(a)
Interpretation:
The amount of heat in kilocalories required to vaporize
Concept introduction:
Heat of fusion: It is defined as the amount of heat required to melt a substance completely once it reaches its melting point.
Heat of vaporization: It is defined as the quantity of heat required to vaporize a substance completely once it reaches its boiling point.
Amount of heat required to produce a given temperature change can be given by the equation:
(b)
Interpretation:
The amount of heat in kilocalories released by the condensation of
Concept introduction:
Heat of fusion: It is defined as the amount of heat required to melt a substance completely once it reaches its melting point.
Heat of vaporization: It is defined as the quantity of heat required to vaporize a substance completely once it reaches its boiling point.
Amount of heat required to produce a given temperature change can be given by the equation:
Want to see the full answer?
Check out a sample textbook solutionChapter 8 Solutions
Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
- For ferrocene (C10H10Fe) the enthalpy of sublimation is 73.2 kJ/mol and the entropy of sublimation is 243 J/mol.K. What is the sublimation temperature of ferrocene in degrees Celsius?arrow_forwardA helium gas cylinder of the sort used to fill balloons has a volume of 0.180 m3 and a pressure of 150 X 105 Pa (150 atm) at 298 K (25 °C). How many moles of helium are in the tank? How many grams?arrow_forwardChloroform is a volatile (readily changes from liquid phase to gaseous phase) once commonly used in the laboratory but now being phased out due to its ozone depletion potential. If the pressure of gaseous chloroform in a flask is 195 Torr at 25°C and its mass for 1 liter of gas is 1.25 g, what is the molar mass (g/mol) of chloroform? O None of these O 119 g/mol 10.0 g/mol O 76.3 g/molarrow_forward
- At 25.0 °C the Henry's Law constant for dinitrogen monoxide (N,0) gas in water is 0.025 M/atm. Calculate the mass in grams of N,0 gas that can be dissolved in 450. mL of water at 25.0 °C and a N,0 partial pressure of 1.31 atm. Be sure your answer has the correct number of significant digits. ?arrow_forwardThe reaction CO (g) + H2O(g) CO2(g) 2 + H2(g) has ΔH = -41 kJ/mol. Does the amount of H2 in an equilibrium mixture increase or decrease when the temperature is decreased?arrow_forwardBalance the following (fictional) chemical equations by supplying the correct coefficient. Do not leave any space blank (in other words, write in 1 if you would be leaving it blank): R(OZ)2 - RY2+ Z20 a) ZY+ b) D2 (g) + L2 (g) – DL3 (e)arrow_forward
- In 2011, researchers showed that hypochlorous acid (HClO) generated by white blood cells kills bacteria. Calculate the percent dissociation of (a) 0.40 M HClO; (b) 0.035 M HClO (Ka = 2.9x10-8).arrow_forwardTo form S²⁻ ions from gaseous sulfur atoms requires 214 kJ/mol, but these ions exist in solids such as K₂S. Explainarrow_forwardHow many liters of dry hydrogen gas, measured at 798 mmHg and 21C, will be released by the decomposition of 230 mL of H20 at 1.42atm and 30C? 2 H20 (g) → 2 H2 (g) + O2 (g) Answer to 3 decimal places. Your Answer: Answer unitsarrow_forward
- The following reaction plays a key role in the destruction of ozone in the atmosphere: Cl(g)+ O3 (g)-> ClO(g)+O2 (g) Given the standard molar entropies (S°) below, calculate the ΔS for this reaction. S°C1O = 218.9 J/mol*K S°O3 = 238.8 J/mol*K S°Cl = 165.2 J/mol*K S°O2= 205.0 J/mol*K _______ J/K = ΔSarrow_forwardThe following data was collected for n-pentane and isopentane: Compound P, (kPa) n-pentane 282.9 at 70°C 895.5 at 120°C Isopentane 955.9 at 115°C 1152.4 at 125°C а) Develop a correlation for the vapor pressure of Isopentane as a function of temperature. Clearly state the units. b) Calculate the vapor pressure of Isopentane at 120°C. c) Estimate the heat of vaporization of Isopentane by using the data in the table. A closed container contains a mixture of 65.0 mol% n-pentane and 35.0 mol% isopentane. The system is initially all liquid at 120.0°C and high pressure and the pressure is gradually reduced at a constant temperature. d) i. Calculate the pressure (in kPa) at which the first bubble of vapor forms. ii. What is the composition (in mole fractions) of the first bubble of vapor at the conditions found in part (i)? A new mixture contains cyclohexane (Pv=288.3kPa at 120°C), n-pentane and isopentane at 120°C and high pressure. The pressure is reduced at constant temperature to a point…arrow_forwardThe vapor pressure of component C is 272 torr, and that of component E is 176 torr at 35°C. The C-E solution at 35C with x=0.200 has a vapor pressure of 904.2 torr and vapor composition of x=0.272. 1. Calculate y, for C 2.15 and for E 4.99 : in this solution. 2. Calculate a, for C 2.42 and for E 2.678 in this solution. 3. Calculate p,-p, for component C 2264.38 : (J/mol) and E 857.32 : (J/mol). 4. Calculate AmyG= -1092.22 : (J) for the corresponding ideal solution.arrow_forward