Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
Question
Book Icon
Chapter 8, Problem 8.21P

(a)

Interpretation Introduction

Interpretation:

The air-standard cycles are to be sketched on PT diagrams for the Carnot cycle and also explain why a PT diagram would not be helpful for depicting power cycles involving liquid/vapor phase changes.

Concept Introduction :

Initially a general treatment is given of paths on a PT diagram for an ideal gas with constant heat capacities undergoing reversible polytropic processes. Equation 3.35c may be written as:

  P=KTδ/δ1

  lnP=lnK+δδ1lnT

  dPP=δδ1dTT

  dPdT=δδ1PT ......(A) Sign of dP/dT is that of δ1,i.e.,+

Special cases { δ=0dP/dT=0δ=1dP/dT=

Where P and T are constant

According to equation A,

  d2PdT2=δδ1(1TdPdTPT2)=δδ11T(δδ1PTPT)

  d2PdT2=δδ1PT2 .....eq B Sign of d2P/dT2 is that of δ,i.e.,+

(b)

Interpretation Introduction

Interpretation:

The air-standard cycles are to be sketched on PT diagrams for the Otto Cycle and also explain why a PT diagram would not be helpful for depicting power cycles involving liquid/vapor phase changes.

Concept Introduction :

Initially a general treatment is given of paths on a PT diagram for an ideal gas with constant heat capacities undergoing reversible polytropic processes. Equation 3.35c may be written as:

  P=KTδ/δ1

  lnP=lnK+δδ1lnT

  dPP=δδ1dTT

  dPdT=δδ1PT ......(A) Sign of dP/dT is that of δ1,i.e.,+

Special cases { δ=0dP/dT=0δ=1dP/dT=

Where P and T are constant

According to equation A,

  d2PdT2=δδ1(1TdPdTPT2)=δδ11T(δδ1PTPT)

  d2PdT2=δδ1PT2 .....eq B Sign of d2P/dT2 is that of δ,i.e.,+

(c)

Interpretation Introduction

Interpretation:

The air-standard cycles are to be sketched on PT diagrams for the Diesel cycle and also explain why a PT diagram would not be helpful for depicting power cycles involving liquid/vapor phase changes.

Concept Introduction :

Initially a general treatment is given of paths on a PT diagram for an ideal gas with constant heat capacities undergoing reversible polytropic processes. Equation 3.35c may be written as:

  P=KTδ/δ1

  lnP=lnK+δδ1lnT

  dPP=δδ1dTT

  dPdT=δδ1PT ......(A) Sign of dP/dT is that of δ1,i.e.,+

Special cases { δ=0dP/dT=0δ=1dP/dT=

Where P and T are constant

According to equation A,

  d2PdT2=δδ1(1TdPdTPT2)=δδ11T(δδ1PTPT)

  d2PdT2=δδ1PT2 .....eq B Sign of d2P/dT2 is that of δ,i.e.,+

(d)

Interpretation Introduction

Interpretation:

The air-standard cycles are to be sketched on PT diagrams for the Brayton cycle and also explain why a PT diagram would not be helpful for depicting power cycles involving liquid/vapor phase changes.

Concept Introduction:

Initially a general treatment is given of paths on a PT diagram for an ideal gas with constant heat capacities undergoing reversible polytropic processes. Equation 3.35c may be written as:

  P=KTδ/δ1

  lnP=lnK+δδ1lnT

  dPP=δδ1dTT

  dPdT=δδ1PT ......(A) Sign of dP/dT is that of δ1,i.e.,+

Special cases { δ=0dP/dT=0δ=1dP/dT=

Where P and T are constant

According to equation A,

  d2PdT2=δδ1(1TdPdTPT2)=δδ11T(δδ1PTPT)

  d2PdT2=δδ1PT2 .....eq B Sign of d2P/dT2 is that of δ,i.e.,+

Blurred answer
Knowledge Booster
Background pattern image
Recommended textbooks for you
Text book image
Introduction to Chemical Engineering Thermodynami...
Chemical Engineering
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:McGraw-Hill Education
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemical Engineering
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Text book image
Elements of Chemical Reaction Engineering (5th Ed...
Chemical Engineering
ISBN:9780133887518
Author:H. Scott Fogler
Publisher:Prentice Hall
Text book image
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:9781119285915
Author:Seborg
Publisher:WILEY
Text book image
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:9781285061238
Author:Lokensgard, Erik
Publisher:Delmar Cengage Learning
Text book image
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:9780072848236
Author:Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:McGraw-Hill Companies, The