Introductory Chemistry (5th Edition) (Standalone Book)
5th Edition
ISBN: 9780321910295
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 9, Problem 40E
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An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.
The reaction of solid dimethylhydrazine, (CH3)2N2H2, and liquefied dinitrogen tetroxide, N2O4, has been investigated for use as rocket fuel. The reaction produces the gases carbon dioxide (CO2), nitrogen (N2), and water vapor (H2O), which are ejected in the exhaust gases. In a controlled experiment, solid dimethylhydrazine was reacted with excess dinitrogen tetroxide, and the gases were collected in a closed balloon until a pressure of 2.50 atm and a temperature of 400.0 K were reached.(a) What are the partial pressures of CO2, N2, and H2O?(b) When the CO2 is removed by chemical reaction, what are the partial pressures of the remaining gases?
One liter of chlorine gas at 1 atm and 298 K reacts completely with 1.00 L of nitrogen gas and 2.00 L of oxygen gas at the same temperature and pressure. A single gaseous product is formed, which fills a 2.00 L flask at 1.00 atm and 298 K. Use this information to determine the following characteristics of the product:(a) its empirical formula;(b) its molecular formula;(c) the most favorable Lewis formula based on formal charge arguments (the central atom is N);(d) the shape of the molecule.
Chapter 9 Solutions
Introductory Chemistry (5th Edition) (Standalone Book)
Ch. 9 - Q1. Which set of wavelengths for light are...Ch. 9 - Which of the listed types of electromagnetic...Ch. 9 - Q3. Which electron transition in the Bohr model...Ch. 9 - What is the electron configuration of arsenic...Ch. 9 - Which orbital diagram corresponds to phosphorus...Ch. 9 - Q6. How many valence electrons does tellurium (Te)...Ch. 9 - Q7. The element sulfur forms an ion with what...Ch. 9 - Order the elements Sr, Ca, and Se in order of...Ch. 9 - Which of the listed elements has the highest...Ch. 9 - Q10. Which of the listed elements is most...
Ch. 9 - Which property decreases as you move down a column...Ch. 9 - Q12. When aluminum forms an ion, it loses...Ch. 9 - 1. When were the Bohr model the quantum-mechanical...Ch. 9 - 2. What is light? How fast does light travel?
Ch. 9 - 3. What is white light? Colored light?
Ch. 9 - Explain in terms of absorbed and reflected light,...Ch. 9 - What is the relationship between the wavelength of...Ch. 9 - Prob. 6ECh. 9 - How are X-rays used?Ch. 9 - Why should excess exposure to gamma rays and...Ch. 9 - Why should excess exposure to ultraviolet light be...Ch. 9 - What objects emit infrared light? What technology...Ch. 9 - Why do microwave ovens heat food but tend not to...Ch. 9 - 12 .What type of electromagnetic radiation is used...Ch. 9 - Describe the Bohr model for the hydrogen atom.Ch. 9 - 14. What is an emission spectrum? Use the Bohr...Ch. 9 - 15. Explain the difference between a Bohr orbit...Ch. 9 - 16. What is the difference between the ground...Ch. 9 - 17. Explain how the motion of an electron is...Ch. 9 - 18. Why do quantum-mechanical orbital have “fuzzy”...Ch. 9 - Prob. 19ECh. 9 - 20. List the quantum-mechanical orbitals through...Ch. 9 - Prob. 21ECh. 9 - Prob. 22ECh. 9 - Within an electron configuration. What do symbols...Ch. 9 - Explain the difference between valence electrons...Ch. 9 - Identify each block in the blank periodic table....Ch. 9 - Prob. 26ECh. 9 - Prob. 27ECh. 9 - Prob. 28ECh. 9 - Prob. 29ECh. 9 - How far does light travel in each time period? a....Ch. 9 - 31. Which type of electromagnetic radiation has...Ch. 9 - 32. Which type of electromagnetic radiation has...Ch. 9 - List the types of electromagnetic radiation in...Ch. 9 - List the types of electromagnetic radiation in...Ch. 9 - List two types of electromagnetic radiation with...Ch. 9 - List two types of electromagnetic radiation with...Ch. 9 - List these three types of radiationinfrared,...Ch. 9 - List these three types of electromagnetic...Ch. 9 - Prob. 39ECh. 9 - 40. In the Bohr model, what happens when an...Ch. 9 - 41. Two of the emission wavelengths in the...Ch. 9 - 42. Two of the emission wavelengths in the...Ch. 9 - 43. Sketch the 1s and 2p orbitals. How do the 2s...Ch. 9 - Sketch the 3d orbitals. How do the 4d orbitals...Ch. 9 - Which electron is, on average closer to the...Ch. 9 - 46. Which electron is, on average, farther from...Ch. 9 - 47. According to the quantum-mechanical model for...Ch. 9 - Prob. 48ECh. 9 - 49. Write full electron configuration for each...Ch. 9 - Prob. 50ECh. 9 - 51. Write full orbital diagrams and indicate the...Ch. 9 - Write full orbital diagrams and indicate the...Ch. 9 - Write electron configurations for each element....Ch. 9 - Write electron configurations for each element....Ch. 9 - Prob. 