Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781305638709
Author: Bettelheim, Frederick A.; Brown, William H.; Campbell, Mary K.; Farrell, Shawn O.; Torres, Omar
Publisher: Brooks Cole
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Chapter 8, Problem 8.62P
8-62 What is the pH of a buffer solution made by dissolving 0.10 mol of formic acid, HCOOH, and 0.10 mol of sodium formate, HCOONa, in 1 L of water?
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Chapter 8 Solutions
Introduction to General, Organic and Biochemistry
Ch. 8.3 - Problem 8-1 Draw the acid and base reactions for...Ch. 8.4 - Prob. 8.2PCh. 8.5 - Prob. 8.3PCh. 8.5 - Problem 8-4 Which is the stronger acid? (a)...Ch. 8.6 - Problem 8-5 Write the balanced net ionic equation...Ch. 8.7 - Problem 8-6 The [OH-] of an aqueous solution is M....Ch. 8.8 - Problem 8-7 (a) The [H3O+] of an acidic solution...Ch. 8.8 - Problem 8-8 The [OH-] of a solution is M. What are...Ch. 8.9 - Problem 8-9 Calculate the concentration of an...Ch. 8.10 - Problem 8-10 What is the pH of a buffer solution...
Ch. 8.11 - Problem 8-11 What is the pH of a boric acid buffer...Ch. 8.12 - Prob. 8.12PCh. 8 - 8-13 Define (a) an Arrhenius acid and (b) an...Ch. 8 - 8-14 Write an equation for the reaction that takes...Ch. 8 - 8-15 Write an equation for the reaction that takes...Ch. 8 - 8-16 For each of the following, tell whether the...Ch. 8 - 8-17 For each of the following, tell whether the...Ch. 8 - 8-18 Which of these acids are monoprotic, which...Ch. 8 - 8-19 Define (a) a Brønsted—Lowry acid and (b) a...Ch. 8 - 8-20 Write the formula for the conjugate base of...Ch. 8 - 8-21 Write the formula for the conjugate base of...Ch. 8 - Prob. 8.22PCh. 8 - Prob. 8.23PCh. 8 - Prob. 8.24PCh. 8 - 8-25 Draw the acid and base reactions for the...Ch. 8 - Prob. 8.26PCh. 8 - Prob. 8.27PCh. 8 - 8-28 Will carbon dioxide be evolved as a gas when...Ch. 8 - Prob. 8.29PCh. 8 - Prob. 8.30PCh. 8 - Prob. 8.31PCh. 8 - Prob. 8.32PCh. 8 - 8-33 Write an equation for the reaction of HCI...Ch. 8 - 8-34 When a solution of sodium hydroxide is added...Ch. 8 - 8-35 Given the following values of [H3O+),...Ch. 8 - 8-36 Given the following values of [OH-],...Ch. 8 - 8-37 What is the pH of each solution given the...Ch. 8 - 8-38 What is the pH and pOH of each solution given...Ch. 8 - 8-39 What is the pH of each solution given the...Ch. 8 - Prob. 8.40PCh. 8 - 8-41 What is the [OH-] and pOH of each solution?...Ch. 8 - Prob. 8.42PCh. 8 - 8-43 What is the molarity of a solution made by...Ch. 8 - 8-44 What is the molarity of a solution made by...Ch. 8 - 8-45 Describe how you would prepare each of the...Ch. 8 - 8-46 If 25.0 mL of an aqueous solution of H2SO4...Ch. 8 - 8-47 A sample of 27.0 mL of 0.310 M NaOH is...Ch. 8 - 8-48 A 0.300 M solution of H2SO4 was used to...Ch. 8 - 8-49 A solution of NaOH base was titrated with...Ch. 8 - 8-50 The usual concentration of HCO3- ions in...Ch. 8 - 8-51 What is the end point of a titration?Ch. 8 - Prob. 8.52PCh. 8 - 8-53 Write equations to show what happens when, to...Ch. 8 - 8-54 Write equations to show what happens when, to...Ch. 8 - 8-55 We commonly refer to a buffer as consisting...Ch. 8 - Prob. 8.56PCh. 8 - Prob. 8.57PCh. 8 - 8-58 What is the connection between buffer action...Ch. 8 - Prob. 8.59PCh. 8 - 8-60 How is the buffer capacity affected by the...Ch. 8 - 8-61 Can 100 of 0.1 M phosphate buffer at pH 7.2...Ch. 8 - 8-62 What is the pH of a buffer solution made by...Ch. 8 - 8-63 The pH of a solution made by dissolving 1.0...Ch. 8 - Prob. 8.64PCh. 8 - Prob. 8.65PCh. 8 - 8-66 Calculate the pH of an aqueous solution...Ch. 8 - Prob. 8.67PCh. 8 - 8-68 If you have 100 mL of a 0.1 M buffer made of...Ch. 8 - Prob. 8.69PCh. 8 - Prob. 8.70PCh. 8 - 8-71 Explain why you do not need to know the...Ch. 8 - Prob. 8.72PCh. 8 - Prob. 8.73PCh. 8 - Prob. 8.74PCh. 8 - Prob. 8.75PCh. 8 - 8-76 (Chemical Connections 8B) Name the most...Ch. 8 - Prob. 8.77PCh. 8 - Prob. 8.78PCh. 8 - 8-79 (Chemical Connections 