9 - Prob. 9D.2BSTCh. 9 - Prob. 9D.3ASTCh. 9 - Prob. 9D.3BSTCh. 9 - Prob. 9D.4ASTCh. 9 - Prob. 9D.4BSTCh. 9 - Prob. 9D.1ECh. 9 - Prob. 9D.2ECh. 9 - Prob. 9D.3ECh. 9 - Prob. 9D.4ECh. 9 - Prob. 9D.5ECh. 9 - Prob. 9D.6ECh. 9 - Prob. 9D.7ECh. 9 - Prob. 9D.8ECh. 9 - Prob. 9D.9ECh. 9 - Prob. 9D.10ECh. 9 - Prob. 9D.11ECh. 9 - Prob. 9D.12ECh. 9 - Prob. 9D.13ECh. 9 - Prob. 9D.14ECh. 9 - Prob. 9D.15ECh. 9 - Prob. 9D.16ECh. 9 - Prob. 9D.17ECh. 9 - Prob. 9D.18ECh. 9 - Prob. 9D.19ECh. 9 - Prob. 9D.20ECh. 9 - Prob. 9D.21ECh. 9 - Prob. 9D.22ECh. 9 - Prob. 9D.23ECh. 9 - Prob. 9D.24ECh. 9 - Prob. 9D.25ECh. 9 - Prob. 9D.26ECh. 9 - Prob. 9D.27ECh. 9 - Prob. 9D.28ECh. 9 - Prob. 9D.29ECh. 9 - Prob. 9D.30ECh. 9 - Prob. 9D.31ECh. 9 - Prob. 9D.32ECh. 9 - Prob. 9D.33ECh. 9 - Prob. 9D.34ECh. 9 - Prob. 9.1ECh. 9 - Prob. 9.2ECh. 9 - Prob. 9.3ECh. 9 - Prob. 9.4ECh. 9 - Prob. 9.5ECh. 9 - Prob. 9.6ECh. 9 - Prob. 9.7ECh. 9 - Prob. 9.8ECh. 9 - Prob. 9.9ECh. 9 - Prob. 9.10ECh. 9 - Prob. 9.11ECh. 9 - Prob. 9.12ECh. 9 - Prob. 9.13ECh. 9 - Prob. 9.14ECh. 9 - Prob. 9.15ECh. 9 - Prob. 9.16ECh. 9 - Prob. 9.17ECh. 9 - Prob. 9.18ECh. 9 - Prob. 9.19ECh. 9 - Prob. 9.20ECh. 9 - Prob. 9.21ECh. 9 - Prob. 9.23ECh. 9 - Prob. 9.25E
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
  • Text book image
    Chemistry: The Molecular Science
    Chemistry
    ISBN:9781285199047
    Author:John W. Moore, Conrad L. Stanitski
    Publisher:Cengage Learning
    Text book image
    Principles of Modern Chemistry
    Chemistry
    ISBN:9781305079113
    Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
    Publisher:Cengage Learning
    Text book image
    Chemistry
    Chemistry
    ISBN:9781305957404
    Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
    Publisher:Cengage Learning
  • Text book image
    Chemistry: An Atoms First Approach
    Chemistry
    ISBN:9781305079243
    Author:Steven S. Zumdahl, Susan A. Zumdahl
    Publisher:Cengage Learning
    Text book image
    Chemistry
    Chemistry
    ISBN:9781133611097
    Author:Steven S. Zumdahl
    Publisher:Cengage Learning
    Text book image
    Chemistry: Principles and Practice
    Chemistry
    ISBN:9780534420123
    Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
    Publisher:Cengage Learning
Text book image
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Text book image
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781133611097
Author:Steven S. Zumdahl
Publisher:Cengage Learning
Text book image
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
The Bohr Model of the atom and Atomic Emission Spectra: Atomic Structure tutorial | Crash Chemistry; Author: Crash Chemistry Academy;https://www.youtube.com/watch?v=apuWi_Fbtys;License: Standard YouTube License, CC-BY