Organic Chemistry: Principles and Mechanisms (Second Edition)
Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Chapter 8, Problem 8.9YT

(a)

Interpretation Introduction

Interpretation:

The percentage of molecules at 100 oC having enough energy to surmount an energy barrier of 15 kJ/mol is to be estimated using figure 8-5.

Concept introduction:

The percentage of molecules with sufficient energy decreases as the size of the energy barrier increases; the percentage of molecules that are able to surmount the energy barrier decreases by a factor of 20. As the temperature increases, the percentage also increases.

(b)

Interpretation Introduction

Interpretation:

The percentage of molecules at 100 oC having enough energy to surmount an energy barrier of 25 kJ/mol is to be estimated using figure 8-5.

Concept introduction:

The percentage of molecules with sufficient energy decreases as the size of the energy barrier increases; the percentage of molecules that are able to surmount the energy barrier decreases by a factor of 20. As the temperature increases, the percentage also increases.

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C6H5CHO reacts with H₂ to form C6H5CH₂OH. The equilibrium constant, Kp, for this reaction is 1.79 at 523 K. C6H5CHO(g) + H₂(g) 2CH₂CH₂OH(g) The standard enthalpy change for this reaction (AHº) is -55.5 kJ/mol. (a) Predict the effect on the production of C6H₂CH₂OH when the temperature of the equilibrium system is increased. ŵ (b) Use the van't Hoff equation to estimate the equilibrium constant for this reaction at 632 K. Kp at 632 K =

Chapter 8 Solutions

Organic Chemistry: Principles and Mechanisms (Second Edition)

Ch. 8 - Prob. 8.11PCh. 8 - Prob. 8.12PCh. 8 - Prob. 8.13PCh. 8 - Prob. 8.14PCh. 8 - Prob. 8.15PCh. 8 - Prob. 8.16PCh. 8 - Prob. 8.17PCh. 8 - Prob. 8.18PCh. 8 - Prob. 8.19PCh. 8 - Prob. 8.20PCh. 8 - Prob. 8.21PCh. 8 - Prob. 8.22PCh. 8 - Prob. 8.23PCh. 8 - Prob. 8.24PCh. 8 - Prob. 8.25PCh. 8 - Prob. 8.26PCh. 8 - Prob. 8.27PCh. 8 - Prob. 8.28PCh. 8 - Prob. 8.29PCh. 8 - Prob. 8.30PCh. 8 - Prob. 8.31PCh. 8 - Prob. 8.32PCh. 8 - Prob. 8.33PCh. 8 - Prob. 8.34PCh. 8 - Prob. 8.35PCh. 8 - Prob. 8.36PCh. 8 - Prob. 8.37PCh. 8 - Prob. 8.38PCh. 8 - Prob. 8.39PCh. 8 - Prob. 8.40PCh. 8 - Prob. 8.41PCh. 8 - Prob. 8.42PCh. 8 - Prob. 8.43PCh. 8 - Prob. 8.44PCh. 8 - Prob. 8.45PCh. 8 - Prob. 8.46PCh. 8 - Prob. 8.47PCh. 8 - Prob. 8.48PCh. 8 - Prob. 8.49PCh. 8 - Prob. 8.50PCh. 8 - Prob. 8.51PCh. 8 - Prob. 8.52PCh. 8 - Prob. 8.53PCh. 8 - Prob. 8.54PCh. 8 - Prob. 8.55PCh. 8 - Prob. 8.56PCh. 8 - Prob. 8.57PCh. 8 - Prob. 8.58PCh. 8 - Prob. 8.59PCh. 8 - Prob. 8.60PCh. 8 - Prob. 8.61PCh. 8 - Prob. 8.62PCh. 8 - Prob. 8.63PCh. 8 - Prob. 8.64PCh. 8 - Prob. 8.65PCh. 8 - Prob. 8.66PCh. 8 - Prob. 8.67PCh. 8 - Prob. 8.68PCh. 8 - Prob. 8.69PCh. 8 - Prob. 8.70PCh. 8 - Prob. 8.71PCh. 8 - Prob. 8.72PCh. 8 - Prob. 8.73PCh. 8 - Prob. 8.74PCh. 8 - Prob. 8.75PCh. 8 - Prob. 8.76PCh. 8 - Prob. 8.1YTCh. 8 - Prob. 8.2YTCh. 8 - Prob. 8.3YTCh. 8 - Prob. 8.4YTCh. 8 - Prob. 8.5YTCh. 8 - Prob. 8.6YTCh. 8 - Prob. 8.7YTCh. 8 - Prob. 8.8YTCh. 8 - Prob. 8.9YTCh. 8 - Prob. 8.10YTCh. 8 - Prob. 8.11YTCh. 8 - Prob. 8.12YTCh. 8 - Prob. 8.13YTCh. 8 - Prob. 8.14YTCh. 8 - Prob. 8.15YTCh. 8 - Prob. 8.16YTCh. 8 - Prob. 8.17YTCh. 8 - Prob. 8.18YTCh. 8 - Prob. 8.19YT
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