8D) Another form of the...Ch. 8 - Prob. 8.80PCh. 8 - Prob. 8.81PCh. 8 - 8-82 Assume that you have a dilute solution of HCI...Ch. 8 - Prob. 8.83PCh. 8 - Prob. 8.84PCh. 8 - Prob. 8.85PCh. 8 - 8-86 Following are three organic acids and the...Ch. 8 - 8-87 The pKavalue of barbituric acid is 5.0. If...Ch. 8 - Prob. 8.88PCh. 8 - Prob. 8.89PCh. 8 - Prob. 8.90PCh. 8 - Prob. 8.91PCh. 8 - Prob. 8.92PCh. 8 - 8-93 Do a 1.0 M CH3COOH solution and a 1.0 M HCI...Ch. 8 - 8-94 Suppose you wish to make a buffer whose pH is...Ch. 8 - Prob. 8.95PCh. 8 - 8-96 Suppose you want to make a CH3COOH/CH3COO-...Ch. 8 - Prob. 8.97PCh. 8 - 8-98 When a solution prepared by dissolving 4.00 g...Ch. 8 - Prob. 8.99PCh. 8 - Prob. 8.100PCh. 8 - 8-101 Suppose you have an aqueous solution...Ch. 8 - Prob. 8.102PCh. 8 - 8-103 Suppose you have a phosphate buffer...Ch. 8 - Prob. 8.104PCh. 8 - Prob. 8.105PCh. 8 - Prob. 8.106PCh. 8 - 8-107 Following are pH ranges for several human...Ch. 8 - 8-108 What is the ratio of HPO42-/H2PO4- in a...Ch. 8 - Prob. 8.109PCh. 8 - 8-110 A concentrated hydrochloric acid solution...Ch. 8 - 8-111 The volume of an adult's stomach ranges from...Ch. 8 - 8-112 Consider an initial 0.040 M hypobromous acid...Ch. 8 - Prob. 8.113PCh. 8 - Prob. 8.114PCh. 8 - 8-115 When a solution prepared by dissolving 0.125...Ch. 8 - 8-116 A railroad tank car derails and spills 26...Ch. 8 - Prob. 8.117P
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- 8-93 Do a 1.0 M CH3COOH solution and a 1.0 M HCI solution require the same amount of 1.0 M NaOH to hit a titration end point? Explain.arrow_forward8-58 What is the connection between buffer action and Le Chatelier's principle?arrow_forward8-55 We commonly refer to a buffer as consisting of approximately equal molar amounts of a weak acid and its conjugate base—for example, CH3COOH and CH3COO-. Is it also possible to have a buffer consisting of approximately equal molar amounts of a weak base and its conjugate acid? Explain.arrow_forward
- 8-68 If you have 100 mL of a 0.1 M buffer made of NaH2PO4 and Na2HPO4 that is at pH 6.8 and you add 10 mL of 1 M HCI, will you still have a usable buffer? Why or why not?arrow_forwardThe pH of 0.10 M CH3NH2 (methylamine) is 11.8. When the chloride salt of methylamine, CH3NH3Cl, is added to this solution, does the pH increase or decrease? Explain, using Le Chteliers principle and the common-ion effect.arrow_forward8-53 Write equations to show what happens when, to a buffer solution containing equimolar amounts of CH3COOH and CH3COO-, we add: (a) H3O (b) OH-arrow_forward
- 8-94 Suppose you wish to make a buffer whose pH is 8.21. You have available 1 L of 0.100 M NaH2PO4 and solid Na2HPO4. How many grams of the solid Na2HPO4 must be added to the stock solution to accomplish this task? (Assume that the volume remains 1 L.)arrow_forwardAn important component of blood is the buffer combination of bicarbonate ion and carbonic acid. Consider blood with a pH of 7.42. a What is the ratio of [H2CO3] to [HCO3]? b What does the pH become if 15% of the bicarbonate ions are converted to carbonic acid? c What does the pH become if 25% of the carbonic acid molecules are converted to bicarbonate ions?arrow_forwardCalculate the mass of sodium acetate, NaCH3COO, you should add to 500. mL of a 0.150-M solution of acetic acid, CH3COOH, to buffer a solution at a pH of 4.57.arrow_forward
- A 25.0-mL sample of hydroxylamine is titrated to the equivalence point with 35.8 mL of 0.150 M HCl. a What was the concentration of the original hydroxylamine solution? b What is the pH at the equivalence point? c Which indicators, bromphenol blue, methyl red, or phenolphthalein, should be used to detect the end point of the titration? Why?arrow_forward8-51 What is the end point of a titration?arrow_forwardWhich of these combinations is the best to buffer the pH at approximately 9? Explain your choice. CH3COOH/NaCH3COO HCl/NaCl NH3/NH4Clarrow_forward
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