Interpretation:
The curved arrow notation and products for each elementary step described by the given sequence are to be drawn.
Concept introduction:
The curved arrow can be drawn from electron-rich site to an electron-poor site to show the flow of electron from electron-rich site to electron-poor site. The first curved arrow drawn from the lone pair of negatively charged atom of electron-rich site to the less electronegative atom of electron-poor site. The second curved arrow drawn from the region between the less electronegative atom and more electronegative atom towards the more electronegative atom indicating the breaking of bond.
An elementary step in which a proton is transferred from electron-poor site to electron-rich site and one bond is broken and another is formed simultaneously is called proton transfer step.
In an elementary step with heterolysis, the bond to the substrate is broken and the bonding electrons become a lone pair on the leaving group. In a coordination step, the Lewis acid is usually deficient of an octet, and the Lewis base has an atom with a partial or full negative charge and a lone pair of electrons.
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Chapter 7 Solutions
ORGANIC CHEMISTRY PRINCIPLES & MECHANISM
- Draw the curved arrow notation and product for each of the following when they undergo an SH2 step.arrow_forwardStudy the following reaction energy diagram: products energy reactants Then answer the following questions about the chemical reaction.arrow_forwardDraw the complete, detailed mechanism for the reaction shown here and draw the major organic product. NH3 C,H15N H2O, Aarrow_forward
- Be sure to include all lone pair electrons and nonzero formal charges. Step 1 Step 2 i Draw H3CO¯, and then add curved arrow notation showing nucleophilic addition.arrow_forwardDraw the complete, detailed mechanism for the reaction shown here and give the major product. CH3I (excess) ? NH2arrow_forwardplease help with this question thank you. Draw the mechanism for the reaction given.arrow_forward
- Draw the missing reactant for the following reactionarrow_forwardHelp please. Draw the curved arrow notation and products for the each elementary step described by the sequence shown here.Note that the products of each step should be used as the reactants in the next step, and you may need to draw in additional reagents as directed. Remember to click on each box to see step-specific instructions. Draw H3CH2C–, and then add the curved arrow notation showing a nucleophilic addition.arrow_forwardBy following the curved red arrows, draw the product(s) of each of the following reaction steps. Also indicate which species is the electrophile and which is the nucleophile.arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
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