Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Question
Chapter 7, Problem 7.78E
Interpretation Introduction
Interpretation:
The osmotic pressure of the mercurous solution of sodium is to be calculated.
Concept introduction:
The osmotic pressure is given by the formula,
In the above expression,
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Physical Chemistry
Ch. 7 - Prob. 7.1ECh. 7 - Prob. 7.2ECh. 7 - Prob. 7.3ECh. 7 - Prob. 7.4ECh. 7 - 7.5. For this chemical equilibrium in an enclosed...Ch. 7 - 7.6. The production of nitrogen gas for automobile...Ch. 7 - Prob. 7.7ECh. 7 - Prob. 7.8ECh. 7 - 7.9. For a solution of and in which , what are...Ch. 7 - Prob. 7.10E
Ch. 7 - Prob. 7.11ECh. 7 - Prob. 7.12ECh. 7 - Prob. 7.13ECh. 7 - 7.14. Determine the total equilibrium pressure of...Ch. 7 - Prob. 7.15ECh. 7 - 7.16. Many police departments use breath tests to...Ch. 7 - Prob. 7.17ECh. 7 - 7.18. The vapor pressures of pure liquid A and...Ch. 7 - 7.19. At , the vapor pressure of pure ethanol, ,...Ch. 7 - 7.20. A solution of methanol () and ethanol () has...Ch. 7 - 7.21. At , the vapor pressure of pure ethanol, ,...Ch. 7 - Prob. 7.22ECh. 7 - Prob. 7.23ECh. 7 - Prob. 7.24ECh. 7 - Prob. 7.25ECh. 7 - Prob. 7.26ECh. 7 - Prob. 7.27ECh. 7 - Prob. 7.28ECh. 7 - What are mixG and mixS for the combination of...Ch. 7 - Prob. 7.30ECh. 7 - Prob. 7.31ECh. 7 - Prob. 7.32ECh. 7 - Prob. 7.33ECh. 7 - Prob. 7.34ECh. 7 - Prob. 7.35ECh. 7 - Prob. 7.36ECh. 7 - Prob. 7.37ECh. 7 - Prob. 7.38ECh. 7 - Convert the units of Henrys law constant for CO2,...Ch. 7 - Prob. 7.40ECh. 7 - Prob. 7.41ECh. 7 - Prob. 7.42ECh. 7 - 7.43. The Henry’s law constant for methyl...Ch. 7 - Prob. 7.44ECh. 7 - 7.45. At , the mole fraction of air in water is...Ch. 7 - 7.45. At , the mole fraction of nitrogen, , in...Ch. 7 - Prob. 7.47ECh. 7 - 7.48. Nitrogen narcosis begins to affect scuba...Ch. 7 - Prob. 7.49ECh. 7 - 7.50. What is the approximate molarity of a...Ch. 7 - 7.51. Calculate the solubility of phenol, , in...Ch. 7 - a Convert the calculated mole fraction of...Ch. 7 - Prob. 7.53ECh. 7 - Consider the following solutions: Sodium chloride...Ch. 7 - Determine how ideal the following solutions are by...Ch. 7 - Iron metal has a fusH value of 14.9kJ/mol and is...Ch. 7 - Prob. 7.57ECh. 7 - 7.58. Do communities that use salt in the winter...Ch. 7 - 7.59. Starting from in figure in the liquid...Ch. 7 - Prob. 7.60ECh. 7 - Prob. 7.61ECh. 7 - Estimate the solubility of Na in Hg at 0C. The...Ch. 7 - Prob. 7.63ECh. 7 - Prob. 7.64ECh. 7 - Explain how the unit molarity automatically...Ch. 7 - Prob. 7.66ECh. 7 - The vapor pressure of isopropanol is 47.0mmHg at...Ch. 7 - A sample of 25.0g of solid anthracene is dissolved...Ch. 7 - Prob. 7.69ECh. 7 - A technician dissolves 12.00g of a nonvolatile...Ch. 7 - Prob. 7.71ECh. 7 - Estimate the osmotic pressure, freezing point, and...Ch. 7 - In February 2006, a pharmacy technician...Ch. 7 - Prob. 7.74ECh. 7 - Calculate the freezing point depression of mercury...Ch. 7 - Glacial acetic acid has a melting point of 16.0C...Ch. 7 - Prob. 7.77ECh. 7 - Prob. 7.78ECh. 7 - Use the system in exercise 7.62 to calculate the...Ch. 7 - Prob. 7.80ECh. 7 - Prob. 7.81ECh. 7 - Prob. 7.82ECh. 7 - Prob. 7.83ECh. 7 - Prob. 7.84ECh. 7 - Prob. 7.85ECh. 7 - Determine osmotic pressures for each solution...Ch. 7 - Prob. 7.87ECh. 7 - The vapor pressures of benzene and and 1,1...Ch. 7 - Prob. 7.89ECh. 7 - Tabulate the solubility of naphthalene in toluene...
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- 6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.arrow_forwardThe freezing point of a 0.21 m aqueous solution of H2SO4 is -0.796C. (a) What is i? (b) Is the solution made up primarily of (i) H2SO4 molecules only? (ii) H+ and HSO4- ions? (iii) 2H+ and 1SO42- ions?arrow_forwardConvert the units of Henrys law constant for CO2, in table 7.2, to units of, mmHg, atm, and bar. In which cases does the numerical value of the constant change?arrow_forward
- A patient has a “cholesterol count” of 214. Like manyblood-chemistry measurements,this result is measured inunits of milligrams per deciliter (mgdL1). Determine the molar concentration of cholesterol inthis patient’s blood, taking the molar mass of cholesterolto be 386.64gmol1. Estimate the molality of cholesterol in the patient’sblood. If 214 is a typical cholesterol reading among men inthe United States, determine the volume of such bloodrequired to furnish 8.10 g of cholesterol.arrow_forwardHeat is released when some solutions form; heat is absorbed when other solutions form. Provide a molecular explanation for the difference between these two types of spontaneous processes.arrow_forward
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