55ECh. 9 - Prob. 56ECh. 9 - Prob. 57ECh. 9 - 58. Write full electron configurations and...Ch. 9 - Write orbital diagrams for the valence electrons...Ch. 9 - 60. Write orbital diagrams for the valence...Ch. 9 - How many valence electrons are in each element? a....Ch. 9 - Prob. 62ECh. 9 - Prob. 63ECh. 9 - Prob. 64ECh. 9 - Prob. 65ECh. 9 - Use the periodic table to write electron...Ch. 9 - Use the periodic table to write electron...Ch. 9 - Prob. 68ECh. 9 - Prob. 69ECh. 9 - Prob. 70ECh. 9 - Prob. 71ECh. 9 - Prob. 72ECh. 9 - Name the element in the third period (row) of the...Ch. 9 - 74. Name the element in the fourth period of the...Ch. 9 - 75. Use the periodic table to identify the element...Ch. 9 - Prob. 76ECh. 9 - 77. Choose the element with the higher ionization...Ch. 9 - Choose the element with the higher ionization...Ch. 9 - Arrange the elements in order of increasing...Ch. 9 - Prob. 80ECh. 9 - 81. Choose the element with the larger atoms from...Ch. 9 - Choose the element with the larger atoms from each...Ch. 9 - Prob. 83ECh. 9 - Prob. 84ECh. 9 - 85. Choose the more metallic element from each...Ch. 9 - Choose the more metallic element from each pair....Ch. 9 - 87. Arrange these elements in order of increasing...Ch. 9 - Arrange these elements in order of decreasing...Ch. 9 - What is the maximum number of electrons that can...Ch. 9 - Prob. 90ECh. 9 - Use the electron configurations of the alkaline...Ch. 9 - Prob. 92ECh. 9 - Write the electron configuration for each ion....Ch. 9 - Write the electron configuration for each ion....Ch. 9 - Prob. 95ECh. 9 - 96. Examine Figure 4.14, which shows the elements...Ch. 9 - Prob. 97ECh. 9 - Identify what is wrong with each electron...Ch. 9 - Prob. 99ECh. 9 - Prob. 100ECh. 9 - Prob. 101ECh. 9 - Based on periodic trends, which one of these...Ch. 9 - When an electron makes a transition from n=3 to...Ch. 9 - Prob. 104ECh. 9 - The distance from the sun to Earth is 1.496108 km....Ch. 9 - Prob. 106ECh. 9 - In the beginning of this chapter, you learned that...Ch. 9 - 108. Niels Bohr said, “Anyone who is not shocked...Ch. 9 - 107. The wave nature of matter was first proposed...Ch. 9 - 108. The particle nature of light was first...Ch. 9 - Prob. 111ECh. 9 - When atoms lose more than one electron, the...Ch. 9 - 111. Excessive exposure to sunlight increases the...Ch. 9 - 112. The quantum-mechanical model, besides...Ch. 9 - Prob. 115ECh. 9 - 116. Using grammatically correct sentences,...
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- How does the square root mean square velocity of gas molecules vary with temperature? Illustrate this relationship by plotting the square root mean square velocity of N2 molecules as a function of temperature from T=100 K to T=300 K.arrow_forwardDraw product B, indicating what type of reaction occurs. F3C CF3 NH2 Me O .N. + B OMearrow_forwardBenzimidazole E. State its formula. sState the differences in the formula with other benzimidazoles.arrow_forward
- Draw product A, indicating what type of reaction occurs. F3C CN CF3 K2CO3, DMSO, H₂O2 Aarrow_forward19) Which metal is most commonly used in galvanization to protect steel structures from oxidation? Lead a. b. Tin C. Nickel d. Zinc 20) The following molecule is an example of a: R₁ R2- -N-R3 a. Secondary amine b. Secondary amide c. Tertiary amine d. Tertiary amidearrow_forwardpls helparrow_forward
- pls helparrow_forward35) Complete the following equation by drawing the line the structure of the products that are formed. Please note that in some cases more than one product is possible. You must draw all possible products to recive full marks! a. ethanol + 2-propanol + H2SO4 → b. OH conc. H2SO4 CH2 H3C CH + K2Cr2O7 C. d. H3C A pressure CH3 + H2 CH Pt catalystarrow_forward21) The rate of reaction depends upon: a. the concentration and nature of reactants b. the temperature of the reaction C. whether or not a catalyst was used d. all of the above 22) A Maxwell-Boltzmann curve shows the distribution of molecular energies in a reaction system. When the temperature in this system is increased, the peak is a. higher and further to the right. b. higher and further to the left. c. lower and further to the right. d. lower and further to the left. 23) Which of the following correctly describes the reaction represented by the reaction below? CaCO3 (s) + energy → CaO (s) + CO2 (g) a. It is exothermic and the potential energy is greater in the reactants than the products. b. c. It is exothermic and the potential energy is greater in the products than the reactants. It is endothermic and the potential energy is greater in the products than the reactants. d. It is endothermic and the potential energy is equal for the products and reactants.arrow_forward
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