Organic Chemistry (8th Edition)
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 8.20, Problem 60P

a)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds has to be explained.

Concept Introduction:

Criteria for Aromaticity:

  • A molecule must be cyclic.
  • Every atom in the ring must have a p-orbital.
  • The molecule must be planar.
  • π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

b)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compound has to be explained.

Concept Introduction:

Criteria for Aromaticity:

  • A molecule must be cyclic.
  • Every atom in the ring must have a p-orbital.
  • The molecule must be planar.
  • π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

c)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds to be explained.

Concept Introduction:

Criteria for Aromaticity:

  • A molecule must be cyclic.
  • Every atom in the ring must have a p-orbital.
  • The molecule must be planar.
  • π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

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a. What is the hybridization of each N atom in nicotine? b. What is the geometry around each N atom? c. In what type of orbital does the lone pair on each N atom reside? d. Draw a constitutional isomer of nicotine. e. Draw a resonance structure of nicotine.
Answer the following: 1. Ethyl alcohol and dimethyl ether are isomers. However, they differ in theirdipole moment. Which statement is TRUE? a. Dimethyl ether has a lower dipole moment than ethyl alcohol.b. Ethyl alcohol has a lower dipole moment than dimethyl ether.c. Ethyl alcohol has a greater bond dipole than dimethyl ether.d. Dimethyl ether has a greater bond dipole than ethyl alcohol. 2. Carbocation stability is important in reaction mechanisms involving alcohols.Based on the general structure of alcohols, rank the carbocation stability ofalcohols (increasing trend) if a central carbon is the point of reference. a. Tertiary alcohol > Secondary alcohol > Primary alcoholb. Tertiary alcohol > Primary alcohol > Secondary alcoholc. Secondary alcohol > Tertiary alcohol > Primary alcohold. Primary alcohol > Secondary alcohol > Tertiary alcohol
#47. C is the answer but please help explain why. I cannot figure it out according to the book material.

Chapter 8 Solutions

Organic Chemistry (8th Edition)

Ch. 8.7 - Prob. 12PCh. 8.7 - Prob. 13PCh. 8.8 - Prob. 14PCh. 8.8 - Prob. 15PCh. 8.8 - Prob. 16PCh. 8.9 - Which member of each pair is the stronger acid?Ch. 8.9 - Which member of each pair is the stronger base? a....Ch. 8.9 - Rank the following compounds from strongest acid...Ch. 8.10 - Prob. 20PCh. 8.10 - Which acid in each of the following pairs is...Ch. 8.10 - Prob. 23PCh. 8.11 - Prob. 24PCh. 8.11 - Prob. 26PCh. 8.12 - Prob. 27PCh. 8.12 - Prob. 28PCh. 8.12 - Prob. 29PCh. 8.12 - Prob. 30PCh. 8.12 - Prob. 31PCh. 8.12 - Prob. 32PCh. 8.13 - Prob. 33PCh. 8.13 - Prob. 34PCh. 8.13 - Prob. 35PCh. 8.13 - What are the major 1,2- and 1,4-addition products...Ch. 8.13 - Prob. 38PCh. 8.14 - Prob. 39PCh. 8.14 - Prob. 40PCh. 8.14 - Prob. 41PCh. 8.14 - Prob. 42PCh. 8.14 - Prob. 43PCh. 8.14 - Prob. 44PCh. 8.14 - Prob. 46PCh. 8.15 - Prob. 47PCh. 8.17 - Prob. 48PCh. 8.17 - Prob. 49PCh. 8.18 - Prob. 50PCh. 8.18 - Prob. 52PCh. 8.18 - Prob. 53PCh. 8.18 - Prob. 54PCh. 8.19 - Prob. 55PCh. 8.20 - Prob. 56PCh. 8.20 - What orbitals contain the electrons represented as...Ch. 8.20 - Prob. 59PCh. 8.20 - Prob. 60PCh. 8 - Prob. 61PCh. 8 - Prob. 62PCh. 8 - Prob. 63PCh. 8 - Prob. 64PCh. 8 - Prob. 65PCh. 8 - Prob. 66PCh. 8 - Prob. 67PCh. 8 - Prob. 68PCh. 8 - Prob. 69PCh. 8 - Prob. 70PCh. 8 - Prob. 71PCh. 8 - Prob. 72PCh. 8 - Prob. 73PCh. 8 - Which compound is the strongest base?Ch. 8 - Prob. 75PCh. 8 - Prob. 76PCh. 8 - a. The A ring (Section 3.16) of cortisone (a...Ch. 8 - Prob. 78PCh. 8 - Prob. 79PCh. 8 - Prob. 80PCh. 8 - Prob. 81PCh. 8 - Purine is a heterocyclic compound with four...Ch. 8 - Prob. 83PCh. 8 - Why is the delocalization energy of pyrrole (21...Ch. 8 - Prob. 85PCh. 8 - Prob. 86PCh. 8 - Prob. 87PCh. 8 - A student obtained two products from the reaction...Ch. 8 - Prob. 89PCh. 8 - a. How could each of the following compounds be...Ch. 8 - Draw the products obtained from the reaction of...Ch. 8 - How would the following substituents affect the...Ch. 8 - Prob. 93PCh. 8 - The acid dissociation constant (Ka) for loss of a...Ch. 8 - Protonated cyclohexylamine has a Ka = 1 1011...Ch. 8 - Draw the product or products that would be...Ch. 8 - Prob. 97PCh. 8 - Prob. 98PCh. 8 - Prob. 99PCh. 8 - Prob. 100PCh. 8 - Prob. 101PCh. 8 - a. Propose n mechanism for the following reaction:...Ch. 8 - Prob. 103PCh. 8 - As many as 18 different Diels-Alder products can...Ch. 8 - Prob. 105PCh. 8 - Prob. 106PCh. 8 - Prob. 107PCh. 8 - Prob. 108PCh. 8 - The experiment shown next and discussed in Section...Ch. 8 - Prob. 110PCh. 8 - Prob. 111PCh. 8 - Prob. 112PCh. 8 - Prob. 1PCh. 8 - Prob. 2PCh. 8 - Prob. 3PCh. 8 - Prob. 4PCh. 8 - Prob. 5PCh. 8 - Prob. 6PCh. 8 - Prob. 7PCh. 8 - Prob. 8PCh. 8 - Prob. 9PCh. 8 - Prob. 10PCh. 8 - Prob. 11PCh. 8 - Prob. 12P
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